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Evaluating natural pozzolans for use as alternative supplementary cementitious materials in concreteSeraj, Saamiya 15 January 2015 (has links)
Concerns over the future availability of traditional SCM sources, such as fly ash, have left the concrete industry in need of alternative sources of SCMs. The research presented here has evaluated natural pozzolans such as pumice, perlite, vitric ash, zeolites, shale and calcined clay as alternative sources of SCMs. Unlike previous research that has only concentrated on empirically evaluating the performance of natural pozzolans in concrete, the research presented in this dissertation has measured both the performance of the pozzolans in cementitious mixtures as well as their physical and chemical characteristics, to draw meaningful relationships between pozzolan properties and performance. The physical and chemical characteristics of these natural SCMs were measured using techniques like particle size analysis, Brunauer–Emmett–Teller (BET) surface area, scanning electron microscope (SEM) imaging, x-ray fluorescence (XRF), x-ray diffraction (XRD), and thermal gravimetric analysis (TGA). The performance of the pozzolans as alternative SCMs was examined by looking at their effect on mortar strength and mixture workability, as well as by their ability to mitigate expansions from durability problems like alkali silica reaction (ASR) and sulfate attack. The performance of the pozzolans was related back to their physical and chemical characteristics to gain an understanding of the underlying mechanisms of cement and pozzolan interaction, and to draw insights as to why some pozzolans perform better than others in cementitious mixtures. Using this knowledge, some of the under-performing pozzolans were modified to see if changes in their properties could improve performance. Results of the research showed that other than the two coarse zeolites, the rest of the pozzolans tested could be used as Class F fly ash replacements in concrete, with the pumice, perlite, metakaolin and fine zeolite being the best performers in terms of mortar strength and durability. Although the pumice mortar had lower strengths than the control at early ages, results from the performance improvement studies showed that the reactivity of pumice could be enhanced by grinding the pozzolans to a finer particle size distribution. Zeolites were found to negatively affect mixture workability, but calcination of the zeolites helped to improve the workability of zeolite mixtures. / text
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Influence of Nontraditional and Natural Pozzolans (NNPs) on the Mechanical and Durability Properties of Mortars and ConcretesAlberto Castillo (12323243) 29 April 2022 (has links)
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<p>Concrete is the second most consumed material in the world after water and is an essential element of constructed infrastructure. Over 14 billion m3 of concrete are being produced annually, resulting in a serious impact on the environment. The production of cement, which is the main component of concrete, is responsible for 5 – 8 % of global CO2 emissions. As a result, several global initiatives have been undertaken to achieve carbon neutrality by 2050. This carbon neutrality target coincides with the Paris Agreement's goal to limit global warming to 1.5 °C. A well-known, and successful strategy to reduce CO2 emissions in the concrete industry is to use supplementary cementitious materials (SCMs) as a partial replacement for cement. However, it is projected that in 2030 the demand for two of the most commonly used SCMs, fly ash and slag cement, will exceed their supply. Using nontraditional and natural pozzolans (NNPs) can help to close this supply gap, but there is a lack of knowledge regarding the reactivity and long-term performance of these materials.</p>
<p>The purpose of this research was to perform experiments on several NNPs, some of which can be supplied in commercially viable quantities with the objective of evaluating their performance in cementitious systems (mortars and concretes) with the goal of accurately assessing their potential for use as alternative SCMs. The mortar study was performed using a total of 11 different NNPs, belonging to 4 distinctive groups and distributed as follows: 3 from the group of calcined clays (CCs) - CC1, CC2, and CC3, 3 from the group of natural pozzolans (NPs) - NP1, NP2 and NP3, 2 from the group of fluidized bed combustion (FBCs) ashes - FBC1 and FBC2, and 3 from the group of bottom ashes (GBAs) - GBA1, GBA2, and GBA3.</p>
<p>The concrete study was performed on 4 different materials, one from each of the previously mentioned groups. The materials selected for concrete study were the worst-performing members of each group, as determined by the analysis of the test results obtained from mortars. These included CC2, NP3, FBC1, and GBA3 materials. This approach was adopted under the assumption that achieving adequate concrete characteristics with lowest-quality materials will all but assure satisfactory performance of concretes with higher-quality materials. </p>
<p>The findings generated from this research indicate that several of the NNPs used in this study present a viable alternative to traditional SCMs. As an example, out of the 11 NNPS, 9 were found to conform to the requirements of the ASTM C618-19, the standard specification currently used to assess the suitability of coal fly ash and raw or calcined natural pozzolans for use in concrete. Results obtained from tests performed on mortars demonstrated that, when used at the replacement level of 25%, all 11 NNPs produced mixtures with characteristics similar to those obtained from the plain cement (OPC) mortar. For that reason, this level of replacement was selected to prepare concrete specimens. The results collected from concrete specimens showed that, when compared to plain concrete, mixtures with all 4 NNPs attained comparable (or improved) mechanical (compressive and flexural strength), durability (freeze-thaw resistance), and transport (formation factor and rate of water absorption) properties. As in the case of traditional SCMs, the mixtures with NNPs were found to require extended curing times to fully realize their property-enhancing potential associated with pozzolanic reactions. Overall, the best performing materials were those from the CCs group, followed by those belonging to, respectively, NPs, GBAs, and FBCs groups. </p>
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