Elevated manganese (Mn) concentrations have been measured in groundwater within the Roanoke River watershed, Virginia. Concentrations of Mn often exceed the secondary drinking water standard. A historic belt of Mn ores, the James River-Roanoke River Manganese District (JRRRMD), occurs in the eastern part of the watershed. The project objectives were to 1) evaluate the formation of the JRRRMD ore deposits and 2) analyze existing groundwater chemistry data to evaluate sources and processes that control groundwater Mn. Analysis of ore minerals, morphologies, and chemistry provides support that the ore deposits are supergene in origin, consistent with previous work. Spatial correlations between Mn ore locations and stream terrace deposits support a model of ore formation in which Mn-oxides were precipitated near discharge zones as anoxic groundwater mixed with oxic groundwater. Terrace deposits present at elevations higher than modern streams suggests that topography has been inverted, allowing ores to be found at higher elevations than what is typically associated with ores formed in discharge zones. Analysis of groundwater chemistry data shows positive correlations between Mn, calcium and bicarbonate concentrations in groundwater, suggesting that carbonate-bearing lithologies are probable sources of Mn to groundwater. Regionally, groundwater flows toward the Roanoke River where the flowpath terminus is marked by elevated Mn. The inverse correlation of Mn with dissolved oxygen suggests that reducing conditions that develop along flowpaths allow for Mn to persist in groundwater. Overall, results suggest that the same processes that allowed for formation of the JRRRM ore deposits continue to occur today. / Master of Science

Thesis (M.Arch.)--University of Detroit Mercy, 2009. / "April 24th, 2009." Includes bibliographical references (p. 118).

Methods of collecting, concentrating, separating, and identifying organic compounds in natural water systems are presented. These methods were applied to a eutrophic reservoir (Hyrum Reservoir, Utah) and resulted in the identification of the following 27 volatile, organic compounds: Alcohols: methanol, ethanol, 1-propanol, isopropyl alcohol, 1-butanol, 2-butanol, isobutyl alcohol, tert-butyl alcohol, 1-pentanol, 2-methyl-l-butanol, methyl-1- butanol, 3-methyl-2-butanol, 2-methyl-2-butanol, 2-methyl-3-buten-2-ol, 1-penten-3-ol, 2-methyl-2-pentanol Ketones: acetone, methyl ethyl ketone, 4-methyl-3-penten-2-one Aldehydes: acetaldehyde, propanal, 2-buten-1-al Others: acetonitrile, ethyl acetate, pyridine, 3-methylpyridine, diethyl ether The concentration level of the following 13 compounds was established in the reservoir from October 1974 to January 1976: Alcohols: methanol, ethanol, propanol, isopropyl alcohol, 1-butanol, isobutyl alcohol, tert-butyl alcohol 2-methyl-2-butanol, 2-methyl-3-buten-2-ol Ketones: acetone, methyl ethyl ketone Others: acetonitrile, acetaldehyde The highest concentrations of organics were found in the late summer or early fall as the bloom of Aphanizomenon flos-aquae died and the level of bacterial fermentation increased. Other sources of organic compounds in the reservoir (besides fermentation) included compounds (acetonitrile and ethanol) at least partially produced by active algal growth and associated bacteria. Melting snowpack and mountain streams that feed the reservoir also contained organic compounds similar to those found in the reservoir, however at lower levels. Most of the compounds at low concentrations had no effect on the growth of certain algae tested, however there was some indication that certain organics may have increased the net growth of Aphanizomenon flos-aquae.

No description available.

There is some evidence from scholarship that politeness norms in China are diversified. I maintain that a study aiming to provide systematic evidence of this would require an approach to politeness phenomena that is able to address such diversity. Drawing upon the insights of recent scholarship on the distinction between the modernist and postmodernist approaches to politeness, I survey relevant literature. I show that many current works on politeness argue that the modernist approach (Lakoff 1973/1975, Brown and Levinson 1987[1978], Leech 1983) generally tends to assume that society is relatively homogeneous with regard to politeness norms. By contrast, I demonstrate that the postmodernist approach to politeness (e.g. Eelen 2001, Mills 2003, Watts 2003) foregrounds the heterogeneity of society and the rich variability of politeness norms within a given culture. I argue that, by using a postmodernist approach to politeness, it is possible to show evidence of differences between groups of the Chinese in their politeness behaviour and the informing norms of politeness. I then explore this issue in depth by focusing on compliments and compliment responses (CRs). I show that studies on these speech acts in Chinese have to date tended to adopt a modernist approach to politeness and often assume a compliment and a CR to be easily identifiable. Moreover, I show that they do not address the heterogeneity of Chinese society and generally assume interactants to be homogeneous in terms of politeness norms that inform compliment and CR behaviours. On this basis, I raise the questions as to whether, by adopting a postmodernist rather than modernist approach, there is empirical evidence that politeness norms informing compliments and CRs vary among the Chinese, and whether these norms correlate with generation. v To this end, by audio-recording both spontaneous naturally occurring conversations and follow-up interviews, I construct a corpus of compliments and CRs generated by two generations of the Chinese brought up before and after the launch of China's reform. Quantitative and qualitative analyses of these data show that there is variation in compliment and CR behaviours in Chinese and the informing politeness norms. Furthermore, the result shows that this variation is correlated with generation. I then show how, by using a research methodology which emphasizes the interactants' perceptions obtained through follow-up interviews, my study brings to light problems with previous studies on compliments and CRs which hitherto are not addressed. By showing evidence that compliments and CRs are not as easy to identify as many previous researchers have indicated. I argue that my emic approach to data analysis provides a useful perspective on the complexity of intention in studies on speech acts and perhaps beyond. My study, therefore, makes an interesting contribution to the debate over this notion central to politeness research. Moreover, I argue my methodology which is able to categorize and analyze data according to participants' self-reported perceptions allows me to draw out differences in the two generations' compliment and CR behaviours and the informing politeness norms.

No description available.

4 pp. / This short fact sheet is taken from "Arizona Well Owner's Guide to Water Supply" currently in print. We plan to complete part 2 of this fact sheet by the end of July, 2009. Please note that the text has already been incorporated into the eXtension Community of Practice web page - - I am the author for the COP/Drinking Water group text on chemistry of naturally occurring water contaminants. / Arizona well water is often contaminated with elevated concentrations of naturally occurring constituents that are a human health concern. This short fact sheet is the first in a two-part series about what naturally occurring contaminants may be found in your water supply well and includes a brief discussion on environmental pollutants that originate from land use activities. If you own a well in Arizona, you have the sole responsibility for checking to see if your drinking water is contaminated. Arizona state law does not require private well owners to test or treat their water for purity. The second part of this series outlines what to sample for and how to understand your analytical results.

This thesis takes Discursive Psychology as its main theoretical influence. Drawing on the resources of Discursive Psychology and utilising analytic tools provided by Conversation Analysis, these principles are applied to the study of addiction, and specifically alcohol problems. The data explored are telephone calls to an alcohol helpline. Four analytic chapters are presented. The first focuses on the concept of loss of control over drinking, identifying features of how this concept is constructed in talk and suggests possible functions of control talk for both callers and Advice Workers. The second analytic chapter examines how Advice Workers respond to callers' professed impaired control over their drinking and I demonstrate that embedded in discursive sequences of problem formulation and advice giving are issues of agency, accountability and responsibility. The thesis moves on to explore the role of knowledge in calls to an alcohol helpline and the analysis reveals that both the expert status of the Advice Worker and the speciality of the topic are co-constructed between the speakers on the helpline. The final analytic chapter features just one telephone call and demonstrates the application of such an analysis for alcohol service providers. The thesis ends with a discussion of the main overall findings and the implications of the research for clinical practice. I close by arguing that initial agency contact is a very important site of study and recommend that this should be explored utilising naturally-occurring talk.

Arsenic (As) and nitrate (NO3) are common contaminants in groundwater that are introduced through a variety of natural and anthropogenic sources. In this study we investigated the sources and distribution of As and NO3 in Goshen Valley, Utah, USA. Goshen Valley is a semi-arid alluvial basin that is impacted by geothermal waters, agriculture, urban development, and legacy mining. In this study we sampled surface water, springs, and wells to analyze concentrations of major ions, trace elements (As, B, Ba, Ca, Fe, K, Li, Mg, Mn, Mo, Pb, Si, Sr, Zn), and stable isotopes in water (δ18O and δD). A subset of samples were also analyzed for 87Sr/86Sr, δ34S, and tritium (3H). Major ion concentrations showed high spatial variability ranging from freshwater to brines, with the highest concentrations found in springs discharging from playa sediments. Likewise, the highest trace element concentrations, including As, were found in the playa-impacted springs. Elevated NO3 concentrations were found in springs and wells in agricultural areas of the valley. δ18O and δD values range from -0.90238 to -17.6 and -37.0891 to -134.5 respectively and represent that the valley contains old groundwater, evaporative surface water, and mixed water signatures in multiple wells. Tritium values range from 0.5 to 7.8 and further show the diversity of water in the valley by indicating old, young, and mixtures of old and young waters. Variations in 87Sr/86Sr were used to evaluate flowpaths of waters with elevated As. 87Sr/86Sr ratios suggest that the groundwater has interacted with a mixture of lithologic units including Tertiary volcanics, Paleozoic carbonates, and Quaternary alluvial/lacustrine fill. Correlations with As and playa affected springs indicate playa sediments as a major As source. The As found in wells has no apparent elemental correlations or spatial patterns and is likely due to the naturally occurring As in the valley alluvium and carbonate units. NO3 in the valley is concentrated in agricultural areas and is likely due to fertilizers, livestock, and alfalfa crops. Of all the potential contaminant sources, the data suggests that the major source of As is the saline playa soils and the major source of NO3 is agricultural activities in the valley.

Thesis (M.G.S.)--Miami University, Dept. of Sociology and Gerontology, 2006. / Title from first page of PDF document. Includes bibliographical references (p. 31-32).