Thesis (Ph. D.)--University of Texas at Austin, 1999. / Vita. Includes bibliographical references (leaves 314-328). Available also in a digital version from Dissertation Abstracts.

Thesis (M.S.)--Virginia Polytechnic Institute, 1951. / Vita. Includes bibliographical references (leaves 105-112). Also available via the Internet.

Thesis (M.S.)--University of Wisconsin--Madison. / Typescript. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 205-210).

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The catalytic interaction of potassium salts in the reaction of carbon with oxygen and carbon dioxide has been studied with the aim of elucidating the mechanism of the reaction. In order to achieve this the approach used has been to utilise a wide variety of physical techniques in order to identify the active species. These range from bulk in-situ techniques like X-ray diffraction and thermogravimetric analysis to surface sensitive techniques like photoelectron spectroscopy and scanning electron microscopy. Experimental apparatus was also developed that enabled thermogravimetric analysis of samples to be carried out with mass spectra analysis of gaseous products formed. These techniques enabled the behaviour of K<SUB>2</SUB>CO<SUB>3</SUB> with and without the presence of carbon to be characterised over a wide range of temperatures and under inert and reactive atmospheres. This showed that at room temperature K<SUB>2</SUB>CO<SUB>3</SUB> would readily react with the atmosphere to form hydrated carbonate as well as KHCO<SUB>3</SUB> however upon heating to above 100<SUP>o</SUP>C these phases would decompose to leave K<SUB>2</SUB>CO<SUB>3</SUB>. This phase remained upto 600<SUP>o</SUP>C where decomposition started. The decomposition products evaporated from the solids as CO<SUB>2</SUB> and K<SUB>2</SUB>O or K. The presence of K<SUB>2</SUB>CO<SUB>3</SUB> enhanced the reaction of graphite with O<SUB>2</SUB> and CO<SUB>2</SUB>. C<SUB>8</SUB>K and residually intercalated C<SUB>8</SUB>K were used as model compounds to aid the identification of the active potassium species present during gasification. This showed K intercalates and K metal to be unstable under gasification conditions and therefore played no role in the mechanism of catalytic gasification. Photoelectron spectroscopy identified C-O-K and carbon oxides to be the predominant surface species present during gasification, while scanning electron microscopy revealed that in general graphite gasification occurred along the prismatic plane, however gasification on the basal plane took place if a fine disperson of catalyst occurred in the graphite surface.

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