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New diphosphines with acenaphthene and phenylene backbonesBasra, Sandeep January 2002 (has links)
No description available.
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Catalysts for stereoselective transformationsCooper, Christine J. January 2012 (has links)
No description available.
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Polyisobutylene as a Polymer Support for Homogeneous CatalysisHongfa, Chayanant 14 January 2010 (has links)
Phase selective soluble polymers are useful in organic synthesis because they
simplify purification and separation processes. Such selective soluble polymers enable
the use of Green chemistry principles to be utilized as ways to simplify catalyst, reagent,
and product recovery. Polyisobutylene oligomers serve as examples of such polymers.
Vinyl terminated polyisobutylene (PIB) oligomers can be easily transformed into a
variety of end-functionalized PIB oligomers. Previous work has shown that PIB
oligomers possess nonpolar phase selective solubility that allows them to be used as
polymer supports for ligands and catalysts in liquid/liquid biphasic systems. This
dissertation focuses on the use of PIB oligomers as supports for a salen Cr(III) complex,
a Hoveyda-Grubbs 2nd generation catalyst, and a N-heterocyclic carbene. The syntheses
of these PIB-supported ligands and catalysts are simple and straightforward. The
synthetic products and the intermediates in these syntheses can all be readily analyzed
and monitored by conventional spectroscopic methods. The activity of the PIBsupported
catalysts is shown to be analogous to that of other soluble polymer supported
catalysts or their non-supported analogs. The PIB-bound catalysts can be separated from products by a latent biphasic, liquid/liquid extractions, or product self-separation
systems. The recovered PIB-bound catalysts can then be recycled multiple times.
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Information and politics /Frisell, Lars, January 1900 (has links)
Diss. Stockholm : Handelshögsk., 2001.
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Concerning homogeneous plane continuaCohen, Herman Jacob, January 1949 (has links)
Thesis (Ph. D.)--University of Wisconsin--Madison, 1949. / Typescript. Vita. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 25-26).
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Continuous flow synthesis of silicon compounds as feedstock for solar-grade silicon productionChigondo, Fidelis January 2016 (has links)
This thesis describes the key steps in the production of high purity (solar-grade) silicon from metallurgical-grade silicon for use in the production of photovoltaic cells as alternative renewable, environmentally benign and cheap energy source. The initial part of the project involves the development and optimization of a small chemical production platform system capable of producing alkoxysilanes from metallurgical-grade silicon as green precursors to solar-grade silicon production. Specifically, the main aim of the study was to synthesize trialkoxysilanes in continuous flow mode, although the synthesis on monosilane was also done in batch mode. The alkoxylation reaction was carried out in a traditional slurry phase batch reactor, packed bed flow tubular reactor and also attempted in a continuous flow falling film tubular reactor. The effect of key parameters which affect the silicon conversion and selectivity for the desired trialkoxysilane were investigated and optimized using ethanol as a reagent model. The synthesis was then extended to the other alcohols namely methanol, n-propanol and n-butanol. Copper catalysts which were tested in the alkoxylation reaction included: CuCl, Cu(OH)2, CuO and CuSO4. CuCl and Cu(OH)2 showed comparable activity in the batch mode but the former was more efficient in the packed bed flow tubular reactor. Cu(OH)2 could be used as a non-halide catalyst but its activity is limited to short reaction cycles (<10 h). The uncatalysed reaction resulted in negligible reaction rates in both types of reactors. High temperature catalyst pre-heating (>500 oC) resulted in a lower rate of reaction and selectivity than when slightly lower temperatures are used (<350 oC) in both reactors, although much difference was noticed in the packed bed flow tubular reactor. Synthesis in the batch reactor needed longer silicon-catalyst activation time, higher pre-heating temperature and higher catalyst amounts as compare to the packed bed flow tubular reactor. Reaction temperature and alcohol flow rate influenced the reaction in both methods. The optimum reaction temperature range and alcohol flow rate was comparable in both reactors (230 to 240 oC) and 0.1mL/min respectively. The effect of alcohol R-group (C1 to C4) on the reaction revealed that conversion and selectivity generally decrease with an increase in carbon chain length in both methods. Ethanol showed highest selectivity (>95% in batch and >97% in flow) and conversion (about 88% in batch and about 64% in flow) as compared to all other alcohols studied showing that it could be the most efficient alkoxylation alcohol for this reaction. Overally, the packed bed flow tubular reactor resulted in higher selectivity to trialkoxysilanes than the batch system. Performing the reaction under pressure resulted in increased conversion but selectivity to the desire trialkoxysilane diminished. Synthesis in a continuous flow falling film tubular reactor was not successful as it resulted in very poor conversion and selectivity. Monosilane was successfully synthesized from the disproportionation of triethoxysilane using homogeneous and heterogeneous catalysts in batch mode. The results obtained from homogeneous catalysis showed that the reaction can be conducted at room temperature. The heterogeneous catalysis method resulted in slow conversion at room temperature but mild heating up to 55 oC greatly improved the reaction. Conducting the reaction under neat conditions produced comparable results to reactions which were carried out using solvents. The disproportionation reaction was best described by the first order kinetic model. The results obtained in this research indicate that the packed bed flow tubular reactor can be utilized with future modifications for continuous flow synthesis of alkoxysilanes as feedstock for the solar-grade silicon production.
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A tumbler and pore water expression device to prepare homogeneous samples for the extraction of free chloride in cement pasteDelport, D.J., Potgieter-Vermaak, S.S., Potgieter, J.H. January 2013 (has links)
Published Article / Corrosion of rebar in concrete is commonly associated with the free chloride in the pore water in the cement matrix. Knowing the quantity of chloride in concrete is important because chloride can promote corrosion of steel reinforcement when moisture and oxygen are present. The problem ofphysical extraction and the measurement of the free chloride content in pore water solutions extracted from cement pastes has received attention in literature but has not been explained in full detail. However, the variability of results obtained from the different methods used by various investigators only serves to confuse the issue. This investigation describes the use of a tumbler designed to prepare homogeneous samples and the use of a pore water expression device designed to extract free chloride in cement paste and concrete samples.
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New electron-poor phosphine ligands for hydroformylation and hydrocyanation catalysisMason, Katie Louise January 1997 (has links)
No description available.
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Developments in supported aqueous-phase catalysisMirza, Amin Ruhul January 1999 (has links)
No description available.
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Study on breeding performance of commercial liquid metal cooled fast breeder reactorKOSAKA, NANAMI 09 October 2014 (has links)
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01137.pdf: 2868692 bytes, checksum: b96683d678b98d2146c456600b10bbfe (MD5) / Tese (Doutoramento) / IPEN/T / University of Tokyo, Faculty of Engineering, Japan
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