Powerlines are important in the process of electricity transmission and distribution (T & D) and their essential role in transmitting electricity from the large generating stations to the final consumers cannot be over emphasized. Over the years, an increase in the demand for electrical energy (electricity) has led to the construction and inevitable use of high transmission voltage, sub-transmission voltage and distribution voltage power conducting lines, for the electricity T & D process. Along with this essential role, electricity conductors can also give rise to some electrically related effects such as interference with telecommunication circuits, electric shocks, electromagnetic fields, audible noise, corona ion discharges, etc. The presence of powerline generated corona ions in any ambient air environment can be associated with the local modification of the earth’s natural dc electric field (e-field), while the interactions between these ions and other airborne aerosol particles can be associated with the presence of charged aerosol particles in the environment of the corona ion emitting lines. When considering all the studies conducted to date on the possible direct and indirect effects of high voltage powerlines (HVPLs), of significant interest are those suggesting links between powerlines and some adverse human health effects – with such health effects alleged to be strongest amongst populations directly exposed to HVPLs. However, despite the numerous studies conducted on HVPLs, to date a lack of proper scientific understanding still exist in terms of the physical characterization of the electrical environment surrounding real-world HVPLs - mostly in terms of the entire dynamics of ions and charged particles, as well as the possible links/associations between the different parameters that characterize these electrical environments. Yet, gaining a sound understanding about the electrical environment surrounding energized real-world HVPLs is imperative for the accurate assessment of any possible human exposure or health effects that may be associated with powerlines. The research work presented in this thesis was motivated by the existing gaps in scientific understanding of the possible association between corona ions generated by real-world HVPLs and the production of ambient charged aerosol particles. The aim of this study was to supply some much needed scientific knowledge about the characteristics of the electrical environment surrounding real-world energized HVPLs. This was achieved by investigating the possible effects of corona ions generated by real-world overhead HVPLs on ambient aerosol particle number concentration level, ambient aerosol particle charge concentration level, ambient ion concentration level and the magnitude of the local vertical dc e-field; while also taking into consideration the possible effect of complex meteorological factors (such as temperature, pressure, wind speed wind direction, solar radiation and humidity) on the instantaneous value of these measured parameters, at different powerline sites. The existence of possible associations or links between these various parameters measured in the proximity of the powerlines was statistically investigated using simple linear regression, correlation and multivariate (principal component, factor, classification and regression tree-CART) analysis. The strength of the regression was tested with coefficient of determinations R2, while statistical significance was asserted at the 95 % confidence level. For the powerline sites investigated in this study, both positive and negative polarities of ions were found to be present in the ambient air environment. The presence of these ions was associated with perturbations in the local vertical dc e-field, increased net ambient ion concentrations and net particle charge concentration levels. The mean net ion concentration levels (with a range of 4922 ions cm-3 to -300 ions cm-3) in the ambient environment of these powerlines, were in excess of what was measured in a typical outdoor air (i.e -400 ions cm-3). The mean net particle charge concentration levels (1469 ions cm-3 to -1100 ions cm-3) near the powerlines were also found to be statistically significantly higher than what was obtained for a mechanically ventilated indoor room (-84 ± 49 ions cm-3) and a typical urban outdoor air (-486 ± 34 ions cm-3). In spite of all these measured differences however, the study also indicated that ambient ion concentration as well as its associated effects on ambient particle charge concentration and e-field perturbations gradually decreased with increase in distance from the powerlines. This observed trend provided the physical evidence of the localized effect of real-world HVPL generated corona ions. Particle number concentration levels remained constant (in the order of 103 particles cm-3) irrespective of the powerline site or the sampling distance from the lines. A close observation of the output signals of the sampling instruments used in this study consistently revealed large fluctuations in the instantaneous value of all the measured electrical parameters (i.e. non-periodic extremely high and low negative and positive polarities of ions/charged particles and e-field perturbations was recorded). Although the reason for these observed fluctuations is not particularly known at this stage, and hence in need of further investigations, it is however being hypothesized that, since these fluctuations appear to be characteristic of the highly charged environment surrounding corona ion emitting electrical infrastructures, they may be suggestive of the possibility that the release of corona ions by ac lines are not necessarily in the form of a continuous flow of ions. The results also showed that statistically significant correlations (R2 = 74 %, P < 0.05) exists between the instantaneous values of the ground-level ambient ion and the ground-level ambient particle charge concentration. This correlation is an indication of the strong relationship/association that exists between these two parameters. Lower correlations (R2 = 3.4 % to 9 %, P < 0.05) were however found to exist between the instantaneous values of the vertical dc e-field and the ground-level ambient particle charge concentration. These suggest that e-field measurements alone may not necessarily be a true indication of the ground-level ambient ion and particle charge concentration levels. Similarly, low statistical correlations (R2 = 0.2 % to 1.0 %, P < 0.05) were also found to exist between the instantaneous values of ambient aerosol particle charge concentration and ambient ultrafine (0.02 to 1 μm sized) aerosol particle number concentration. This low level of correlations suggests that the source contribution of aerosol particle charge and aerosol particle number concentration into the ambient air environment of the HVPLs were different. In terms of the implication of human exposure to charged aerosol particles, the results obtained from this study suggests that amongst other factors, exposure to the dynamic mixture of ions and charged particles is a function of : (a) distance from the powerlines; (b) concentration of ions generated by the powerlines; and (c) meteorology - wind turbulence and dispersal rate. In addition to all its significant findings, during this research, a novel measurement approach that can be used in future studies for the simultaneous monitoring of the various parameters characterizing the physical environment of different ion/charged particle emission sources (such as high voltage powerlines, electricity substations, industrial chimney stack, motor vehicle exhaust, etc.) was developed and validated. However, in spite of these significant findings, there is still a need for other future and more comprehensive studies to be carried out on this topic in order to extend the scientific contributions of in this research work.

The measurement of submicrometre (< 1.0 m) and ultrafine particles (diameter < 0.1 m) number concentration have attracted attention since the last decade because the potential health impacts associated with exposure to these particles can be more significant than those due to exposure to larger particles. At present, ultrafine particles are not regularly monitored and they are yet to be incorporated into air quality monitoring programs. As a result, very few studies have analysed their long-term and spatial variations in ultrafine particle concentration, and none have been in Australia. To address this gap in scientific knowledge, the aim of this research was to investigate the long-term trends and seasonal variations in particle number concentrations in Brisbane, Australia. Data collected over a five-year period were analysed using weighted regression models. Monthly mean concentrations in the morning (6:00-10:00) and the afternoon (16:00-19:00) were plotted against time in months, using the monthly variance as the weights. During the five-year period, submicrometre and ultrafine particle concentrations increased in the morning by 105.7% and 81.5% respectively whereas in the afternoon there was no significant trend. The morning concentrations were associated with fresh traffic emissions and the afternoon concentrations with the background. The statistical tests applied to the seasonal models, on the other hand, indicated that there was no seasonal component. The spatial variation in size distribution in a large urban area was investigated using particle number size distribution data collected at nine different locations during different campaigns. The size distributions were represented by the modal structures and cumulative size distributions. Particle number peaked at around 30 nm, except at an isolated site dominated by diesel trucks, where the particle number peaked at around 60 nm. It was found that ultrafine particles contributed to 82%-90% of the total particle number. At the sites dominated by petrol vehicles, nanoparticles (< 50 nm) contributed 60%-70% of the total particle number, and at the site dominated by diesel trucks they contributed 50%. Although the sampling campaigns took place during different seasons and were of varying duration these variations did not have an effect on the particle size distributions. The results suggested that the distributions were rather affected by differences in traffic composition and distance to the road. To investigate the occurrence of nucleation events, that is, secondary particle formation from gaseous precursors, particle size distribution data collected over a 13 month period during 5 different campaigns were analysed. The study area was a complex urban environment influenced by anthropogenic and natural sources. The study introduced a new application of time series differencing for the identification of nucleation events. To evaluate the conditions favourable to nucleation, the meteorological conditions and gaseous concentrations prior to and during nucleation events were recorded. Gaseous concentrations did not exhibit a clear pattern of change in concentration. It was also found that nucleation was associated with sea breeze and long-range transport. The implications of this finding are that whilst vehicles are the most important source of ultrafine particles, sea breeze and aged gaseous emissions play a more important role in secondary particle formation in the study area.

Phenomenon of industrial grounds placed near residential areas can be frequently detected in European cities, which may cause decrease of air quality in these areas. The aim of this diploma thesis is to determine level of concentration and size distribution of aerosol in the planetary boundary layer above the residential area and industrial complex of Škoda auto a.s. in Mladá Boleslav city by using remotely controlled airship. Thereby, the thesis extends terrestrial experiment realized in February and March 2013 which revealed no significant impact of industry and traffic on air quality. Size distribution and concentration of aerosol particles in range from 11.5nm to 10µm with integration time one second or one minute (depending on measure mode - SINGLE or SCAN) was measured by two aerosol spectrometers placed in dirigible gondola during 13 flights on February 11, 2015. SINGLE mode lead the airship in one stable flight level during one flight above residential area and industrial complex of Škoda auto a.s. Whereas SCAN mode changed flight level every two minutes during the flight of airship above sports fields in residential zone only. Exhausts of car painting halls and place of automobile loading were identified as the sources of nanoparticles, PM1 a PM2.5 and coarse aerosol in the industrial area...

Biomass burning started to attract attention since the last decade because of its impacts on the atmosphere and the environmental air quality, as well as significant potential effects on human health and global climate change. Knowledge of particle emission characteristics from biomass burning is crucially important for the quantitative assessment of the potential impacts. This thesis presents the results of study aimed towards comprehensive characterization of particle emissions from biomass burning. The study was conducted both under controlled laboratory conditions, to quantify the particle size distribution and emission factors by taking into account various factors which may affect the particle characteristics, and in the field, to investigate biomass burning processes in the real life situations and to examine vertical profile of particles in the atmosphere. To simulate different environmental conditions, a new technique has been developed for investigating particle emissions from biomass burning in the laboratory. As biomass burning may occur in a field at various wind speeds and burning rates, the technique was designed to allow adjustment of the flow rates of the air introduced into the chamber, in order to control burning under different conditions. In addition, the technique design has enabled alteration of the high particle concentrations, allowing conducting measurements with the instrumentations that had the upper concentration limits exciding the concentrations characteristic to the biomass burning. The technique was applied to characterize particle emissions from burning of several tree species common to Australian forests. The aerosol particles were characterized in terms of size distribution and emission factors, such as PM2.5 particle mass emission factor and particle number emission factor, under various burning conditions. The characteristics of particles over a range of burning phases (e.g., ignition, flaming, and smoldering) were also investigated. The results showed that particle characteristics depend on the type of tree, part of tree, and the burning rate. In particular, fast burning of the wood samples produced particles with the CMD of 60 nm during the ignition phase and 30 nm for the rest of the burning process. Slow burning of the wood samples produced large particles with the CMD of 120 nm, 60 nm and 40 nm for the ignition, flaming and smoldering phases, respectively. The CMD of particles emitted by burning the leaves and branches was found to be 50 nm for the flaming phase and 30 nm for the smoldering phase, under fast burning conditions. Under slow burning conditions, the CMD of particles was found to be between 100 to 200 nm for the ignition and flaming phase, and 50 nm for the smoldering phase. For fast burning, the average particle number emission factors were between 3.3 to 5.7 x 1015 particles/kg for wood and 0.5 to 6.9 x 1015 particles/kg for leaves and branches. The PM2.5 emission factors were between 140 to 210 mg/kg for wood and 450 to 4700 mg/kg for leaves and branches. For slow burning conditions, the average particle number emission factors were between 2.8 to 44.8 x 1013 particles/kg for wood and 0.5 to 9.3 x 1013 particles/kg for leaves and branches, and the PM2.5 emissions factors were between 120 to 480 mg/kg for wood and 3300 to 4900 mg/kg for leaves and branches. The field measurements were conducted to investigate particle emissions from biomass burning in the Northern Territory of Australia over dry seasons. The results of field studies revealed that diameters of particles in ambient air emissions were within the size range observed during laboratory investigations. The laboratory measurements found that the particles released during the controlled burning were of a diameter between 30 and 210 nm, depending on the burning conditions. Under fast burning conditions, smaller particles were produced with a diameter in the range of 30 to 60 nm, whilst larger particles, with a diameter between 60 nm and 210 nm, were produced during slow burning. The airborne field measurements of biomass particles found that most of the particles measured under the boundary layer had a CMD of (83 ± 13) nm during the early dry season (EDS), and (127 ± 6) nm during the late dry season (LDS). The characteristics of ambient particles were found to be significantly different at the EDS and the LDS due to several factors including moisture content of vegetation, location of fires related to the flight paths, intensity of fires, and burned areas. Specifically, the investigations of the vertical profiles of particles in the atmosphere have revealed significant differences in the particle properties during early dry season and late dry season. The characteristics of particle size distribution played a significant role in these differences.