Thesis (Ph.D.)--Murdoch University, 2004. / Thesis submitted to the Division of Science and Engineering. Bibliography: leaves167-191.

Thesis (Ph. D.)--Duke University, 2007.

Thesis (M.S.)--Ball State University, 2008. / Title from PDF t.p. (viewed on Oct. 22, 2009). Includes bibliographical references.

Thesis supervisor: Jerald L. Schnoor. Thesis supervisor: Craig L. Just. Includes bibliographic references (p. 186-196).

Thesis (M.C.E.)--University of Delaware, 2006. / Principal faculty advisor: William Ritter, Dept. of Civil & Environmental Engineering. Includes bibliographical references.

Nutrients are of critical concern in water quality assessment. The development of empirical models to estimate mean nutrient concentrations, based on satellite derived land use, could aid water resource managers. Models using land use acreages outperformed those using percentages, and discrete urban land uses were superior to lumped urban. Regressions of the combinations of two, three and four of the eight possible land use variables were investigated. Sensitivity analyses, with one stream deleted each series, identified robust combinations of variables at each level. Although uncertainty exists regarding the final regression coefficients, five of the six actual measured nitrate and total phosphorus mean concentrations were within the 95 percent confidence limits.

Approximately 25% of households in the U.S. treat their wastewater onsite using conventional onsite wastewater treatment systems (OWTS). These systems typically include a septic tank or a series of septic tanks followed by a soil absorption system. They effectively remove biochemical oxygen demand (BOD), total suspended solids (TSS), fats and grease but are not designed to remove significant amounts of nitrogen. High nitrogen loading to coastal and ground waters can be dangerous to aquatic life and public health. Hence, there is a need for advanced onsite wastewater treatment systems that can effectively remove nitrogen. Making enhanced nitrogen removal for OWTS as our primary goal, a laboratory scale Hybrid Adsorption and Biological Treatment Systems (HABiTS) was developed and upon observation of its effective nitrogen removal capacity, a pilot demonstration study with two side-by-side HABiTS, one with recirculation and one without recirculation (only forward flow) were constructed and tested at the Northwest Regional Water Reclamation Facility in Hillsborough County (Florida). HABiTS employ biological nitrogen removal and ion exchange for effective nitrogen removal. HABiTS is a two-stage process which uses nitrification for the oxidation of ammonium to nitrate and ion exchange for ammonium adsorption that helps buffer transient loading and also acts as a biofilm carrier in its stage 1 biofilter and it uses tire-sulfur hybrid adsorption denitrification (T-SHAD) in its stage 2 biofilter. These sulfur pellets help promote sulfur oxidation denitrification (SOD) and tire chips are used for nitrate adsorption during transient loading conditions, as biofilm carriers for denitrifying bacteria, and can also be used as organic carbon source to promote heterotrophic denitrification because they leach organic carbon. For this research, HABiTS without recirculation is considered as the control system and the performance of HABiTS with recirculation was tested for its ability to further enhance nitrogen removal from HABiTS. Nitrified effluent recirculation is a common strategy employed in wastewater treatment for enhanced nitrogen removal. It is the reintroduction of semi-treated wastewater to pass through an anoxic pre-treatment chamber to achieve better quality effluent. Recirculation is said to improve and consistently remove nitrogen at any hydraulic loading rate and/or nitrogen concentration. This is because of the dilution of high BOD septic tank effluent with nitrified effluent which lowers COD:TKN ratio and also improves mass transfer of substrates in the stage 1 biofilter. Recirculation also provides some pre-denitrification in the pre-treatment chamber, thereby reducing nitrogen load on the system. The HABiTS with recirculation (R) was run at 1:1 ratio of nitrified effluent recirculation rate to the influent flow rate for 50 days, and at 3:1 ratio for the remaining period of this research (200 days). The forward flow system (FF) was run under constant conditions throughout the research and comparisons between the two systems were made for different water quality parameters (pH, DO, conductivity, alkalinity, TSS, chemical oxygen demand (COD), total nitrogen (TN), total phosphorus (TP) and various nitrogen species). The final effluent ammonium results showed that the system with recirculation removed consistently > 80% NH4+-N during 1:1 and 3:1 recirculation ratios whereas the forward flow system achieved 57% removal. Further, an average of 81% total inorganic nitrogen (TIN) removal from the system influent was seen in the recirculation system’s final effluent when compared to an average of 55% in forward flow system’s final effluent. This research explains in detail, the impact of nitrified effluent recirculation on enhanced nitrogen removal in onsite systems and the results presented in this thesis proved that nitrified effluent recirculation provides promising enhanced nitrogen removal in an onsite wastewater treatment system.

Interactions between cyanobacteria and herbivorous grazers play an important role in mediating the responses of freshwater phytoplankton assemblages to nutrient enrichment and top-down manipulation. Negative consequences associated with these interactions include dangerous blooms of harmful blue-green algae that have been implicated in the sickness and death of fishes, livestock, and, in extreme cases, humans. Frequently cited mechanisms influencing the interactions between grazers and cyanobacteria include cyanobacterial toxicity and morphology. To tease apart the importance of these mechanisms, I used meta-analysis to quantitatively synthesize the available literature on this topic. In addition, I conducted several experiments using novel techniques to determine the effect that cyanobacterial secondary metabolites from the bloom-forming cyanobacterium,

This study investigated temporal changes in nutrient concentrations and other water quality parameters at one sampling location at Muncie, Indiana in the Upper White River Watershed. Baseline sampling was conducted weekly over a six-month period in 2012 and focused on the analysis of total suspended solids and different forms of nitrogen and phosphorus. Three storm events were also investigated to understand how storm water runoff affected nutrient concentrations and other water quality parameters. It was hypothesized that storm events would temporarily increase nutrient concentrations in the river. Overall, nutrient concentrations increased during the initial stages of storm events and subsequently decreased at a rate slower than discharge. Concentrations measured exceeded recommended limits suggesting that these contaminants could cause eutrophication at downstream locations. These data suggest that improved or increased best management practices should be implemented in the Upper White River Watershed to control the inputs of nutrients into the river. / Department of Natural Resources and Environmental Management

The Prairie Creek Reservoir, located in east central Indiana in an agricultural watershed, serves as a secondary drinking water source as well as a recreational facility. Limited research of water quality performed at the reservoir has affected management decisions over the past years, threatening its future.. Consequently, additional investigation was necessary to examine the reservoir dynamics, and continue to provide data to determine long-term water quality trends. Basic water quality parameters were measured using a Hydrolab Sonde, nutrients were measured spectrophotometrically, and a Secchi disk was used to determine water transparency. The Prairie Creek Reservoir was categorized as an eutrophic water body. Concentrations of the measured nutrients were higher in the hypolimnion and increased as summer progressed. Concentration of ammonia and soluble reactive phosphorus exceeded the recommended water quality guidelines. Increased concentration of phosphorus has resulted in nitrogen limitation in the reservoir. Internal loading of nutrients, especially phosphorus, was found to deteriorate water quality. Dissolved oxygen concentrations varied vertically and anoxic conditions frequently reached 50% of the total reservoir depth. Reservoir restoration and watershed protection programs need to address internal P load and nitrogen limitation to prevent development of toxic algal blooms and eutrophication in the future. / Department of Natural Resources and Environmental Management