Thesis (Ph. D.)--Lehigh University, 2005. / Includes vita. Adviser: H. Daniel Ou-Yang. Bibliography: leaves 151-157.

Third order nonlinear optical properties of organic compounds with $\pi$ electron delocalization are currently receiving much attention in view of potential applications in switching and optical information processing. Polymers of Benzidine were synthesized by hydrogen peroxide reaction catalyzed by horseradish peroxidase enzyme. The polymerization reaction was carried out at room temperature in a monophasic organic solvent with a small amount of water at pH 7.5. The technique of Degenerate Four Wave Mixing with picosecond and nanosecond pulses was employed to measure the third order susceptibility $\chi\sp{(3)}$ of polybenzidine. The observed values for $\chi\sp{(3)}$ are of order 10$\sp{-9}$ to 10$\sp{-8}$ esu. In order to understand the origin of these high values of $\chi\sp{(3)}$, we measured the real and imaginary components of $\chi\sp{(3)}$. Investigation of total energy transmission as a function of incident intensity and fluence at 532 nm for picosecond and nanosecond laser pulses using a frequency doubled Nd:YAG laser indicates reverse saturable absorption. The experiments are carried out for the sample in solution in Dimethyl Sulfoxide and Methanol (DMSO:MeOH) 4:1 ratio. As we observe the nanosecond and picosecond curves to be superimposed for intensity dependence and not for fluence, we conclude that the third order nonlinearity is predominantly due to two photon absorption. Values for Im $\chi\sp{(3)}$ determined by our experiments are of order 10$\sp{-9}$ to 10$\sp{-8}$ esu. We measure the real part of $\chi\sp{(3)}$ by optical Kerr gate technique. The value is about one order lower compared to the imaginary component. In view of the reverse saturable absorption characteristics observed for the samples, the material is a good candidate for applications in optical power limiting.

The demand for products of ever increasing quality or for novel applications has required increasing attention to or manipulation of the anisotropy of manufactured parts. Oriented plastics are used everywhere from recording film to automotive body parts to monofilament fishing line. Liquid crystals are also used in a wide array of applications including their dominance in the flat panel display industry, color changing temperature sensors, and woven bullet resistant fabrics. Anisotropy can also be detrimental, for instance sometimes leading to poor fracture resistance or low yield stress along specific directions. Controlling and measuring anisotropy of materials has become increasingly important, but doing so is wrought with challenges. Measuring physical properties of isotropic liquids, such as water or most oils can be done in a straightforward fashion. Their viscosities and densities, for example, have unique values under a given set of conditions. With anisotropic fluids, like liquid crystals, the viscosity, for instance, will not only depend upon temperature, concentration, etc. but also upon the direction of observation, degree of anisotropy, source of anisotropy, and so forth. This added degree of complexity complicates our ability to define the state of the material at which the measurements are made and generally necessitates the use of more sophisticated measurement strategies or techniques. This work presents techniques and tools for investigating anisotropy in liquid crystalline and stretched polymeric systems. Included are the use of conoscopy for the determination of birefringence and orientation of nematic liquid crystals and stretched polymers, the shear response of flow aligning nematic liquid crystal monodomains, and the design of a novel linear rheometer that allows for in situ optical or scattering investigations.

Thesis (M.S.)--University of North Texas, May, 2008. / Title from title page display. Includes bibliographical references.

Ces travaux de thèse portent sur la conception, la réalisation et d'une nouvelle génération de MOEMS (Micro-Optical-Electrical-Mechanical System) pour le contrôle actif du faisceau laser émis par des matrices de VCSELs (Vertical-Cavity Surface-Emitting Lasers). Le microsystème à base de polymères que nous avons conçu est compatible avec une intégration monolithique en post-processing. Il est composé d'une membrane suspendue associée à une microlentille réfractive. Le plan de focalisation est contrôlé dynamiquement grâce au déplacement vertical de la membrane grâce à un actionnement électrothermique. La géométrie du MOEMS a été optimisée à l'aide notamment de simulations électro-thermo-mécaniques pour minimiser l'énergie de commande et fiabiliser les dispositifs. Nous avons ensuite développé l'ensemble des briques technologiques pour la fabrication collective de ce dispositif sur des matrices de VCSELs. En particulier, une technique originale de transfert thermique doux de films secs photosensibles épais a été mise au point au moyen d'un équipement de nano-impression, pour permettre un dépôt uniforme et précis sur des substrats fragiles ou de faible taille. En outre, nous avons développé un procédé simple et totalement planaire pour la fabrication du MOEMS et optimisé un procédé de dépôt par jets d'encre pour l'intégration finale des microlentilles, avec la possibilité de choisir la distance focale la plus adaptée à la fin du process. La caractérisation des microsystèmes que nous avons réalisés a conduit à l'obtention de déplacements mécaniques de 8µm pour seulement 12.5mW appliqués, ce qui constitue une validation de nos résultats de modélisation. Enfin, des premiers résultats de focalisation dynamique du faisceau VCSELs sont présentés. / This thesis deals with the study and the fabrication of a novel type of polymer MOEMS (Micro Optical Electrical Mechanical Systems) to achieve passive or active beam shaping of Vertical-Cavity Surface-Emitting Lasers (VCSELs). To improve the photonic integration of these compact laser sources in optical communication and detection systems (sensors, biomedical analysis), we designed a polymer-based optical microsystem that is suitable with a post-processing integration on VCSELs. Its operation principle is based on the out-of-plane displacement of a suspended SU-8 membrane including a polymer refractive microlens at its surface. Thanks to electro-thermal actuation, the vertical displacement of the membrane allows to dynamically modify the microlens-source distance and leads to a vertical shift of the laser beam waist position. MOEMS actuation power and reliability were optimized owing to a comprehensive tri-dimensional thermo-electro-mechanical model that takes into account SU-8 material properties and precise geometry of the device. Technological steps necessary for the collective fabrication of such MOEMS on VCSELs arrays were also developed. In particular, we report on a new photoresist film transfer method we developed to achieve a highly uniform fabrication of high aspect ratio MOEMS on small-sized or fragile samples such as GaAs-based VCSELs wafers. This method that we call "soft thermal printing" is based on the use of a thermal nano-imprint set-up. Moreover, a simple and planar process for MOEMS fabrication was successfully tested. A dedicated inkjet printing process for drop-on-demand deposition of the microlens on the membrane center was also developed. Finally, the fabricated MOEMS were characterized. A vertical displacement as high as 8µm was observed for only 12.5mW applied, in good agreement with our 3D modeling results and first results on 850nm VCSEL dynamic beam focusing were obtained, demonstrating the interest of our approach.