Thesis (M.A.)--Catholic Theological Union at Chicago, 1999. / Vita. Includes bibliographical references (leaves [118]-123).

Yes / We report the synthesis of halido Os(II) p-cymene complexes bearing bidentate chelating phenylazobenzothiazole (AZBTZ) ligands. Unlike the analogous phenylazopyridine (AZPY) complexes, AZBTZ-NMe2 is capable of both N,N-coordination to Os(II) and cyclometalation to form N,C-coordinated species. N,C-Coordination occurs via an azo nitrogen and an ortho carbon on the aniline ring, as identified by 1H NMR and X-ray crystallography of [Os(p-cym)(N,N-AZBTZ-NMe2)Cl]PF6 (1a), [Os(p-cym)(N,N-AZBTZ-NMe2)Br]PF6 (2a), [Os(p-cym)(N,C-AZBTZ-NMe2)Br] (2b), and [Os(p-cym)(N,C-AZBTZ-NMe2)I] (3b). The N,C-coordinated species is more stable and is not readily converted to the N,N-coordinated complex. Analysis of the crystal structures suggests that their formation is influenced by steric interactions between the p-cym and AZBTZ-NMe2 ligands: in particular, larger monodentate halide ligands favor N,C-coordination. The complexes [Os(p-cym)(N,N-Me2-AZBTZ-NH2)Cl]PF6 (4) and [Os(p-cym)(N,N-Me2-AZBTZ-NH2)I]PF6 (5) were synthesized with methyl groups blocking the ortho positions on the aniline ring, forcing an N,N-coordination geometry. 1H NMR NOE experiments confirmed hindered rotation of the arene ligand and steric crowding around the metal center. Complex 2b exhibited unexpected behavior under acidic conditions, involving regiospecific deuteration of the aniline ring at the meta position, as observed by 1H NMR and high-resolution ESI-MS. Deuterium exchange occurs only under acidic conditions, suggesting an associative mechanism. The calculated partial charges on 2b show that the meta carbon is significantly more negatively charged, which may account for the regiospecificity of deuterium exchange. / ERC, EPSRC, The Royal Society

The Yazoo River Basin of Mississippi includes several rivers and hundreds of floodplain lakes within an area greatly impacted by agriculture. I studied 17 of these lakes distributed over the lower half of the Yazoo River Basin to document fish assemblages and limnological patterns and to identify environmental variables that might influence these assemblages. Potential connectivity of the lake to parent river and wetland-lake area ratio in the watershed were related to the limnological conditions and fish communities. Lakes with greater potential connectivity tended to be deeper and had greater specific conductance and greater fish species richness including more riverine species. Conversely, as the potential connectivity decreased, lakes were shallower, had greater chlorophyll-a fluorescence, wetland-lake area ratio, and a less speciose lacustrine fish community. Species richness and assemblage composition of riverine species were related directly to potential connectivity. Lacustrine species assemblages were linked to wetland-lake area ratio and turbidity.

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Thesis (Th .M)--St. Vladimir's Orthodox Theological Seminary, 1988. / Includes bibliographical references (leaves 110-114).

Originally presented as the author's Thesis (doctoral)--Ludwig-Maximilians-Universität--München, 1981. / Includes bibliographical references (p. 477-499).

Thesis (DD(Kerkgesk.)--Universiteit van Pretoria, 2007. / Includes bibliographical references (leaves 391-413).

Diss.--Katholisch-Theologische Fakultät--München--Ludwig-Maximilians-Universität, 1993.

Originally presented as the author's Thesis (doctoral)--Ludwig-Maximilians-Universität--München, 1981. / Includes bibliographical references (p. 477-499).