Thesis (M.Phil.) - University of Queensland, 2006. / Includes bibliography.

From introduction: The Tasman Geosyncline covers the eastern part of the continent of Australia, an area of over 2 million km'. The area has been a major source of Australian gold and tin production, and though it contains important base metal sulphide deposits, these are overshadowed in scale by the very large stratabound Proterozoic deposits (for example, Mt Isa, Broken Hill and McArthur River). This dissertation deals with the metallic mineral deposits of the Tasman Geosyncline, and as such does not include the extensive post Palaeozoic continental successions, with their important coal reserves, that overlie the deformed geosyncl i nal sequences.

The grade of a mineral deposit is determined by the effectiveness of a geological ore forming process, which is the result of the interaction between an ore forming mechanism and the environment in which it operates. Properties of a mineral deposit controlled by ore forming processes include the distribution, density and nature of ore minerals and gangue, and the metal content and impurities of the ore minerals. More efficient ore forming processes tend to develop in the larger mineralizing systems giving rise to richer deposits. As the geological environment within which a mineral deposit evolves becomes more complex a greater number of variables interact to determine the grade of the deposit. This is reflected in the greater variability of the grade distribution, resulting in greater difficulties in obtaining reliable estimates of the recoverable grade, and increased difficulties in the processing of ores. In response to economic fluctuations the working grade of heterogeneous orebodies, that form in geologically complex environments, can often be altered to ensure the continued viability of a mining venture. In contrast the evenly mineralized orebodies that tend to develop in geologically simple environments do not have this flexibility. All the important decisions in the mining industry, such as feasibility studies, choice of ~ining and processing methods, selection and planning, are made on the basis of, or are related to, grade estimates. If the geological controls of grade are fully understood, then it is possible to optimize the selection of the various mining alternatives, leading to the efficient exploitation of ore deposits.

From introduction: The mining of porphyry type deposits accounts for about 50% of the world's present copper (Figs.I,2) and molybdenum production and resources. Mining organizations therefore invest substantial amounts of time, money and skills in the location and delineation of these types of deposit. The optimization of this investment effort is based on complex inter-relationships between geological, economic and political factors. The object of this dissertation is to review the geological and some of the economic aspects involved in the exploration and evaluation of porphyry deposits . These may hopefully provide some practical guidelines for decision making during the exploration and evaluation of such deposits. For the purpose of this dissertation, the exploration-evaluation of porphyry deposits, has been divided into three main stages:- Stage 1 : Geological mapping, interpretation of exploration drilling results and other geological factors which may help in understanding the shape and nature of the deposit. A knowledge of existing geological models for porphyry deposits will be essential in understanding the geological factors affecting tonnage and grade of these deposits Stage 2 Stage 3 (see Part I). Determination of grade-tonnage relationships. This is important in order to establish the different tonnage-grade alternatives for the deposit. Based on this, reserve estimations are calculated for different possible scales of mining. Drilling and sampling techniques, as well as statistical and preliminary economic evaluation methods are applied during this stage (see Part 2). Mine development and feasibility studies involve factors that influence type and scale of mining, and factors affecting mineral processing and extraction in relation to tonnage- grade alternatives. These factors are reviewed in Part 3.

From Chapter 1: It has been a long standing belief that many nickel sulphide ores are derivatives of magmatic processes in ultramafic and mafic rocks, and that they segregate from these magmas as immiscible sulphide droplets which are then concentrated into an orebody by gravitational settling either during intrusion or extrusion, or during the early stages of crystallization of the magma (Naldrett, 1981). Some geologists however, have suggested alternative mechanisms to explain the concentration of nickeliferous sulphides in the mafic and ultramafic hosts. These include hydrothermal replacement (Fleet, 1977), exhalative volcanic processes (Lusk, 1976), or major metamorphic upgrading of low grade, initially magmatic deposits (Barrett et al., 1977). It is not the purpose of this study to verify or disprove these hypotheses, but in so far as the initial concentration of sulphides in most deposits is concerned, these effects are relatively unimportant (Naldrett, 1981). The nickel sulphide ores associated with these mafic and ultramafic host rocks, invariably consist of nickeliferous pyrrhotite as the dominant phase, together with lesser, but variable, amounts of magnetite, pentlandite, chalcopyrite, cubanite, and platinum group elements (Reynolds, 1982).

The Olavi Mountain Land is a 10 000 km2 mineral province located at the eastern extremity of the exposed Northern Platform of the Damara Pan African orogenic belt. The Olavi Mountain Land is tbe most important mineral province on the Northern Platform. Exploitation of tbe Cu-Pb-Zn-V province has been on-going since the possession of the territory by the German colonial authority in 1890. Production has been mostly from four mines which in order of importance are Tsumeb, Kombat, Berg Aukas and Abeoab. A second mineral province on the Northern Platform located in the west is centred on Sesfontein where as yet only insignificant mineralization has been noted. Besides these localities, the Northern Platform is conspicuously devoid of notable mineralization. The aim of this thesis has been to document tbe Berg Aukas deposit, an important end-member type of mineralization in the Otavi Mountain Land. The basic premise bas been to show tbat the derivation and localization of the mineralization is a consequence of two broad controls which can be simply summarised as features of the basement and of the carbonate sequences. The geodynamic evolution of the Damara Belt commenced with intra-continental rifting approximately 900 Ma ago. Rift grabens trending north-east were filled by the Nosib Group which comprises mostly clastic lithologies but also some volcanics. The earliest and largest rift is referred to as the Northern Rift. Separation of the Congo, Kalahari, and proto-South American cratons resulted in rifting and rapid downwarping so that an encroaching sea and an Olavi Group carbonate shelf developed along the northern margin of the Northern Rift. Significantly, the carbonates only covered the Northern Rift in the area of the Otavi Mountain Land where a basinal dome, referred to as the Grootfontein Basement High, marked the basin edge. In the west, the carbonates covered the less important Sesfonfein Rift, and it is only in these two areas where Nosib sequences underlie the carbonate platform. Carbonate sedimentation was interrupted by a major period of crustal readjustment and the deposition of an extensive mixtite throughout the geosynclinal Swakop Trough and Northern Platform. This is referred to as the Chuos Formation and subdivides the Olavi Group into a lower Abenab and an upper Tsumeb Subgroup. Reversal of spreading led to plate collision and subduction of tbe Kalahari craton beneath the Congo craton. It was accompanied by orogenesis which resulted in F1 folding of the Northern Platform into a series of north-easterly trending intermontane basins into which a molasse sequence known as the Mulden Group was unconformably deposited. Following this major north-south deformation mild east-west compression initiated F2 folding and the formation of doubly plunging synclines. The Berg Aukas Syncline represents a primary depositional basin which was subsequently folded. The original basin was formed by late Nosib rifting wben spreading caused the Swakop geosynclinal Trough to form. Carbonates of the basal Berg Aukas Formation were deposited in a lagoonal setting typified by reef and fore-reef facies witb peri-platform conditions. Rapid subsidence caused these sediments to be overlain by deep water carbonates of the Gauss Formation. Two styles of mineralization known as the Tsumeb-type and Berg Aukas-type are stratigraphically, isotopically, and mineralogically distinct. The Tsumeb-type is a cupriferous variety of discordant bodies confined to the upper sequences beneath the Mulden unconformity. The Berg Aukas-type is a Zn-Pb variety confined to tbe basal unconformity. The Berg Aukas deposit comprises three ore bodies known as the Northern Ore Horizon, the Central Ore Body, and the Hanging Wall Ore Body. Sphalerite and galena constitute the bypogene ore. Willemite, smithsonite, cerussite, and descloizite are important supergene ores. A review of genetic models concludes that a magmatic origin initially proposed for tbe Tsumeb deposit is entirely rejected and a basin dewatering model in line with Mississippi Valley-type deposits is proposed. The syntectonic nature of mineralization at Berg Aukas and elsewhere in the Otavi Mountain Land indicates that orogenesis encouraged dewatering and leaching of metals from a broad mineralizing front along the margin of the Swakop Trough. These were transported by acidic saline brines which migrated along the clastic aquifers and structural conduits provided by the Northern Rift. Fluid inclusion studies indicate that the hydrothermal fluids at Berg Aukas were very saline (23% TDS) and were transported at temperatures ranging between 92° to 210°C. Hydrothermal fluids which mineralized Berg AukaS-type deposits migrated along the basal unconformity towards the basement high and were responsible for hydrothermally altering the basement granites and gabbros and the Nosib clastic rocks. Tsumeb-type deposits resulted by migration of fluids through the carbonate pile and along north-easterly trending basement geofractures. As a consequence of variation in transport, the Berg Aukas-type and Tsumeb-type fluids leached different sources and therefore derived mineralogically and isotopically seperable characteristics. The localization of the Berg Aukas ores was controlled by the carbonate stratigraphy and structure. Hydrothermal karsting and ore deposition took place on the contact between Massive Grey and Light Grey Dolostones which represents a permeability contrast. The movement of the hydrothermal fluids was controlled by north-south trending vertical fractures caused by F2 folding which resulted in a peric1inal structure. Hydrothermal karsting was accompanied by ca1citic, dolomitic and silicic alteration. The heated acidic fluids initiated solution collapse and a variety of breccia types. Supergene processes resulted in oxidation and upgrading of the ore. Vanadium derived indirectly from gabbros in the basement complex were transported as calcium metavanadate complexes and deposited on contact with the oxidizing base metal sulphides.

In the last two decades much has been published on the behaviour of certain elements in the magmatic , hydrothermal, sedimentary and weathering environments , but the information is scattered throughout the literature . This situation prompted the present study on the elements Ni, Co, Cu, Pb , Zn , Au, Ag , Mo , Sn, W and U. The behaviour of the elements Ni, Cu, Pb , ZN, Au, Sn , W and U has been studied experimentally in some depth. Ag has been moderately studied, but there is very little information about Co and Mo. Studies on the complexes formed by the elements within the hydrothermal and aqueous environment are often inconclusive and controversial , but conclusions are drawn as to the more likely complexes formed . A genetic classification of ore deposits is used as a framework for the discussion . The source of the elements is regarded as being the mantle, and therefore discussion on other possible sources is beyond the scope of this dissertation. The crystal chemistry and geochemistry of the elements are presented and the essay concludes with a discussion on the elements within their depositional environments

Stratiform and stratabound ore deposits commonly show a direct relationship with rifts. This association is studied by developing a geodynamic model of mantle processes and crustal responses. The geodynamics of the earth can be modelled by the process of mantle advection, which involves the episodic generation and segregation of low density mantle diapirs and their rise and subsequent interaction with the crust. The theory of mantle advection explains the genetic association between rifting, magmatism, basin development and subsequent orogeny and metamorphism. Global evolution has passed through a number of major stages of non-uniformitarian development in which each cycle was characterized by fairly uniform behaviour terminated by intense geodynamic upheaval. The relationship between geological evolution and mantle advection is examined by reviewing the major characteristics of each of the cycles, which correspond to the Archean, Early Proterozoic, Mid Proterozoic, Late Proterozoic-Palaeo2oic, and Mesozoic - Cainozoic eras. Although mentle advection has controlled crustal processes throughout time, the decrease in the thermal energy of the earth has caused >the major evolutionary changes in response to thickening and a greater rigidity of the sialic crust. Rifts are penetrative taphrogenic faults in the earths crust which act as major conduits for the transfer of magmas, from the mantle and lower crustal levels, to the upper crust and the surface. Rifts are also permeable zones for the migration of metalliferous brines, generated by magmatic differentiation. These metalliferous brines would either be exhaled at surface to form stratiform volcanogenic and volcanosedimentary ore deposits , or would interact with preferential host horizons to form stratabound ore deposits . The associat ion between rifting and stratiform and stratabound ore deposits is illustrated by examining :he tectonic setting, and st ratigraphic relationships of typical ore deposit types .

No description available.

Many conceptual models have been proposed to explain the fluid-flow mechanism responsible for the origin of carbonate-hosted lead-zinc deposits such as those in the Mississippi Valley and at Pine Point. This study is devoted to the quantitative investigation of one ore-genesis mechanism: gravity-driven groundwater-flow systems. Numerical modeling techniques are used to develop a self-contained computer code for two-dimensional simulation of regional transport processes along cross sections through sedimentary basins. The finite-element method is applied to solve the steady-state, fluid-flow and heat-transport equations, and a moving-particle random-walk model is developed to predict the dispersion and advection of aqueous components. The program EQ3/EQ6 is used to compute possible reaction-path scenarios at the ore-forming site. Full integration of geochemical calculations into the transport model is currently impractical because of computer-time limitations. Results of a sensitivity analysis indicate that gravity-driven ground-water-flow systems are capable of sustaining favorable fluid-flow rates, temperatures, and metal concentrations, for ore formation near the thin edge of a basin. Dispersive processes render long-distance transport of metal and sulfide in the same fluid an unlikely process in the genesis of large ore deposits, unless metal and sulfide are being added to the fluid along the flow path. The transport of metal in sulfate-type brines is a more defensible model, in which case the presence of reducing agents control the location of ore deposition. Hydrodynamic conditions that could result.--in ore formation through mixing of two fluids are rare. The theoretical approach is a powerful tool for gaining insight into the role of fluid flow in ore genesis and in the study of specific ore districts. A preliminary model of the Pine Point deposit suggests paleoflow rates on the order of 1.0 to 5.0 m³/m² yr, paleoconcentrations of zinc on the order of 1.0 to 5.0 mg/kg • H₂O, and paleotemperatures in the range 60°C to 100°C. Under these conditions, the time required for the formation of Pine Point would be on the order of 0.5 to 5.0 million years. / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate