Les lignes à grande vitesse sont considérées comme une source importante de perturbations environnementales qui sont de moins en moins tolérées par les habitants. Afin de comprendre la dynamique de ces systèmes, il est important de développer des modèles numériques pour simuler les problèmes de vibration véhicule/voie ferrée et comprendre les interactions de la voie ferrée et des composants du véhicule. Une nouvelle approche basée sur la mise à jour périodique de la configuration « Méthode PCU » est d’abord proposée pour l’évaluation de la réponse dynamique des poutres infinies continuellement supportées sous charges mobiles à grande vitesse. La méthode PCU est utilisée pour évaluer la réponse dynamique d’un système simplifié voie ferrée/sol dans lequel la fondation du rail est remplacée par une couche viscoélastique continue. D’autre part, une modélisation numérique 3D considérant le couplage dynamique mutuel complexe entre les composantes de la voie ferrée et la couche du sol est développée. Un schéma de maillage adaptatif est appliqué pour simuler l’effet des charges mobiles ; il est représenté par la création des nœuds mobiles attachés aux charges. Cette modélisation est appliquée avec succès dans la gamme de vitesses sub-Rayleigh et super-Rayleigh. Dans la dernière partie, la modélisation numérique 3D est utilisée pour calibrer les impédances dynamiques du modèle simplifié proposé dans le premier chapitre. Une procédure itérative d’ajustement de courbe est réalisée à l’aide de l’algorithme génétique. Des lois constitutives qui régissent le comportement dynamique des éléments discrets sont proposées aux différentes fréquences de chargement et gamme de vitesses. / The high speed lines are considered as an important source of environmental disturbance that are less and less tolerated by inhabitants. In order to understand the dynamics of these systems, it is important to develop numerical models to simulate the vibration problems vehicle/track and understand the interactions of the track and vehicle components. A new approach based on periodic configuration update “PCU method” is firstly proposed for the assessment of the dynamic response of continuously supported infinite beams under high speed moving loads. The PCU method is used to assess the dynamic response of a simplified track/ground system in which the rail foundation is replaced by a continuous viscoelastic layer. On the other hand, a 3D numerical modeling that considers the complex mutual dynamic coupling between the track components and the subgrade layer is developed. An adaptive meshing scheme is applied to simulate the moving loads effect; it is represented by the creation of load-attached moving nodes on the rail-beam. This modeling is successfully applied in the sub-Rayleigh and super-Rayleigh velocity range. In the last part, the 3D numerical modeling is used to calibrate the dynamic impedances of the simplified beam model proposed in the first chapter. An iterative curve fitting procedure is carried out using the genetic algorithm. Constitutive laws that govern the dynamic behavior of the discrete elements are proposed at different load frequency and velocity range.

Rice (Oryza sativa L.) that is grown in the U.S. is predominantly grown in the mid-south. Current Mississippi State University recommendations for nitrogen (N) fertilization of rice suggest a single application of 168 kg N ha-1 on soils with CEC ¡Ü 20 and 202 kg N ha-1 on soils with CEC > 20. The primary objective was to identify alternative N management strategies that may potentially be used to reduce costs associated with aerial application of N fertilizer to rice. Research was established at the Delta Research and Extension Center, at Stoneville, MS, on two soil textures during 2015 and 2016. The combination of application timings and N sources resulted in a total of eight N management strategies. Data from all siteyears were pooled together for analysis to evaluate differences among N management strategy. Urea + [N-(n-butyl)thiophosphoric triamide] (NBPT) applied in a single application 7 days before flood (DBF), two-way split application, and PCU-2 LF produced statistically similar and greatest mean rice grain yield. These data suggests that N fertilizer can be applied early (2 to 3 leaf growth stage) from a ground based fertilizer spreader prior to the levee construction. Single optimum and two-way split N management strategies produced more total dry matter (TDM) at heading (HDG) and more N uptake at HDG. Urea + NBPT applied in a single application 7 DBF should be the N management strategy of choice in mid-southern U.S. rice production.

Baeyer-Villiger oxidation of 1-methylpentacyclo[5.4.0.02,6.03,10.05,9] undecane-8,11-dione, performed by using m-chloroperbenzoic acid in 1:1 molar ratio, resulted in the formation of monolactone. The corresponding dilactone, was synthesized by reacting 1-methyl-PCU-8,11-dione with m-chloroperbenzoic acid in 1:2 molar ratio. 6-Methyl-1,4,4a,8a-tetrahydro-1,4-methanonaphthalene-5,8-dione was converted into the corresponding exo-6,7-monoepoxide via treatment with 30% aqueous hydrogen peroxide. Epoxidation of this monoepoxide by using m-chloroperbenzoic acid afforded the corresponding bis-epoxide. Ceric ammonium nitrate (CAN) promoted oxidation of 1-methyl-PCU-8,11-dione afforded "methylated lactones" and a "methylated alkene."

Baeyer-Villiger oxidation of 1,9-dibromopentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione (1,9-dibromo-PCU-8,11-dione) was performed by using an excess amount of m-chloroperbenzoic acid (3 equivalents) and resulted in the formation of the corresponding monolactone. The reaction would not proceed to the dilactone stage. The structure of the reaction product was established unequivocally via single crystal X-ray diffraction. Baeyer-Villiger oxidation of 1,9-dibromo-PCU-8,11-dione using ceric ammonium nitrate (CAN) was also performed and afforded a mixture of lactones. Only one of these lactones, which also contained an alkene functionality, could be isolated and characterized. 1,7-dibromo-PCU-8,11-dione was also reacted with CAN, yielding the mono-lactone, which has also been characterized.

Conversion of 1-Methylpentacyclo[5.4.0.0²⋅⁶.0³⋅¹⁰.0⁵⋅⁹]undecane- 8,11-dione into the corresponding mono(ethylene ketal) followed by Wolff-Kishner reduction resulted in a mixture of two isomers (i.e., 1- and 7-methyl-8-[2',-(1',3',dioxolano)]pentacyclo[5.4.0.0²⋅⁶.0³⋅¹⁰.0⁵⋅⁹] undecane. Hydrolysis of each isomer in turn resulted in 1- and 7- methyl pentacyclo[5.4.0.0²⋅⁶.0³⋅¹⁰.0⁵⋅⁹ ]undecan-8-ones (i.e.,"methylated PCU-8-ones"), respectively. "Titanium-promoted reductive dimerization of each of the methylated pentacycloundecane (PCU)-8-ones afforded mixtures of "methylated PCU alkene dimers". Individual isomers have been isolated from these mixtures via column chromatography by using silver nitrate impregnated silica gel as adsorbent followed by fractional recrystallizations of individual chromatography fractions. Structures of three isomerically pure methylated PCU alkene dimers (C₂₄H₂₈) have been established unequivocally by application of single crystal X-ray crystallographic methods.

The 4Rs of nutrient management is a global agronomic initiative with an aim to improve the sustainability of major cropping systems and the environment. The objective for this project is to evaluate individual and stacked 4R management practices and how they intersect. A field trial near Grace, Idaho was conducted on potato (Solanum tuberosum L.) in 2020 and 2023. Nitrogen (N) fertilizer treatments included all combinations of two sources [urea or polymer coated urea (PCU)], two rates (82 or 100% of the recommended rate), and/or two timing/placements (all applied at emergence or 84% at emergence + 16% fertigation simulation) compared to an untreated control. Overall, potato was responsive to N for petiole nitrate (NO3-N), Normalized Difference Vegetative Index (NDVI), and US No. 1 and marketable tuber yield. There were large numerical yield increases for most treatments compared to the unfertilized control in both years (2.2-8.2 Mg ha-1), though statistical significance for multiple yield classes was only reached in 2023. Treatments with PCU had a significant increase in US No. 1, US No. 2, and marketable yield over urea. The split application timing resulted in larger tubers and less cull yield in 2020 with little impact on yield and quality in 2023. The reduced rate negatively impacted US No. 1 and marketable yield while increasing cull yield, though not when applied as PCU. This data reinforces the 4R principles and suggests that stacking some methods may not be necessary.

No description available.

Part I. The syntheses of a series of stable ferrocenylsilane compounds and their corresponding polyradical cations are reported. Electron spin properties of these molecules were investigated by cyclic voltammetry, ESR, and magnetic susceptibility measurements. All the compounds presented, showed significant electronic communication (>100 mV) between the redox centers by CV. Part II. Baeyer-Villiger oxidation of (1,9-dimethyl-PCU-8,11-dione) was performed using m-chloroperoxybenzoic acid in 1:2 molar ratios. The product obtained was the corresponding dilactone 113. The structure of the reaction products was established unequivocally via single crystal X-ray diffraction methods. The reaction of the 1,9-dimethyl-PCU-8,11-dione with 1:1 molar ratio of m-chloroperoxybenzoic acid produced again the dilactone 113, and not the expected monolactone 114. Ceric ammonium nitrate (CAN) promoted oxidation reaction of 1,9-dimethyl-PCU-8,11-dione afforded a mixture of dimethylated lactones, which indicated unique reaction mechanism pathways. These individual isomers, 115 and 116, have been isolated from these mixtures via column chromatography by using silica gel as adsorbent followed by fractional recrystallization of individual chromatography fractions. Structures of these pure products have been established unequivocally by application of single crystal X-ray crystallographic methods.

Nitrogen (N) is the most commonly over-applied nutrient in urban environments because of the large visual and growth increases. This over-application has led to an increase in the loss of N gas in the forms of ammonia and nitrous oxide, as well as an increase in nitrate leaching to surface and groundwater. Furthermore, excess N results in increased maintenance costs and landfill volume due to increased shoot growth from mowed clipping removal. Polymer coated urea (PCU) has proven to be an excellent source to these losses of N to the environment, but rate and timing parameters need study. A two-year field study, on sand and sandy loam soils in Provo, UT, was initiated in April 2014. Seven fertilized treatments included: urea split applied monthly; a single application of PCU (Agrium One Ap) applied in spring, a single PCU application in fall; two evenly split applications in spring and late summer; and three evenly split applications in spring, late summer, and late fall. These were compared to an untreated control. In addition the two application of PCU also had reduced rates of half and three-quarters, in addition to the full rate. Height and verdure measurements were taken on a weekly basis, along with periodic visual and biomass readings. All fertilized treatments resulted in a significant response to N as compared to the control. The single annual application treatments had significantly greater shoot growth during the weeks immediately after application and a significant reduction in verdure months later and, therefore, were unacceptable for consumer recommendation. Two applications of PCU, either at the three-quarter or full rates, were nearly identical in all measurements as compared to the spoon feeding of urea applied monthly. The half rate of two applications showed signs of inadequate N. Three applications of PCU was identical to two and, therefore, not recommended. This study shows two applications of PCU at the three-quarter rate is equally effective as spoon feeding the N. Doing so would result in less labor for fertilization. Further work is needed to evaluate other timing approaches for a single annual application, as well as long term effects of a reduced rate of N.

Plants require N to complete their life cycle. Without adequate concentration of N, crops will not produce their potential yields. For turfgrass systems, N fertilizer application allows for the maintenance of functional, aesthetic, and recreational properties. However, fertilizer mismanagement is common and leads to N pollution in the environment. Controlled-release and slow-release fertilizers can enhance nitrogen (N)-use efficiency, reduce N pollution, minimize the need for repeated fertilizer applications, and reduce turfgrass shoot growth and associated costs. In order to evaluate the effectiveness of these fertilizers in the Intermountain West, research is needed. The timing of N release was evaluated for seven urea fertilizers: uncoated, sulfur coated (SCU), polymer-sulfur coated (PSCU), and four polymer-coated (PCU) with release timings of 45, 75, 120, and 180 d estimated release. These products were placed on bare soil, a Kentucky bluegrass (Poa pratensis L.) thatch layer, and incorporated into soil. These three placement treatments were replicated to allow for enough samples to be placed in two locations. The first was outside in a field to represent field conditions with diurnal fluctuating temperatures and the second was placed in a storage facility to replicate laboratory conditions with static diurnal temperatures. The PCU prills incorporated into soil under field conditions generally released N over the estimated release period. However, when applied to bare soil or thatch, N from PCU had 80% or greater N release by 35 d after application regardless of expected release time. Fertilizers under laboratory conditions had minimal N release despite having similar average daily temperatures, suggesting that fluctuating temperatures impact N release. The PSCU and SCU treatments were no different from uncoated urea, showing no slow release properties for this particular product. Spring-applied N fertilizer trials were conducted over two years to determine the optimal N rate for Kentucky bluegrass. Similar PCU120 products were applied at 50, 75, and 100% of the recommended full rate, while also being compared to an unfertilized control and urea applied either all at once or split monthly. Spring-applied PCU showed minimal initial N response while urea applied all at once resulted in an initial spike of N uptake. Once PCU began to release N, there was minimal difference for all rates compared to urea split monthly for biomass growth, verdure, and shoot tissue N. Although at the 50% rate, there were a few sampling dates with slower growth and lower verdure. The decrease in verdure at this low rate was slight, and it is recommended that PCU could be applied effectively at a reduced rate between 50 and 75%. Although for better results, additional quick release N is required to compensate for early season lag in N release.