The separation of four or more components traditionally requires the use of three or more distillation columns. Due to the associated high costs, process intensification techniques have been studied. Semicontinuous separation is one method that allows multiple separations using one column integrated with middle vessels. This thesis aims to develop a new semicontinuous separation process that can separate a mixture with four or more components into high purity products with one column and two or more middle vessels. It is an extension of the conventional ternary semicontinuous process, which has been repeatedly shown to be profitable at intermediate throughputs when compared to continuous systems. The semicontinuous process operates in a forced cycle, with three operating modes that ensure separation objectives are met. The performance of the proposed quaternary semicontinuous separation is analyzed through rigorous dynamic simulations over a range of production capacities. To determine the feasibility, operability, and applicability to non-ideal mixtures, three case studies were considered: 1. Equimolar mixture of alkanes (n-hexane; n-heptane; n-octane; n-nonane). 2. Equimolar mixture of aromatics (benzene; toluene; ethyl-benzene; and o-xylene). 3. Non-ideal mixture of mixed-alcohols (methanol, ethanol, and water; propanol; isobutanol; pentanol and hexanol) The extendibility of the quaternary semicontinuous separation process, referred to as quintenary semicontinuous separation, is then evaluated on a five-component alkane mixture (n-hexane; n-heptane; n-octane; n-nonane; n-decane), via three case studies: 1. Equimolar mixture 2. Non-equimolar mixture, rich in light and heavy components. 3. Non-equimolar mixture, rich in intermediate components. The results for both the quaternary and quintenary semicontinuous processes indicate that this new technique is successful at achieving separation objectives while staying within safe operating limits. Comparison of both equimolar mixtures of alkanes for quaternary and quintenary semicontinuous processes with continuous systems indicates that the proposed system is profitable for intermediate flow rates. / Thesis / Master of Applied Science (MASc) / Traditionally, several large distillation columns (that can be hundreds of feet tall) are required to split a mixture of liquid chemicals into its individual components. Distillation is the separation of mixtures due to differences in boiling points. When the mixture is heated, the vapour phase will contain the components with lower boiling points, which can be separated once the vapour phase is cooled and condensed. The main goal of this research is to create a new system that can carry out the same separation, but using complex techniques that require only one column and a few extra storage tanks that are much cheaper and smaller than a distillation column. Different liquid mixtures were used to show how well the new process is able to separate the liquid into its individual components, while remaining in safe operating limits.

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Aevitas is an industrial wastewater treatment plant that receives about 300 m3/day of mixture of wastewater from different industries. The chemical oxygen demand of higher 600 ppm and the variety of the chemical constitution of industrial wastewater are two significant problems on Aevitas. Therefore, there is a strong need for developing advanced analytical techniques that can identify the specific compounds that are the source of COD. During 10 months, about 75 industrial samples were characterized using a battery of tests including GC/MS, COD, TOC, and pH to identify the chemicals that are main source of COD in the industrial wastewaters. Results showed that the COD of 87% of 75 provided samples from Aevitas plant was higher than 600. At the first step of process design, activated carbon was used to eliminate the identified organic chemicals from the wastewaters. The maximum and minimum of COD removal (depends on the chemical composition) of the wastewaters were obtained as 94 and 24%, respectively. Moreover, the amount of COD and TOC that can be adsorbed on the surface of 1 gram of the activated carbon were 25 and 7 mg, respectively. Although activated carbon is capable to reduce the COD, its capacity of adsorption is limited. To overcome this problem an alternative process, membrane filtration was applied for COD removal. Two types of crossflow NF (NF270, NF90, NFX, NFW, NFS, TS80, XN45, and SXN2_L) and RO (BW60 and TW30) membranes in two modules of the spiral wound and flat sheet were used. The filtration results of 11 different industrial wastewaters showed that NF90, TS80, NFX, and NFS were effective in COD removal. However, in terms of output flux NFX and NFS flat sheet were better than others were. Similar to the activated carbon process, the COD removal in filtration process was between 30 and 90%. The obtained results can be used to scale up the membrane filtration process at Aevitas. / Thesis / Master of Chemical Engineering (MChE) / Aevitas is an industrial wastewater treatment plant, which is situated at the City of Brantford. Every day, this plant receives about 15 trucks of the mixture of wastewaters from many different industries. The input wastewater into the plant should be treated and meet the environmental standard so that it can be discharged into a municipal wastewater plant. Currently, the maximum allowable chemical oxygen demand (COD) for discharging the treated wastewater from Aevitas to the municipal wastewater treatment plant is 600 ppm. Despite the fact, the current system in Aevitas is not efficient to meet this criterion. Thus, we strive to design efficient processes to overcome the problem. To this end, 75 samples were collected from Aevitas to observe the kind of chemicals that are the source of COD and then, two processes including activated carbon adsorption and membrane filtration were used for further reduction of COD. Although activated carbon can reduce the COD, the limited adsorption capacity was a major concern for its long-term application, especially if the COD of influent wastewater is higher than 2000 ppm. Membrane filtration was used as an alternative for activated carbon and the results showed that membrane could reduce the COD below 600 in 48% of the cases.

Fine particle separation is a grand challenge in the mining and mineral processing industry. The industry standard process, froth flotation, is extremely robust and adaptable; however, it is inefficient for particles less than 20 microns. Owing to this limitation, some mining sectors, such as coal, opt to discard the ultrafine particles to waste impoundments as the costs to recover and dewater these materials are prohibitive. The Hydrophilic Hydrophobic Process (HHS) is one alternative to flotation that uses a recyclable solvent, rather than air bubbles, to selectively recover fine hydrophobic particles. Prior laboratory, proof-of-concept, and demonstration-scale testing has shown that the HHS process is extremely efficient, having no effective size limitation. The purpose of this research was to continue the development and improvement of the HHS process, through the design, construction, and testing of a mobile pilot plant. The pilot plant would in turn be used to demonstrate the robustness of the HHS process through a systemic study of multiple coal sources and ranks. In addition, the pilot plant would serve as a testbed for inquiry-based process intensification, the development and evaluation of design criteria for the various unit operation. Through the course of this research, a 50 lb./hr. (product rate) pilot plant was constructed and commissioned. Initial investigations focused on the shakedown and design of key unit operations, including the agglomeration and de-emulsification (i.e. Morganizing) steps. Studies showed that the initial design of these units, namely pump induced mixing in agglomeration and packed bed emulsification in the Morganizer, were not adequate to meet production demands, and as such, these stages were redesigned after appropriate fundamental evaluations. After implementing the design changes, the pilot plant was successfully operated over a 7-month period, routinely producing bituminous products with less than6% ash and less than 10% moisture as well as anthracite products with less than 3% ash and less than 4% moisture. This study also evaluated a new approach to de-emulsification using a jig based Morganizer in place of the standard oscillating column Morganizer. The jig utilizes a pulsing mechanism to move liquid to break up agglomerates versus the mechanical disk stack. Preliminary results showed that the jig Morganizer was comparable to the oscillating unit at more than half the size. This new design provides a pathway for reduced cost, footprint, and improved scalability. Lastly, this study evaluated both the HHS process and dual-scan X-ray based particle sorting as means of increasing the REE content of coal-based materials. Data from a pilot-scale x-ray sorter showed the unit was capable of preconcentrating REEs to over 300 ppm, while data from the HHS similarly showed the process was capable of REE recoveries of 85-90% and of preconcentrating REEs above 300 ppm. Altogether, these results indicate That both of these technologies are capable of efficiently and cost effectively preconcentrate REEs from wastes streams at operating coal preparation plants. / Doctor of Philosophy / The mining sector has traditionally been a large producer of waste, with the vast majority of this waste being ultrafine particles that are unable to be recovered using conventional technologies. These particles are often disposed of in large surface impoundments, which are an environmental and social liability in many mining districts. This study has evaluated a novel method of fine particle separation, the hydrophobic-hydrophilic separation (HHS) process. The HHS process uses a recyclable oil to selectively agglomerate fine particles, which are subsequently dispersed and recovered. The oil is then filtered and recycled within the process creating an approach that is both efficient and environmentally friendly. In this study, a mobile pilot HHS plant was constructed and tested, with the results showing that the HHS can effectively recover fine carbon from waste coals, thus turning an environmental liability into a potential value stream for high-end applications. In addition, the study showed that the process can be further improved to reduce costs while improving overall efficiency. Overall, this study has provided the data needed to further commercialize the HHS process. If widely deployed, the HHS process has the potential to both reduce the current amount of waste fines being generated and reclaim the existing impoundments.

In the field of sustainable architecture, transformability is an important way of actively responding to ambient conditions while also meeting the needs of occupants and addressing issues of building performance. This research contributes knowledge for architects about the potential of kinetics for the shading system to respond effectively to changes in its environment. Within contemporary architecture, there is a growing interest in motion; buildings and their parts are gradually shifting from static to dynamic. However, contemporary activities in architecture are evidence of a lack of a holistic approach to the design of motion in architecture and the design of motion as an alternative mode of design thinking is still in its infancy. Consequently, the existing tradition of static forms being the sole forms taught in architectural studies should be reevaluated as a design strategy. This research is a step in the direction of better understanding the key knowledge exchanges within the design process of transformable shading systems. It will seek to investigate, explore, and propose how the concept of transformability in designing shading systems can be suggested, depicted, or physically incorporated in building envelopes. In order to get the full potential of the design process of transformable shading systems, this study presents a design workflow of a specific case, called AURA, that helps to create openings for establishing a proper design methodology of transformable shading systems. While the workflow will be concerned with identifying the key decision nodes, it is anticipated that in-depth development will determine critical parameters addressing transformation itself as a design parameter of transformable shading systems. Two studio-based courses offered at Virginia Tech and Texas AandM by the author will become a testing ground for evaluating the key decision nodes found in the design process of AURA within the context of architectural programs, bringing forth the opportunity to expand the current domain of transformable shading systems to a broader perspective of architecture pedagogy. In this case, this research is a step towards adding values directly into the content of the curricula, and thus into the field of design education as a whole.' / Ph. D.

Waste from construction and demolition-building activities is increasing every day. Landfills have almost reached their capacity. When thinking about the negative impact of demolishing activities on the environment it becomes very necessary to think about reusing and recycling building materials in new construction or perhaps better recycling our thoughts on how to make use of waste materials. In Kevin Lynch's book, Wasting Away, he wrote: "Architects must begin to think about holes in the ground and about flows of materials." Studies show that construction and demolition activities are the primary source of solid waste worldwide. For example construction and demolition wastes constitute about 40% of the total solid waste stream in the United States. The growing interest in materials and resource conservation in the United States is inherent in the growth of green building practices. The USGBC identifies six categories in the Materials and Resources (MR) section of LEED. One of these six categories is Resource Reuse (RR). Interestingly enough, a recent study about the cost of green buildings indicated that RR was the category credits least often achieved in most LEED certified projects. Literature suggests that there are a number of constraints and barriers to resource reuse primarily due to the complexity of buildings but perhaps the most important barrier, according to many architects, is the lack of easily accessible information to the design team on resource reuse. Therefore, as we promote the idea of building material reuse to a wider audience of designers and architects, we mus not forget that in the Architecture, Engineering and Construction (AEC) industry, both Reuse and Recycle terms are used interchangeably without yet a clear distinction between them. The use of arbitrary descriptions to distinguish reuse from recycle has caused nothing but more confusion to the public. This study argues that the real distinction between reuse and recycle exists in Knowledge and Information. This suggests that design with reuse requires a paradigm shift in the required knowledgebase and the way information flows within the design process. Unfortunately, the structure of this paradigm shift is not known and has not been well defined. Since knowledge forms the core of building a Decision Support Systems (DSS) for a design team in order to consider reuse, it is necessary to capture the required knowledge and information from the industry experts through a Knowledge Acquisition (KA) process. This knowledge can then be used to 1) identify the building material reuse criteria and 2) to build a prescriptive decision model and 3) to map the process design of the current traditional architectural design workflow and the proposed one. The overarching goal of this study is to use the building material reuse knowledgebase for 1) building a Unified Virtual Repository database to be connected to all available physical repositories and share a unified standard of information. 2) When the unified virtual repository is integrated with the Building Information Modeling (BIM) database, the DSS can work as a feedback and feed forward support for architects and designers as they consider building material reuse in new designs and constructions. / Ph. D.

Thesis (MScEng (Civil Engineering))--University of Stellenbosch, 2008. / Thesis presented in partial fulfilment of the requirements for the degree of Master of Science in Civil Engineering at the University of Stellenbosch. / ENGLISH ABSTRACT: The logical scheduling of activities in an engineering project currently relies heavily on the experience and intuition of the persons responsible for the schedule. In large projects the complexity of the schedule far exceeds the capacity of human intuition, and systematic techniques are required to compute a consistent sequence of activities. In this study a simple model of the engineering process is described. Based on certain specified relationships between components of the model, a consistent sequence of activities is determined in the form of a logical step schedule. The problem of resource constraints receives special attention. Engineering projects are often executed with limited resources and determining the impact of such restrictions on the logical step schedule is important. This study investigates activityshifting strategies to find a near-optimal sequence of activities that guarantees consistent evolution of deliverables while resolving resource conflicts within the context of logical step schedules. / AFRIKAANSE OPSOMMING: Die logiese skedulering van aktiwiteite in ‘n ingenieursprojek steun swaar op die ondervinding en intuisie van die persone wat verantwoordelik is vir die skedule. In groot projekte is die kompleksiteit van die skedule veel hoër as die kapasiteit van die menslike intuisie, en sistematiese tegnieke word benodig om ‘n konsekwente volgorde van aktiwiteite te bereken. In hierdie studie word ‘n eenvoudige model van die ingenieursproses beskryf. Gebasseer op sommige relasies tussen komponente van die model, kan ‘n konsekwente volgorde van aktiwiteite bepaal word in die vorm van ‘n logiese stap-skedule. Die probleem van beperkte hulpbronne ontvang spesiale aandag. Ingenieursprojekte word dikwels uitgevoer met beperkte hulpbronne en dit is belangrik om die impak daarvan op die logiese stap-skedule te bepaal. Die studie ondersoek die gebruik van aktiwiteit-skuiwende strategieë om ‘n nabyoptimale volgorde van aktiwiteite te vind wat konsekwente ontwikkeling van die projekprodukte waarborg, terwyl hulpbron konflikte opgelos word binne die konteks van ‘n logiese stap-skedule.