In situ chemical oxidation using permanganate is an increasingly employed approach to organic contaminant remediation at hazardous waste sites. Manganese dioxide (MnO2) particles form as a by-product of the reaction of permanganate with contaminants and naturally-reduced subsurface materials. These particles are of interest because they have the potential to deposit in the subsurface and impact the flow regime in/around permanganate injection, including the well screen, filter pack, and the surrounding subsurface formation. Control of these particles can allow for improved oxidant injection and transport, and contact between the oxidant and contaminants of concern. Sodium hexametaphosphate (HMP) has previously been identified as a promising aid to stabilize MnO2 in solution when included in the oxidizing solution, increasing the potential to inhibit particle deposition and impact subsurface flow. The goal of the experimental studies described herein was to investigate the ability of HMP to prevent particle deposition in transport studies using four different types of porous media. Permanganate was delivered to a contaminant source zone (trichloroethylene) located within four different media types with variations in sand, clay, organic carbon, and iron oxides (as goethite) content. Deposition of MnO2 within the columns was quantified with distance from the source zone. Experiments were repeated in replicate columns with the inclusion of HMP directly with the oxidant delivery solution, and MnO2 deposition was again quantified. While total MnO2 deposition within the 60 cm columns did not change significantly with the addition of HMP, deposition within the contaminant source zone decreased by 25-85%, depending on the specific media type. The greatest differences in deposition were observed in the goethite-containing and clay-containing columns. Columns containing these two media types experienced completely plugged flow in the oxidant-only delivery systems; however, the addition of HMP prevented this plugging within the columns, increasing the oxidant throughput.

The use of chemically compatible nano and fine particle colloidal consolidants is a new development within the field of cultural heritage conservation and applied most widely so far to the historic built environment. The ability to introduce a significantly higher quantity of chemically compatible consolidant to a substrate in fewer treatments with the possibility for greater penetration and fewer possible side-effects compared to more established consolidants is a significant advantage. This fundamental scientific study examines the effects of a colloidal calcium hydroxide (nanolime) consolidant on medieval and quarried limestone and autoclaved aerated concrete and the efficacy of a colloidal hydroxyapatite treatment on archaeological human bone. Both calcium hydroxide and hydroxyapatite were synthesised. Characterisation of both compounds was performed by X-ray diffraction spectroscopy and particle morphology was confirmed by electron microscopy. Particle size was determined by laser diffraction and particle tracking analysis techniques, used together to study these particle systems for the first time, and electron microscopy. The location of particles within treated substrates was established by electron and optical microscopy whilst effects on water transport were determined by imbibition experiments and numerical modelling. For the first time a modified sharp front model was applied to [particle-material]-material composites to aid the understanding of water transport in such materials. Mechanical testing was used to identify differences in material strength depending on treatment layer thickness and mercury intrusion porosimetry suggested extent of pore blocking. It was found that non-classical effects occur in the calcium hydroxide system synthesised in this study and that particle stability can be influenced by reagent concentration. For the first time material sorptivity properties, modality and pore size distribution of Lincoln stone and archaeological bone are reported. The application of a nanolime consolidant to autoclaved aerated concrete allowed the nature of the particle transport through a highly complex material to be determined, showing that the particle concentration decreases with increasing penetration depth. Shallow nanolime particle penetration into limestone appeared ineffective on compressive strength. In a novel study the prospects of a hydroxyapatite consolidant treatment for bone were also evaluated, finding the results to be inconclusive in this small study. For all consolidants a small reduction in material water sorptivity after treatment demonstrated the permeable nature of the treatment layer and suggests the avoidance of damage mechanisms due to highly restricted water transport. Knowledge of the efficacy and location of treatment particles and their affect on water movement, particularly in weathered material, within limestones and archaeological bone is important and was determined for all materials used in this study. This work adds to the understanding of such treatments and their capabilities and the nature of the porous materials used herein.

Aerosolized drug delivery to the human lungs for asthma treatment has long been studied and yet the relationship between the delivery efficacy and the inter-subject variability due to gender, age, and disease severity remains unclear. A recent imaging-based cluster analysis on a population of asthmatic patients identifies four clusters with distinct structural and functional characteristics. The use of cluster membership to explore inter-subject variability by investigating numerically the air flow and particle transport in representative subjects of the asthmatic clusters on inhalation drug delivery in asthma sub-populations is proposed. Large-eddy simulations using computed tomography (CT)-based airway models were performed with a slow and deep breathing profile corresponding to application of a metered dose inhaler. Physiologically consistent subject specific boundary conditions in peripheral airways were produced using an image registration technique and a resistance network compliance model. Particle simulations and final deposition statistics were calculated for particle sizes ranging from 1–8 μm. The results suggested an emphasis on the importance of airway constriction for regional particle deposition and prominent effects of local features in lobar, segmental, and sub-segmental airways on overall deposition patterns. Asthmatic clusters characterized by airway constriction had an increase in deposition efficiency in lobar, segmental, and sub-segmental airways. Local constrictions produced jet flows that impinged on distal bifurcations and resulted in large inertial depositions. Decreased right main bronchus (RMB) branching angle decreased the fraction of particles ventilated to the right upper lobe (RUL). Cluster-based computational fluid dynamics results demonstrate particle deposition characteristics associated with imaging based variables that could be useful for future drug delivery improvements. One method for circumventing low deposition in small airways due to constriction in tracheobronchial airways is through hygroscopic growth of aerosols for inhalation. Hygroscopic materials have an affinity for water and can enlarge in size significantly as they traverse through respiratory tract. Hygroscopic growth has shown promise as a viable drug delivery method for decreasing deposition in the upper tracheobronchial region and increasing drug penetration and retention in small airways. Current models for hygroscopic growth models show promise in predicting steady state final diameter aerosol droplet sizes, but much uncertainty in predicting transient effects exists. This paper discusses in detail one such growth model and modifies it to include realistic spatial temperature and humidity variations associated with the lung. The growth model is simplified through grouping of terms and is then solved using MATLAB ODE 45 solver. The model is compared to experimentally acquired in vitro data for validation. The results do not show good agreement with the model, and suggests that additional factors exist that inhibit aerosol droplet growth from commencing immediately upon entering the respiratory tract like is assumed true in literature. This paper briefly hypothesizes for reasons for model and data disagreement and limitations of current growth models.

Submarine canyons are common features on continental margins worldwide. They are important natural conduits for transfer of terrigenous sediments to the deep sea, and thus, preferential pathways for shelf-slope exchange. The purpose of this study is to understand the biogenic particle transport in the seasons according two sediment trap moorings deployed in the Gaoping submarine canyon. The T6KP mooring was deployed in dry season while the T7KP mooring was deployed in wet season. Two typhoons, Kalmaegi and Fung Wong, invaded Taiwan during 16-18 and 26-29 July within the deployment of T7KP. We discussed the influence of rainfall and river discharge on biogenic particle transport based on results of the two sediment traps. The foraminiferal abundance in sediment traps in comparison with plankton tows was discussed regarding the particle transport mechanism of the water column in the Gaoping submarine canyon. The biogenic particle transport was a tide-dominated situation and displayed a periodic variation in dry season. In wet season, fine grain fraction (less than 63 micro meter) was dominant in the particle size and sedimentary condition was flood-dominated. The sedimentary condition was back to the tide-dominated state approximately 15 days after Kalmaegi typhoon (16-18, July). The activities of 210Pb and 234Th in the lower trap of T7KP mooring were an order less than that in T6KP mooring, indicating particles scavenge nuclides of the water column less effectively in wet season than in dry season. The absolute abundances of foraminifera in the canyon revealed that the biogenic particle was influenced by the terrigenous input and was different between dry and wet seasons. Seasonal variations of total flux and relative abundance of living foraminifera were evident in the upper 200 m water column near the Gaoping submarine canyon. Therefore, the seasonal variations of living foraminifera might be reflected on the biogenic particle transport in different seasons in the Gaoping submarine canyon.

The naturally occurring isotopes 231Pa and 230Th are used as tracers of marine biogeochemical processes. They are both produced from the radioactive decay of their uniformly distributed uranium parents (235U and 234U) in seawater. After production, 231Pa and 230Th are removed by adsorption onto settling particles (scavenging) and subsequently buried in marine sediments. 230Th is more particle reactive compared to 231Pa. Consequently, 230Th will be removed from the open ocean by adsorption onto settling particles, while 231Pa tend to be laterally transported by currents and removed by scavenging in areas of high particle flux (e.g. ocean margins). The primordial 232Th indicates lithogenic supply via rivers and resuspension of sediments, which provides additional information about processes involved in the cycling of particle reactive elements in the ocean. The preferential deposition of particle reactive elements at ocean margins (boundary scavenging) has important implications for our understanding of the distribution and dispersion of micronutrients (e.g. iron) and pollutants in the ocean. It is therefore valuable to understand the nature of boundary scavenging processes in order to evaluate the relative contribution of circulation and scavenging behaviors.The major characteristics of thermohaline circulation in the Mediterranean are well known and have been studied for decades. This sea is an almost land-locked area, where limited water-exchange with the Atlantic Ocean only occurs through the Strait of Gibraltar. Therefore, this marginal sea is often referred to as a “miniature ocean” suitable as a “laboratory” for marine environmental research. In this licentiate thesis, distributions of 231Pa, 230Th and 232Th in seawater and marine particles collected during the GEOTRACES MedSeA-GA04-S cruise in 2013 are presented. Observed nuclide distributions indicate the impact of deep water formation processes, where observed differences can be linked to the type of deep water formation process that occurs in respective basin. Essentially all in-situ produced 230Th is buried in Mediterranean Sea sediments. Despite lower affinity of 231Pa for marine particles, most 231Pa is also scavenged and deposited in Mediterranean Sea sediments. The efficient scavenging of 231Pa produces a relatively low fractionation between 231Pa and 230Th in terms of the fractionation factor FTh/Pa. This licentiate thesis presents a summary of the methods used for the analysis of 231Pa and Th-isotopes with details on the exchange chromatography method and the treatment of mass spectrometric data. The study of 231Pa, 230Th and 232Th in the Mediterranean Sea has important implications for our understanding of processes that control their water column distributions and how their behavior can be utilized to trace chemical flux in modern and past ocean environments. / GEOTRACES / MeDSeA

A colloidal system usually refers to when very small particles are suspended within a solution. The study of these systems encompasses a variety of cases including bacteria in ground water, blood cells and platelets in blood plasma, and river silt transport. Taking a look at these kinds of systems using computer simulation can provide a great deal of insight into how they work. Most approaches to date do not look at the details of the system, however, and are specific to given system. In this study a program called OpenFOAM is used as a basis to build a computer simulation tool that is flexible and that provides a detailed look at what is happening with all of the particles within the colloidal solution. This code is run through a series of tests to verify its usefulness.

No description available.

Turbulent magnetic fields are ubiquitous in space physics and astrophysics. The influence of magnetic turbulence on the motions of charged particles contains the essential physics of the transport and acceleration of energetic charged particles in the heliosphere, which is to be explored in this thesis. After a brief introduction on the energetic charged particles and magnetic fields in the heliosphere, the rest of this dissertation focuses on three specific topics: 1. the transport of energetic charged particles in the inner heliosphere, 2. the acceleration of ions at collisionless shocks, and 3. the acceleration of electrons at collisionless shocks. We utilize various numerical techniques to study these topics. In Chapter 2 we study the propagation of charged particles in turbulent magnetic fields similar to the propagation of solar energetic particles in the inner heliosphere. The trajectories of energetic charged particles in the turbulent magnetic field are numerically integrated. The turbulence model includes a Kolmogorov-like magnetic field power spectrum containing a broad range of scales from those that lead to large-scale field-line random walk to small scales leading to resonant pitch-angle scattering of energetic particles. We show that small-scale variations in particle intensities (the so-called "dropouts") and velocity dispersions observed by spacecraft can be reproduced using this method. Our study gives a new constraint on the error of "onset analysis", which is a technique commonly used to infer information about the initial release of energetic particles. We also find that the dropouts are rarely produced in the simulations using the so-called "two-component" magnetic turbulence model (Matthaeus et al., 1990). The result questions the validity of this model in studying particle transport. In the first part of Chapter 3 we study the acceleration of ions in the existence of turbulent magnetic fields. We use 3-D self-consistent hybrid simulations (kinetic ions and fluid electrons) to investigate the acceleration of low-energy particles (often termed as "injection problem") at parallel shocks. We find that the accelerated particles always gain the first amount of energy by reflection and acceleration at the shock layer. The protons can move off their original field lines in the 3-D electric and magnetic fields. The results are consistent with the acceleration mechanism found in previous 1-D and 2-D simulations. In the second part of Chapter 3, we use a stochastic integration method to study diffusive shock acceleration in the existence of large-scale magnetic variations. We show that the 1-D steady state solution of diffusive shock acceleration can be significantly modified in this situation. The results suggest that the observations of anomalous cosmic rays by Voyager spacecraft can be explained by a 2-D shock that includes the large-scale magnetic field variations. In Chapter 4 we study electron acceleration at a shock passing into a turbulent magnetic field by using a combination of hybrid simulations and test-particle electron simulations. We find that the acceleration of electrons is greatly enhanced by including the effect of large-scale magnetic turbulence. Since the electrons mainly follow along the magnetic lines of force, the large-scale braiding of field lines in space allows the fast-moving electrons interacting with the shock front multiple times. Ripples in the shock front occurring at various scales also contribute to the acceleration by mirroring the electrons. Our calculation shows that this process favors electron acceleration at perpendicular shocks. We discuss the application of this process in interplanetary shocks and flare termination shocks. We also discuss the implication of this study to solar energetic particles (SEPs) by comparing the acceleration of electrons with that of protons. The intensity correlation of electrons and ions in SEP events indicates that perpendicular or quasi-perpendicular shocks play an important role in accelerating charged particles. In Chapter 5 we summarize the results of this thesis and discuss possible future work.

No description available.

Transportation of unprocessed multiphase reservoir fluids from deep/ultra deep offshore through a long subsea tieback/pipeline is inevitable. This form of transportation is complex and requires accurate knowledge of critical transport velocity, flow pattern changes, phase velocity, pressure drop, particle drag & lift forces, sand/liquid/gas holdup, flow rate requirement and tieback sizing etc at the early design phase and during operation for process optimisation. This research investigated sand transport characteristics in multiphase, water‐oil‐gas‐sand flows in horizontal, inclined and vertical pipes. Two critical factors that influence the solid particle transport in the case of multiphase flow in pipes were identified; these are the transient phenomena of flow patterns and the characteristic drag & lift coefficients ( D C , L C ). Therefore, the equations for velocity profile were developed for key flow patterns such as dispersed bubble flow, stratified flow, slug flow and annular flow using a combination of analytical equations and numerical simulation tool (CFD). The existing correlations for D C & L C were modified with data acquired from multiphase experiment in order to account for different flow patterns. Minimum Transport Velocity (MTV) models for suspension and rolling were developed by combining the numerically developed particle velocity profile models with semi‐empirical models for solid particle transport. The models took into account the critical parameters that influence particle transport in pipe flow such as flow patterns and particle drag & lift coefficients, thus eliminate inaccuracies currently experienced with similar models in public domain. The predictions of the proposed MTV models for suspension and rolling in dispersed bubble, slug flow and annular flow show maximum average error margin of 12% when compared with experimental data. The improved models were validated using previously reported experimental data and were shown to have better predictions when compared with existing models in public domain. These models have the potential to solve the problems of pipe and equipment sizing, the risk of sand deposition and bed formation, elimination of costs of sand unloading, downtime and generally improve sand management strategies.