The New Amalfi Sheet is a highly differentiated tholeiitic intrusion which is situated between the towns of Matatiele and Swartberg in East Griqualand. It lies within the Central area of the Karoo Igneous Province. Rock types range from dolerites at the base and top through to a highly differentiated granophyre which is found as a 'sandwich horizon' within the top half of the sheet. The most evolved granophyre represents 15.86% of the initial liquid, which was found to be very similar in composition to the average Lesotho-type magma of Marsh and Eales (1984). The paragenetic sequence was found to be chromite → olivine → plagioclase → pigeonite and augite. Cumulus magnetite and ilmenite enter the paragenetic sequence together with immiscible sulphide droplets after 35% crystallization. In the late stages of crystallization, augite changes composition towards ferrohedenbergite. The reappearance of iron-rich olivine coincides with the disappearance of pigeonite and apatite appears as a cumulus phase for the first time after 70% crystallization. Granophyric intergrowth, which contains coarse perthitic Kfeldspar, becomes the most abundant modal entity within the most evolved granophyres. Differentiation was dominated by fractionation of plagioclase and pyroxene, with subordinate olivine and opaque-oxide fractionation. A minor amount of assimilation of country rock occurred within the topmost granophyres. The intrusion has been dated, using the Rb-Sr isochron method, at 178.37 ± 5.52 Ma. Extensive subsolidus deuteric alteration has resulted in the formation of a complete series of hydrothermally altered clinopyroxenes which are enriched in CaO but depleted in TiO₂ compared to the unaltered magmatic clinopyroxenes. It has also resulted in the formation of abundant vermiform ilmenite in the most evolved rocks, recognized by the fact that this phase is enriched in MnO compared to magmatic ilmenites. The very iron-rich orthopyroxene, ferrohypersthene, was found to have crystallized, during cooling of the sheet from the intercumulus liquid. Olivine in the dolerite re-equilibrated with the intercumulus liquid, becoming more iron-rich in composition.

Thesis submitted for the degree MAGISTER SCIENTIAE to the Faculty of Science, Department of Geology, University of the Witwatersrand, Johannesburg / The Koperberg Suite intrusion at Jubilee, Namaqualand varies in composition from anorthosite, through mica diorite to pyroxene leucodiorite and pyroxene diorite. Detailed mapping and petrological studies of these rocks indicate that they were sequentially emplaced into the Concordia Granite country rocks, and that each of the rock types represent discrete magmatic events. The sequence of intrusion is from more acidic to more basic. Whole-rock geochemical analyses indicate that these rocks represent cumulates involving variable proportions of plagioclase, orthopyroxene, mica, quartz, oxides and immiscible sulphides. These cumulate phases intruded into the Concordia Granite at the time of peak of metamorphism and deformation in the Okiep Copper District, i.e, about 1030Ma ago, At the time of intrusion, the country rocks were under going partial melting under high grade (granulite facies) metamorphic conditions. and granitic anatects were present in the crust. Hybridisation of basic magma and granitic melts occurred within the shear zones along which the basic magmas ascended. The En content of orthopyroxene in the Koperberg Suite exceeds the An content of plagioclase. This is atypical of basic intrusions and is a consequence of this mixing. Mixing calculations based on the initial 87Sr/86Srratio (Ru) of the Jubilee samples at 1030Ma, imply high levels of assimilation (as much as 80% assimilation in the case of anorthositic rocks) between a granitic component, similar in composition to the Nababeep Gneiss and a mantle-derived basic magma. Sulphide mineralisation was initiated by the assimilation process, which caused the separation of immiscible sulphides from the hybridised magma. Subsequent oxidation of the original sulphide assemblage produced bornite, chalcopyrite and Ti-poor magnetite. / Andrew Chakane 2019

This study is an account of the stratigraphic sequence, the petrography, mineralogy (microprobe investigations of orthopyroxene, clinopyroxene, olivine and plagioclase feldspar), and whole-rock major- and traceelement geochemistry of the silicate cumulates of the Upper Critical Zone in the western Bushveld Complex. Two parts of the study - an investigation of a 350m column incorporating the MG3 and UGI Footwall Units, and a comparison of two additional Upper Critical Zone profiles with a previously compiled profile between the UGI and Bastard Units - are focused on RPM Union Section in the northwestern sector of the Complex. The third part is a detailed vertical and lateral investigation of the Bastard Unit at the top of the Critical Zone, which draws on sampling and data compilation from seventeen profiles in the western limb of the Complex. The MG3 Unit (45m) is made up of a lower chromitite layer overlain by a norite-pyroxenite-anorthosite sequence while the UGlFW Unit (295m) is composed of a related series of lower chromitite layers (MG4) overlain by a pyroxenite-norite-anorthosite sequence capped by the UGI chromitite layer. These mafic cumulates display a distinctive pattern of oscillating cryptic variation in whole-rock Mg/(Mg+Fe), FeO/Ti0₂, Cr/Co and Ni/V ratios through the sequence. Sympathetic oscillations are recorded for compositions of orthopyroxene and plagioclase feldspar and eight subcycles are recognised through the UGlFW Unit. The entire sequence is characterised by the presence of small, spheroidal, embayed and irregularly shaped plagioclase grains which are poikilitically enclosed in cumulus orthopyroxene grains of both pyroxenites and norites. This texture is indicative of partial resorption of pre-existing feldspar primocrysts within the melt prior to their being incorporated into the host orthopyroxene grains. Textural, geochemical and isotopic data suggest that this sequence was built up by periodic additions of fresh, relatively primitive liquid into fractionated resident liquid, and subsequent mixing within the magma chamber. The Bastard Unit sequence, described in Chapter 4, is the last and most complete cyclic unit (c. 60m) of the Critical Zone, and its upper contact defines the boundary between the Critical and Main Zones of the Complex. This Unit can conveniently be sub-divided into a lower part, where orthopyroxene occurs as a cumulus phase, and the upper part which is composed entirely of anorthosite (Giant Mottled Anorthosite). The basal part of the Unit (≤ 18m) comprises a thin chromitite layer < O.5cm) overlain by a pyroxenite-melanorite-norite-leuconorite sequence. The basal pyroxenite is orthocumulate in character and rapidly gives way to norites and leuconorites. A distinct threefold subdivision emerges within the Giant Mottled Anorthosite which is predominantly an adcumulate which becomes orthocumulate in character at its top. Apart from minor deviations in thicknesses these lithologies are recorded over the entire strike-length covered in this study. Profiles of cryptic variation are compiled for orthopyroxene, plagioclase and whole-rock data and show that the Bastard Unit displays a characteristic pattern which is maintained throughout the western Bushveld Complex. A minor yet distinctive reversal in cryptic variation is revealed at a level which is stratigraphically variable within the lower Giant Mottled Anorthosite, and results in a double cuspate pattern. A remarkable feature of the basal Bastard pyroxenites is that although the modal proportion of mafic to felsic constituents varies systematically away from the northwestern sector, the Mg/(Mg+Fe) ratio of orthopyroxenes remains constant at 0.804 over a lateral strike distance of 171km. Within the upper part of the Unit the orthopyroxene is markedly Fe-rich and it is here that inverted primary pigeonite appears for the first time as a cumulus phase. In addition, K-feldspar, oscillatory zoned plagioclase grains and high levels of incompatible trace elements are noted at this level. On the basis of the data presented it is concluded that the Bastard Unit represents the crystallisation of a final, relatively large influx of hotter primitive liquid, with upper Critical Zone affinities, and subsequent mixing with a column of cooler (less dense) supernatant liquid which had in part hybridized with the overlying Main Zone magma. It is hypothesised that this new liquid was emplaced as a basal flow beneath supernatant liquid and that it initiated the deposition of mafic cumulates at its base. The supernatant liquid is interpreted as representing the fractionated residuum produced by crystallisation of earlier cyclic units, with plagioclase on the liquidus, and that it contained an abundance of small plagioclase primocrysts in suspension. Development of the Unit can be viewed as a two-stage process. In the lower half of the unit, chemical and physical parameters typical of the new magma dominated the crystallisation process, and resulted in cumulates very similar to other relatively complete Upper Critical Zone units. In the upper, leucocratic sequence, above a minor reversal, crystallisation was from a liquid which was the product of mixing of a minor pulse of primitive liquid with the reservoir of hybridized supernatant liquid. Although the Bastard Unit is not continuous around the entire Western limb of the Complex, it is concluded that it developed in a single, or connected, magma chamber and that its irruptive feeder zone was located in the proximal northwestern facies of the Complex.

The Mesoproterozoic rocks of the Bysteek and Koenap Formations of the Arribees Group are exposed within a NW-SE striking antiformal structure comprised of mafic granulites and metapelitic diatexites, and a number of marble and calc-silicate rock layers. The mafic granulites of the Bysteek Formation show a typological variety of anatectic features, including nebulitic, stromatitic mesosomes, melanosomes, quartz syenitic leucocratic vein networks and syenitic pools. Melanosomes consist of hedenbergitic to diopside-rich clinopyroxene (XMg: 0.40), anorthitic plagioclase (An90), with some quartz, minor apatite and titanite. Anatexis was caused by biotite dehydration melting and formed a melt of probably granitic composition. The leucosome composition ranges from either alkali-feldspar-granitic to plagioclase rich or granitic. This variation is interpreted as a result of variable extraction of melt from the source to granitic pools. The diatexites of the Koenap Formation are most likely of metapelitic or meta-greywacke origin. They are texturally variable but always contain high modal contents of alkali feldspar and quartz which generally form magmatic textures. Almandine-rich garnet (XMg: 0.18-0.25), cordierite (XMg: 0.71) form secondary biotite, sillimanite and magnetite during retrograde breakdown. Thermodynamic modelling of mafic granulite compositions suggests peak P-T conditions of ~865 °C and 8.6 kbar. Occasionally, garnet rich in ferric iron (XAdr: 0.55) forms by plagioclase-clinopyroxene breakdown under oxidising conditions at ~6 kilobar and ~ 800 °C. At the same stage amphibole forms in some melanosomes. P-T estimations for the diatexites based on thermodynamic modelling suggest the equilibration of the assemblage garnet, cordierite, alkali feldspar and melt at ~860 °C and 5.5 kbar. Conditions comparable to the peak pressure in the mafic granulites could not be established. However, since the diatexites and the mafic granulites are closely related in the field and no evidence of juxtaposition after the thermal peak exists, the P-T record of the diatexites might be incomplete