Filling the liquid crystals (LCs) into the air holes of the photonic crystal fibers (PCFs), we can obtain the liquid-crystal photonic crystal fibers (LCPCFs). Due to the tunable optical properties of the LCs, we can fabricate tunable optical devices based on the LCPCFs. In this thesis, we investigate the photonic bandgap (PBG) properties and find out the effective modal index curves of the LCPCFs by the finite-difference frequency-domain (FDFD) method. The effects of the operation temperature and the alignment of the LCs are discussed. When the alignment of the LC is in the transverse plane of the PCF, we can observe the blue shift and the splitting of the PBGs as we increase the operation temperature. As the LC is aligned along the PCF, the red shift occurs and the splitting disappears. The shift and the splitting of the PBGs are due to the high anisotropic property of the LCs. Besides, we can rotate the alignment of the LCs by the external electric field, and the effects of the alignment on the propagation properties of the LCPCFs are larger than those of the operation temperature. In the experiment, we successfully fabricate the LCPCFs by using the vacuum method. In the measurement of the LCPCF at different operation temperatures,the red shift of the spectra can be observed with the increasing operation temperatures, which has a very good agreement with the simulation results. As we vary the alignment of the LCs with the external electric field, the transmission bands are almost the same as the voltage is less than 200V. During the range of 200V to 400V, the PBGs demonstrate obvious variations and the deep appears at 1050nm. When the external electric field is raised to 400V, the shapes of the spectra are almost the same and the red shift of the PBGs can be observed. The results of our simulation and the experiment measurement can help us to design and fabricate optical devices based on the LCPCFs.

A novel selective-filling technology of photonic crystal fibers (PCFs) employing a simple selective-blocking process using UV gel is demonstrated in this thesis. In this study the liquid-filled PCFs with the filling in inside three layers and whole four layers represent the insertion loss of gel 7.5dB and the photonic band gap (PBG) guiding effect at wavelength 1100nm~1300nm, having potential to be tunable optical filters by filling the liquid crystal. The liquid-filled PCFs without the filling of the most inside 1ayer represent low insertion loss of gel 2dB and the total index reflection (TIR) guiding effect, having potential to be low loss tunable fiber gratings by filling the liquid crystal. The liquid-filled PCFs with the filling in middle a layer represent the elliptical far field pattern and effect of birefringence at wavelength 1600nm.

Integrated photonic circuits require small photonic elements. Recent progress in nanowire synthesis and nanofabrication enables us to investigate the potential of nanowires in novel integrated photonic devices. This thesis explores light manipulation on two material platforms – metallic nanostructures that support surface plasmon polaritons (SPPs), and periodic dielectric arrays for mode engineering. In Chapters 2 and 3, I will show that chemically-synthesized metallic nanowires are attractive candidates to support SPPs and enhance light- matter interactions. The first model device consists of a single quantum emitter in close proximity to a highly crystalline Ag nanowire. When the quantum emitter is optically excited, its emission rate is enhanced by a factor of 2.5, and 60% of the emission couples into the Ag nanowire, generating single SPPs. In addition to optically exciting SPPs, we demonstrate an optoelectronic device that generates and detects SPPs electrically, paving the way for seamless integration between electronic and plasmonic elements in a single circuit. In Chapter 4, I present a general strategy to create stretchable and flexible photonic devices. Flexible photonics has garnered a lot of interest because mechanical properties can be exploited to generate highly conformal devices with novel optical characteristics. We fabricated Si nanowire photonic crystal cavities and transferred them into polydimethylsiloxane (PDMS). The composite photonic crystal cavity supports high quality factor (Q) modes in the telecommunication range. We achieve mechanical reconfiguration of the cavity by stretching it, and observe tuning of the resonance wavelength over 67 nm, 134 times the resonance linewidth. The above demonstrations, when taken together, underscore the promise and potential of nanowires in integrated photonic circuits. / Chemistry and Chemical Biology

Two dimensional photonic crystal slabs are studied theoretically and experimentally for the application of refractive index sensing with a focus on increasing both quality factor and sensitivity simultaneously. An overview of simulation and experimental techniques, along with fabrication protocols used is given. Through the use of new wafer architectures which allow for an air substrate, sensitivity is enhanced in some cases by more than a factor of 2 from our previous studies. Combining this with a novel lattice proposed which greatly reduces fabrication tolerances, experimental quality factors above 10,500 are achieved while maintaining an experimental sensitivity of above 800 nm/RIU. The effects of a finite photonic crystal slab are studied through the group velocity of guided mode resonances, with an emphasis on zero-group velocity. Future applications of the designs proposed are discussed.

Two dimensional photonic crystal slabs are studied theoretically and experimentally for the application of refractive index sensing with a focus on increasing both quality factor and sensitivity simultaneously. An overview of simulation and experimental techniques, along with fabrication protocols used is given. Through the use of new wafer architectures which allow for an air substrate, sensitivity is enhanced in some cases by more than a factor of 2 from our previous studies. Combining this with a novel lattice proposed which greatly reduces fabrication tolerances, experimental quality factors above 10,500 are achieved while maintaining an experimental sensitivity of above 800 nm/RIU. The effects of a finite photonic crystal slab are studied through the group velocity of guided mode resonances, with an emphasis on zero-group velocity. Future applications of the designs proposed are discussed.

No description available.

Slow photon, or light with reduced group velocity, is a unique phenomenon found in photonic crystals that theoreticians have long suggested to be invaluable for increasing the efficiency of light-driven processes. This thesis demonstrates experimentally the feasibility of using slow photons to optically amplify photochemistry of both organic and inorganic systems. The effect of photonic properties on organic photochemistry was investigated by tracing out the wavelength-dependent rate of photoisomerization of azobenzene anchored on silica opals. The application of slow photons to inorganic photochemical processes was realized by molding nanocrystalline titania into an inverse opal structure and investigating its photodegradation efficiency in relation to the photonic properties. Changes in the photodegradation efficiency were directly linked to modifications of the electronic band gap absorption as a result of the photonic properties. The highest enhancement of twofold was achieved when the energy of the slow photons overlaps with the electronic band gap absorption, such that the loss of light due to photonic stop-band reflection was significantly reduced. In addition, the strength of slow-photon amplification with respect to the macroscopic structural order was studied by introducing controlled disorder via the incorporation of guest spheres into the opal templates. For the first time, a correlation between structural order, photonic properties and a photochemical process was established. The ability to combine slow-photon optical amplification with chemical enhancement was further achieved by incorporating platinum nanoparticles in inverse titania opals where the platinum nanoparticles increased the lifetimes of the higher population of electron-hole pairs arising from slow photon. Overall, various important factors governing the slow photon enhancement were investigated in detail, including the energy of the photonic stop band, angle dependence, thickness of the film, degree of structural order, filling fraction of the dielectric material and diffusion of a second medium if present. Theoretical calculations based on scalar-wave approximation in support of the experimental findings were provided wherever possible. The findings provide a blueprint for achieving optical amplification using slow photons in the broad range of photochemical or photophysical processes.

No description available.

Because of the fast growing in communications, the quality of signal transmission in optical fiber becomes very important. Concurrently, photonic crystal fiber (PCF) consisting of a central defect region surrounded by multiple air holes is attracting much attention in recent years because of its unique properties, such as full photonic bandgaps, wideband, dispersion, endlessly single mode and birefringence, etc. This thesis is mainly focused on the development of the photonic band structures and propagation properties of PCF. And we propose a novel ideal about 3-D PCF, which can be fabricated using the laser heated pedestal growth (LHPG) method. In the thesis, we study the optical properties of 2-D and 3-D PCFs made by Pyrex using the software RSoft. From the result of simulation, the 2-D out-of-plane bandgaps for a hexagonal close packed structure appear between the air filling fraction range from 0.30 to 0.88 for the incident light of wavelength range from 0.7 to 1

Researchers have argued for many years that one of the conditions for omnidirectional reflection in a one-dimensional photonic crystal is a strong refractive index contrast between the two constituent dielectric materials. Using numerical simulations and the theory of Anderson localization of light, in this work we demonstrate that an omnidirectional band gap can indeed be created utilizing low refractive index contrast materials when they are arranged in a disordered manner. Moreover, the size of the omnidirectional band gap becomes a controllable parameter, which now depends on the number of layers and not only on the refractive index contrast of the system, as it is widely accepted. This achievement constitutes a major breakthrough in the field since it allows for the development of cheaper and more efficient technologies. Of particular interest is the case of high index contrast one-dimensional photonic crystal fibers, where the propagation losses are mainly due to increased optical scattering from sidewall roughness at the interfaces of high index contrast materials. By using low index contrast materials these losses can be reduced dramatically, while maintaining the confinement capability of the waveguide. This is just one of many applications that could be proven useful for this discovery.