abstract: Volcanic eruptions are serious geological hazards; the aftermath of the explosive eruptions produced at high-silica volcanic systems often results in long-term threats to climate, travel, farming, and human life. To construct models for eruption forecasting, the timescales of events leading up to eruption must be accurately quantified. In the field of igneous petrology, the timing of these events (e.g. periods of magma formation, duration of recharge events) and their influence on eruptive timescales are still poorly constrained. In this dissertation, I discuss how the new tools and methods I have developed are helping to improve our understanding of these magmatic events. I have developed a method to calculate more accurate timescales for these events from the diffusive relaxation of chemical zoning in individual mineral crystals (i.e., diffusion chronometry), and I use this technique to compare the times recorded by different minerals from the same Yellowstone lava flow, the Scaup Lake rhyolite. I have also derived a new geothermometer to calculate magma temperature from the compositions of the mineral clinopyroxene and the surrounding liquid. This empirically-derived geothermometer is calibrated for the high FeOtot (Mg# = 56) and low Al2O3 (0.53–0.73 wt%) clinopyroxene found in the Scaup Lake rhyolite and other high-silica igneous systems. A determination of accurate mineral temperatures is crucial to calculate magmatic heat budgets and to use methods such as diffusion chronometry. Together, these tools allow me to paint a more accurate picture of the conditions and tempo of events inside a magma body in the millennia to months leading up to eruption. Additionally, I conducted petrological experiments to determine the composition of hypothetical exoplanet partial mantle melts, which could become these planets’ new crust, and therefore new surface. Understanding the composition of an exoplanet’s crust is the first step to understanding chemical weathering, surface-atmosphere chemical interactions, the volcanic contribution to any atmosphere present, and biological processes, as life depends on these surfaces for nutrients. The data I have produced can be used to predict differences in crust compositions of exoplanets with similar bulk compositions to those explored herein, as well as to calibrate future exoplanet petrologic models. / Dissertation/Thesis / Doctoral Dissertation Geological Sciences 2020

Axial piston machines of the swashplate type are commonly used in various hydraulic systems and with recent developments in displacement control, it is essential to maximize their efficiency further reducing operation costs as well as improving performance and reliability. This paper reports findings of a research study conducted for the piston-cylinder interface utilizing a novel fluid structure thermal interaction model considering solid body deformation due to thermal and pressure effects in order to accurately predict the transient fluid film within the gap. A large reduction in energy dissipation is possible due to reduced clearances allowable due to the surface shaping of the piston resulting in a reduction in leakage. From this study, it is shown that surface shaping of the piston in combination with a reduced clearance is not only beneficial by improving the efficiency of a machine, but also increases the reliability and the performance of the machine as the load support is enhanced.

Axial piston machines of the swashplate type are commonly used in various hydraulic systems and with recent developments in displacement control, it is essential to maximize their efficiency further reducing operation costs as well as improving performance and reliability. This paper reports findings of a research study conducted for the piston-cylinder interface utilizing a novel fluid structure thermal interaction model considering solid body deformation due to thermal and pressure effects in order to accurately predict the transient fluid film within the gap. A large reduction in energy dissipation is possible due to reduced clearances allowable due to the surface shaping of the piston resulting in a reduction in leakage. From this study, it is shown that surface shaping of the piston in combination with a reduced clearance is not only beneficial by improving the efficiency of a machine, but also increases the reliability and the performance of the machine as the load support is enhanced.

<div><p>Water is inflammable, non-toxic, environmentally friendly--- desirable traits, for a hydraulic fluid. However, its extremely low viscosity diminishes the load-bearing and sealing capacity of lubricating interfaces. Case in point: axial piston machines of swash plate design are compact, highly efficient positive displacement machines at the heart of hydraulic systems in forestry, construction, aerospace, and agricultural equipment, as well as industrial applications (presses, etc.); however, the three main lubricating interfaces decisive to the performance of such units in terms of both component life and efficiency are challenged by the use of water as working fluid. Especially during high-pressure operation, this low-viscosity lubricant can cause the these interfaces to fail in carrying the imposed load, resulting in severe wear, or even pump failure. The piston-cylinder interface is particularly challenging to design for water because it stands under obligation to carry the heavy side load that acts on the pistons of these machines, which increases with operating pressure. Furthermore, the architecture of axial piston machines of swash plate design does not allow this interface to be hydrostatically balanced.</p> <p> </p> <p>Through the development of a methodology that separates the fluid pressure fields of the three main lubricating interfaces of axial piston machines into their hydrostatic and hydrodynamic components, the present work enables a direct comparison of these interfaces in terms of how they support load. A case study of a 75 cc unit running on hydraulic oil conducted via this methodology at three different operating conditions (low pressure/low speed, low pressure/high speed, and high pressure/low speed) demonstrates that in the piston-cylinder interface, the force from hydrostatic pressure reaches such high magnitudes over the high-pressure stroke that less than half of it is needed to counter the load. The excess force from hydrostatic pressure then becomes the load. Consequentially, hydrodynamic pressure must counter a force from hydrostatic pressure that exceeds the original load. In the other two interfaces, by contrast, over half the load is being carried by hydrostatic pressure, thus significantly diminishing the amount of hydrodynamic pressure the interfaces are required to generate in order to achieve full load support. Moreover, nearly all of the moment on the piston is countered by hydrodynamic pressure, while less than half of the moment on the block is countered by hydrodynamic pressure, and the moment on the slipper is negligible by comparison.</p> <p> </p> <p>While this case study only investigates one pump, it shows how critical hydrodynamic pressure can be to load support in the piston-cylinder interface. The use of a low-viscosity fluid, e.g. water, reduces the hydrodynamic pressure that is generated in this interface, which, at challenging operating conditions, can lead to metal-to-metal contact. However, the performance of the interface can be improved via micro surface shaping, i.e. by giving the surface of the piston, or the bore that it moves through, a shape on the order of microns in height. The aim of present work is to pursue design trends leading to surface shapes that will enable this interface to function at higher pressures than currently achievable. </p> <p> </p> <p>This pursuit takes the form of systematic virtual design studies, an optimization procedure, and an algorithm developed specifically for tailoring the bore surfaces through which the pistons travel to piston tilt and deformation. From this emerges not only a set of design trends corresponding to the dimensions of two particularly powerful types of micro surface shaping, but also a profound insight into the behavior of the water-lubricated piston-cylinder interface fluid film, and how that behavior can be manipulated by changing the component surfaces that constitute its borders. Furthermore, in collaboration with Danfoss High Pressure Pumps, a physical prototype of a 444 cc axial piston pump with surface shaping generated via the aforementioned algorithm has been constructed and tested, achieving a total pump efficiency roughly 3% higher than that achievable by the commercial unit that the geometry of the prototype is based on.</p><br></div>

京都大学 / 新制・課程博士 / 博士(理学) / 甲第24430号 / 理博第4929号 / 新制||理||1704(附属図書館) / 京都大学大学院理学研究科地球惑星科学専攻 / (主査)准教授 河上 哲生, 教授 下林 典正, 教授 田上 高広 / 学位規則第4条第1項該当 / Doctor of Science / Kyoto University / DFAM

Oil feed grooves are implemented in reciprocating compressor piston applications to assure a constant supply of lubricating oil on bearing surfaces and decrease friction loss. In a hermetically sealed compressor, due to small clearances encountered, oil supply becomes critical in order not to operate in boundary lubrication regime. Due to the small size of the piston and small piston &ndash / cylinder clearance, a partial lubrication regime is present. In the current study, a model that solves Reynolds&rsquo / equation for piston-cylinder lubrication and the average Reynolds&rsquo / equation that considers the effect of roughness on partially lubricated bearing for a compressor piston with oil feed grooves is developed. A parametric study is carried out to investigate the effects of piston design parameters and then arrive at an improved piston performance by using alternative designs for oil feed groove and the other design parameters.

Résumé en français indisponible. / Mechanisms of volatile transfer from subducting slab to the melting region beneath arc volcanoes are probably the least understood process of arc magma genesis. Fluorine, which suffers minimum degassing in arc primitive melt inclusions, retains the information about the role of volatiles during magma genesis at depth. Experimentally determined solubility of F in aqueous fluid, and partition coefficients of F between fluid and minerals provide first order geochemical constraints about the volatile-transporting agent.My thesis experimentally determined F solubility in fluid and its partition coefficients among several phases. The systems are in equilibrium with hornblende and a humite group mineral (some contain melt or pyroxene) at 1 – 2 GPa, from 770 to 1047 °C, or equilibrium with hydrogrossular, pyroxene and norbergite or chondrodite at 2.5 – 3 GPa and 877 °C. The experiments were conducted with piston cylinder and cold sealing technique. The oxygen fugacity conditions were controlled by NNO buffer, while some were unbuffered. The fluids were extracted into volumetric flasks, and their compositions were determined by mass balance calculations. Moreover, the consistency was verified by HPLC for fluorine ion, and ICP-MS or ICP-AES for major cations of the quenched fluids.In 1 GPa experiments, the quench phases are so rare that the majority of the fluid compositions from direct analyses are consistent with mass balance results in their uncertainties. Moreover, my mass balance procedure takes into account all the measurements errors, which leads to large uncertainties on fluid compositions. The consistency demonstrates that most of fluorine aflter annealing in the capsule is present as fluorine ion. Futhermore, increases of the masses of starting materials, fluid proportions and analytical precisions will improve the uncertainties performances. ������������ can be represented by a single value 0.135 ± 0.036, which is independent of temperature, bulk composition and buffer conditions at 1 GPa. Df between fluid and humite group minerals is much less. Xf of hornblende and norbergite decrease from 1 to 2 GPa, while F partitionig between them doesn't change much. It indicates that F partitioning between fluid and minerals increases. Moreover, F concentrations in norbergite between NNO buffered and unbuffered experiments are significantly different. Meanwhile, Fe concentration variations of norbergite indicate that unbeffered experiments have higher oxygen fugacity than the NNO buffered ones. According to high temperature improves the free radical exchange reactions, H2O + 0.5O2 ⇄ 2OH. It indicates that both water fugacity and oxygen fugacity contribute to OH fugacity in fluid. I developed a simple model in which XF in humite group minerals are correlated to the ratio between F and OH. It is sucessfully applied to estimate the F concentration in the fluid, which co-exists with clinohumite, using Xf value.With the knowledge of my study, a new constraint can be framed on slab flux. The average F concentration in the fluid is 2700 ppm for F-rich experiments and it constrains the maximum amount of F carried by fluid in the presence of amphibole. Using partition coefficient of F to estimate F abundance in subducting slab, one can conclude that the increase of F concentration in the subarc mantle by fluid, in equilibrium with hornblende, to be less tan 5 ppm. Significant F enrichments found in arc lavas cannot be derived from aqueous fluid of subductiong slab in the presence of amphibole. Therefore, this result highlights the role either 1) slab melt, 2) fluid in equilibrium with eclogite, or perhaps 3) supercritical fluid for the element transfer from slab to mantle wedge.

The temperature distribution of the lubricating interfaces is an important aspect of the functioning of positive displacement machines. It can determine the efficiency and the life time of the unit. In particular, it directly affects the fluid properties and the thermal induced deformations of the solid bodies. A simulation tool capable of predicting the fluid temperature in such gaps thus becomes very useful in the design process of these machines. The temperature distribution in a film comprises of many physical phenomena including convection and conduction along and across the film. Past numerical approaches solved this multi-directional conduction-convection problem using a threedimensional(3D) grid, making the tool computationally expensive and unsuitable for fast simulations. This paper proposes a hybrid fluid temperature solver, based on, a low computational cost twodimensional(2D) grid, to reduce the simulation time with reasonable accuracy. The piston/cylinder interface of an axial piston machine is selected as reference case to demonstrate the proposed approach. The hybrid approach was found to speedup the simulation times by 36%.

While the free electron model can often be surprisingly successful in describing properties of solids, there are plenty of materials in which interactions between electrons are too significant to be neglected. These strongly correlated systems sometimes exhibit rather unexpected, unusual and useful phenomena, understanding of which is one of the aims of condensed matter physics. Heat capacity measurements of paramagnetic YFe$_{2}$Ge$_{2}$ give a Sommerfeld coefficient of about 100 mJ mol$^{−1}$ K$^{−2}$, which is about an order of magnitude higher than the value predicted by band structure calculations. This suggests the existence of strong electronic correlations in the compound, potentially due to proximity to an antiferromagnetic quantum critical point (QCP). Existence of the latter is also indicated by the non-Fermi liquid T$^{3/2}$ behaviour of the low temperature resistivity. Below 1.8 K a superconducting phase develops in the material, making it a rare case of a non-pnictide and non-chalcogenide iron based superconductor with the 1-2-2 structure. This thesis describes growth and study of a new generation of high quality YFe$_{2}$Ge$_{2}$ samples with residual resistance ratios reaching 200. Measurements of resistivity, heat capacity and magnetic susceptibility confirm the intrinsic and bulk character of the superconductivity, which is also argued to be of an unconventional nature. In order to test the hypothesis of the nearby QCP, resistance measurements under high pressure of up to 35 kbar have been conducted. Pressure dependence of the critical temperature of the superconductivity has been found to be rather weak. μSR measurements have been performed, but provided limited information due to sample inhomogeneity resulting in a broad distribution of the critical temperature. While the superconductivity is the result of an effective attraction between electrons, under different circumstances the electronic properties of a system can instead be dictated by the Coulomb repulsion. This is the case for another transition metal based compound NiS$_{2}$, which is a Mott insulator. Applying hydrostatic pressure of about 30 kbar brings the material across the Mott metal-insulator transition (MIT) into the metallic phase. We have used the tunnel diode oscillator (TDO) technique to measure quantum oscillations in the metallised state of NiS$_{2}$, making it possible to track the evolution of the principal Fermi surface and the associated effective mass as a function of pressure. New results are presented which access a wider pressure range than previous studies and provide strong evidence that the effective carrier mass diverges close to the Mott MIT, as expected within the Brinkman-Rice scenario and predicted in dynamical mean field theory calculations. Quantum oscillations have been measured at pressures as close to the insulating phase as 33 kbar and as high as 97 kbar. In addition to providing a valuable insight into the mechanism of the Mott MIT, this study has also demonstrated the potential of the TDO technique for studying materials at high pressures.

This thesis describes investigations into the properties of -phase BEDT-TTF charge transfer salts. Charge transfer salts are mainly studied as they are very useful test beds for fundamental physics due to the tuneability of their proper- ties and ground states. The effects of temperature and pressure on such systems have been studied, as these allow access to a wide range of different states and properties. Transport properties of these systems have been studied to obtain information about the Fermi surface and effective mass, and the effect of deuter- ation and also change of pressure media will be discussed. The interaction of infrared radiation with these systems has also been investigated and simultaneous pressure and temperature measurements will be presented, something not greatly studied due to the large technical challenges. The techniques and approaches for overcoming these are also discussed. Chapter 1 provides an introduction to the organic materials themselves with particular emphasis on the actual compounds studied. Chapter 2 provides the necessary theoretical background for studying organic charge transfer salts using magnetic quantum oscillations and their infrared re- ectivity. Chapter 3 covers the experimental techniques and also discusses some of the challenges encountered and their solutions to aid others working in this area. Chapter 4 describes an investigation into the transport properties of - (ET)2Cu(SCN)2 by studying Shubnikov-de Haas oscillations using both deuter- ated and normal samples and using two different pressure media, and comparing it to work done using a third. Chapter 5 presents an investigation into the pressure dependence of selected phonon modes in -(ET)2Cu(SCN)2 using infrared radiation on a deuterated sam- ple. Chapter 6 presents what is believed to be the first pressure and temperature dependent infrared study of an organic molecular material. In this case the or- ganic molecular material is d8--(ET)2Cu[N(CN)2]Br, but the techniques should be readily transferable to other materials.