The Platreef occurs at the base of the Northern Limb of the Bushveld Complex and is variably mineralised with PGE, Cu, and Ni. The Platreef varies in thickness from a few meters to a few hundred meters and rests on progressively older sediments of the Transvaal Supergroup and Archaean granite basement northwards. Recent studies have highlighted the importance of magmatic processes, contamination of the magma by footwall rocks and syn- and post metasomatic fluid activity on the observed mineralisation. Along the Platreef strike, the PGE grade profiles are generally top-loaded from Overysel to Tweefontein North and more variable and bottom loaded from Tweefontein Hill southwards emphasizing the importance of the change in mineralisation style at Tweefontein in relation to the whole Platreef. This study presents the first significant PGM data on the Tweefontein farm, including ten boreholes along strike, providing insight into the distinctly different PGE mineralisation styles observed. Samples were selected based on assay data, varying rock types, stratigraphic position and proximity to geological features. The selected samples were investigated using petrography, geochemistry and the automated SEM techniques of QEMSCAN and MLA. Over 9000 PGM were analysed forming one of the most comprehensive PGM studies on the Platreef to date. The lowermost footwall intersected along the Tweefontein strike is banded ironstone of the Penge Formation. This is overlain by a metasedimentary footwall package, of variable thickness, derived from the shales and dolomites of the Duitschland Formation. Iron-rich, recrystallised, noritic sills occur at the base of the Platreef and are thought to represent sills which intruded prior to the emplacement of the Platreef. A pre- and possibly syn-Bushveld structural control resulted in irregular floor topography defined by a topographic footwall high in the central Tweefontein area and topographic depressions at Tweefontein North and Tweefontein Hill. The depression areas at Tweefontein are similar to the footwall basins at Turfspruit to the south, in which the Platreef is more lithologically complex compared to the footwall high areas. The footwall basins at Tweefontein and Turfspruit contain basal massive and submassive sulphides, which may not necessarily carry significant PGE grade. The Platreef lithologies at Tweefontein are composed of pyroxenites and norites with minor harzburgitic lithologies and contain numerous cross-cutting granitic veins. Xenoliths/interlayers of metamorphosed Duitschland lithologies occur primarily near the base of the Platreef, but also in the middle and upper Platreef sequence reflecting roof pendants. Unlike the Platreef on the farms adjacent to Tweefontein, the Platreef and footwall lithologies are relatively unaltered, but localised serpentinisation and chloritisation occur within harzburgitic lithologies and metasedimentary interlayers. Based on the stratigraphy and geochemical characteristics, the Platreef at Tweefontein can be subdivided into the upper and lower Platreef. The upper Platreef subdivision occurs in the top 20-40 m of the sequence and is defined by higher Mg#, Cr, Cr (ppm)/MgO and Pt/Pd values compared to the lower Platreef. In addition, the majority of the grade and base metal sulphide (BMS) content is enriched in the upper versus the lower Platreef, particularly for the northern and central parts of Tweefontein. The upper and lower Platreef may have been derived from different magma sources based on the “R Factor” concept proposed by Campbell and Naldrett in 1979 whereby the abundance of the PGE relative to the BMS content is linked to the proportion of magma with which the sulphide ore equilibrated (Naldrett, 2005b). Previous detailed geochemical studies from Tweefontein Hill southwards highlighted compositional breaks in the Platreef sequence thought to represent distinct sill-like intrusions (Hutchinson and Kinnaird, 2005; Kinnaird, 2005; Manyeruke et al., 2005; Nyama et al., 2006). They reported a more primitive sill at the top of the Platreef, which correlates to the upper Platreef at Tweefontein. The lower Platreef is therefore likely to represent a different sill intrusion. A relatively homogenous pyroxenitic package characterises the upper Platreef, although a more heterogeneous package is observed close to and at Tweefontein Hill. At Tweefontein North, the base of the upper Platreef is often marked by a chromitiferous package comprising a pegmatoidal feldspathic pyroxenite unit, up to 6 m thick, capped by a chromitite layer. Due to similar stratigraphy and high PGE grades, this distinct horizon has been compared to the Merensky Reef found elsewhere in the Bushveld Complex. The predominant base metal sulphides (BMS) in the Platreef at Tweefontein are pyrrhotite, pentlandite, chalcopyrite with minor pyrite aligned with that found elsewhere along the Platreef strike. There is an increase in BMS content, primarily pyrrhotite, towards the base of the Platreef with massive and submassive sulphide development near the base and in the footwall, particularly at Tweefontein Hill. Sulphur isotopes and detailed mineralogical studies at Turfspruit have shown that the addition of S, As and Sb into the magma from the Duitschland footwall triggered the development of a PGE-poor sulphide liquid which was then able to mix, modify and dilute the magmatic sulphides (Hutchinson and McDonald, 2008). Due to the similarity in footwall between Turfspruit and Tweefontein, these proposed processes help to explain the increase in BMS towards the base and the development of basal massive and submassive sulphides, which are not necessarily associated with significant PGE grade. At Tweefontein North, the processes dominating the top-loaded PGE mineralisation were primarily magmatic. The PGM assemblage, hosted by base metal sulphides and magmatic silicates, is dominated by Pt-and Pd-bismuthides and -tellurides with minor PGE-sulphides and Pt-arsenides. PGE-sulphides occur in the Platreef where the chromitiferous horizon is developed, which may indicate an environment low in volatile activity and one of the most primary mineralisation styles along the Platreef strike. The footwall high, which separates the depressions at Tweefontein North and Tweefontein Hill may have kept the Platreef at Tweefontein North relatively protected from additional processes affecting Tweefontein Hill. In contrast, assimilation of the Duitschland footwall is thought to play a key role in the development of the variable but predominantly bottom-loaded PGE mineralisation at Tweefontein Hill. The PGM assemblage is Pd-dominant characterised by Sb-, As- and Bi-bearing PGM, reflecting the incorporation of Sb, As and Bi from the Duitschland footwall. The association of the PGE mineralisation with the extensive basal sulphide development implies that the mineralisation at Tweefontein Hill probably occurred due to the gravitational settling of a sulphide liquid containing a mix of sedimentary and PGE-hosting magmatic components. Due to a significant PGM-BMS association in the mineralised footwall and metasedimentary interlayers/xenoliths, a downward migrating sulphide melt is believed to be the main mechanism responsible for the redistribution of PGE, predominantly Pd, into the mineralised metasedimentary lithologies. Finally, the Platreef and footwall lithologies may be locally modified by late-stage felsic and hydrothermal fluids to form bismuthide- and arsenide-dominant PGM assemblages, primarily hosted in quartz and serpentine respectively. This study shows the PGM and sulphide mineralisation at Tweefontein to be multifaceted, involving magmatic processes, assimilation of the Duitchland footwall into the Platreef magma and late-stage hydrothermal and felsic fluid activity. Footwall composition and irregular floor topography, resulting in depression areas at Tweefontein North and Tweefontein Hill, are believed to play a key role in what processes become significant along the Tweefontein strike. This research represents a significant contribution to the understanding of the distinctly different PGE mineralisation styles at Tweefontein and allows for a complete comparison of the Platreef PGE mineralisation from Overysel to Turfspruit.

The Platreef has been the site of platinum mining since the 1920’s. The reef itself comprises a series of pyroxenites, gabbronorites and norites that contain xenoliths/rafts of footwall rocks. The Platreef is irregularly mineralised with PGE, Cu and Ni, and has a greater abundance of sulphides than the Merensky Reef. The main base metal sulphides within the Platreef are pyrrhotite, pyrite, pentlandite, and chalcopyrite. Extremely varied platinum group minerals occur as tellurides, bismuthotellurides, antimonides and arsenides. This study aimed to gain a clearer understanding of the formation of sulphides within the Platreef. In order to do this, cores from both the northern and southern sectors of the Platreef were sampled. A detailed study of the sulphides within these cores was conducted to identify different styles of mineralisation and their occurrences. Four different styles of mineralisation were identified: massive, net-textured, blebby and interstitial. In general, sulphides in the southern sector of the Platreef are concentrated in the lower portion of the package, whereas in the northern sector they are concentrated in the upper part although in both sectors the sulphide occurrences are associated with metasedimentary xenoliths. Conventional and multiple sulphur isotope analyses were undertaken on sulphides from cores from both the southern and the northern sectors. This was done in order to determine the source of the sulphur. These analyses were also conducted to examine sulphur isotope variations with changing footwall. Previous sulphur isotope data predominantly obtained from the central sector of the Platreef indicated a crustal contribution to the sulphur budget but did not provide much data on footwall sulphides so the nature of the crustal component was only implied. In this thesis sulphur from an external source was identified as having contributed to the formation of sulphides in both the southern and the northern sectors of the Platreef, especially for sulphides in proximity to metasedimentary xenoliths. In the southern sector of the Platreef this source was identified as most likely being pyritic shales of the Lower Duitschland Formation. In the northern sector, Malmani dolomites, which are suggested to have collapsed from the roof of the Platreef, are the most likely source of sulphur. Importantly, in the northern sector no sulphur is thought to have come from the Archaean granite footwall. Oxygen isotope analyses were conducted on samples from the southern sector of the Platreef to verify the presence of crustal contamination. Data collected indicated that there had been a crustal oxygen component involved in the formation of silicates that led to their partial recrystallisation. When compared to oxygen isotope data from the central sector of the Platreef it appears that there are variations along strike that most likely result due to the changing footwall. This data indicates a major contribution of oxygen-, sulphur- and other volatile-rich fluids to the Platreef. This led to the partial re-crystallisation of silicates, and in areas in close proximity to sulphur-bearing metasedimentary xenoliths aided in the formation of sulphides. These volatile-rich fluids most likely originated from metasedimentary xenoliths during metamorphism that then migrated through the Platreef package. When the observations from both the southern and northern sectors of the Platreef are compared and combined with pre-existing data for the central sector, several general observations can be made. 1. The entire length of the Platreef has been affected by contamination from crustal sulphur sources to some degree. This contamination is suggested to be from volatile-rich fluids which were released from metasedimentary crustal xenoliths and footwall during metamorphism. 2. The proximity between sulphide enrichment and sulphur-bearing sediments (as footwall or xenoliths) is important and indicates the source of the sulphur which led to sulphide formation. 3. Contamination occurred on a localised scale, depending on the composition of the sedimentary lithologies and the proximity of the contaminant to the magma. In the southern sector of the Platreef the source of the sulphur is almost certainly pyritic shales of the Lower Duitschland Formation. In the central sector, sulphur has most likely come from sulphur-rich dolomites and evaporites from the Malmani dolomites. In the northern sector, sulphur-rich fluids were released from Malmani dolomite rafts that collapsed from the roof into the magma during the emplacement of the Platreef. The Archaean footwall in this area has had little or no control on the formation of the sulphides within the Platreef.

Philosophiae Doctor - PhD / The Platreef is a platinum group elements (PGE) deposit located in the Northern limb of the Bushveld Igneous Complex (BIC). It is a series of mafic and ultramafic sills that are overlain by rocks from the Main Zone (MZ) of the BIC. In comparison to PGE deposits (i.e., Merensky Reef and the UG-2 chromitite) occurring in the Critical Zone (CZ) of the Eastern and Western Limbs of the BIC, which are less than 1 m in thickness, the Platreef is 10 to 400 m in thickness and is comprised of a variety of rocks. PGE mineralisation in the Platreef is not confined to a specific rock type, and its distribution and styles also vary with depth and along strike. Despite the numerous researches that have been conducted, the genesis of Platreef is still poorly understood. New major and trace elements in conjunction with Sr–Nd isotope data, generated from whole-rock analyses of different Platreef rocks, were collected from four drill cores along its strike. The data were examined to determine the source of the magmas and identify the processes involved in its genesis. The study also aimed at establishing whether a genetic link exists between the Platreef magmas and the magmas that formed the Lower Zone (LZ), CZ and MZ in the Rustenburg Layered Suite (RLS) of the BIC. The petrography revealed that the Platreef in the four drill cores consists of harzburgite, olivine pyroxenite, pyroxenite, feldspathic pyroxenite and norite. Based on the textural and modal mineralogy variations, feldspathic pyroxenite was subdivided into five types (I, II, III, IV and V). The variation in the average contents of MgO, LaN/YbN and ΣREE for the Platreef rocks are consistent with the modal mineralogy from the least to the most differentiated rocks. However, the Sr–Nd isotope data of the Platreef rocks have revealed two distinct groups of samples with decreasing ɛNd2060. Group 1 consists of pyroxenite and feldspathic pyroxenite II, III and V having ɛNd2060 values that range from –8.4 to –2.9, and 87Sr/86Sr2060 values from 0.707281 to 0.712106. The Platreef rocks of group 2 consist of olivine pyroxenite and feldspathic pyroxenite Type I with ɛNd2060 ranging from –12.6 to –10.8, and 87Sr/86Sr2060 ranging from 0.707545 to 0.710042. In comparison to the LZ, CZ and MZ rocks, which have ɛNd values ranging from –8.5 to –5.1, and 87Sr/86Sr ranging from 0.704400 to 0.709671, Platreef pyroxenite of group 1 have lower negative ɛNd2060 values (from –3.8 to –2.9) and higher 87Sr/86Sr2060 values from 0.709177 to 0.710492, whereas feldspathic pyroxenite of group 1 have overlapping ɛNd2060 values (from –8.4 to –4.9) but also higher 87Sr/86Sr2060 values (from 0.707281 to 0.712106). Instead, the Platreef olivine pyroxenite and feldspathic pyroxenite in group 2 highly negative ɛNd2060 values and overlapping 87Sr/86Sr2060 values. It is therefore suggested that the Platreef magmas derived from the partial melting of an heterogeneous mantle source comprising depleted mantle melts and both metasomatized slightly unradiogenic Nd enriched melts and highly unradiogenic Nd enriched melts from the subcontinental lithospheric mantle. These magmas ascended via the continental crust using different paths and interacted with rocks of different Sr–Nd isotopic compositions which resulted in the formation the hybrid magmas. The study speculates that sulphide saturation in the Platreef magmas was reached in the staging chambers at depth, and the varying styles of the PGE mineralisation in the Platreef rocks are the result of the varying degree of partial melting of the heterogeneous source for their magmas. In conlusion, this study suggests that the genesis of the Platreef is much more complex and should be considered very much independent from processes involved in the genesis of the RLS in the Eastern and Western Limbs of BIC in agreement with earlier studies. / NRF Inkaba ye Africa Iphakade / 2020-08-31

Magister Scientiae - MSc (Earth Science) / The complexity of the Platreef stratigraphy and the generic position of the Ni-Cu-PGE mineralisation is a challenge to prospecting and mining companies in the Northern Limb of the Bushveld Complex, partially, as a result of various floor rock interactions with the reef. Therefore, this study evaluated the effects of contact metasomatic fluids on the nature and style of PGE mineralisation as the main event leading to the complexity of the Platreef stratigraphy from the contact zone near the floor rock. Fifty samples from boreholes MO009 and MO019 drilled at Moordkopje 813 LR farm for Akanani Project by Lonmin Plc were used for this study. The mineralogy and geochemistry of the Platreef samples were studied and associated with their mineralisation occurrences. Major, minor and trace element contents were analysed by XRF analysis using fused beads, and PGE contents (Pt, Pd) in 11 samples were determined by Fire Assay.

>Magister Scientiae - MSc / This study is focused on the Akanani prospect area, approximately 25 km north-west of the town of Mokopane, Limpopo Province where exploration geologists at the study area have classified the ‘pyroxenitic’ units into P1, P2, P3 and P4 units upward in order of succession with height based on their textures, mineralogy and colour. The primary aim of this study is to distinguish the distinctive geochemical and mineralogical characteristics that can be used to identify each unit (P1 to P4) and in so doing create major geochemical, petrographic and mineralogical variables that will help or facilitate the exploration for and recovery of PGE and BMS mineralisation. Geochemical and mineralogical variation studies were carried out on the cores from ZF044, ZF045, ZF048, ZF057, ZF078, ZF082 and M0023, located in the Platreef at the Akanani Prospect area on the farms Moordkopje 813LR and Zwartfontein 814LR. Using a combination of various multivariate statistical techniques (factor, cluster and discriminant analysis) and mineralogical studies (CIPW norm, microprobe analysis, petrography), the outcomes of the study have demonstrated that the Platreef at Akanani comprise at least four lithological units i.e. the basal pyroxenite portion referred to as the P1 unit comprises chromitite, pyroxenites and feldspathic pyroxenites with associated Cr, TiO2, chromite, pyroxenes, hematite and Fe2O3, the mineralized section of the P2 unit is characterized by harzburgite, serpentinized harzburgite and in places orthopyroxenites are present consistent with high MgO and LOI contents, the feldspathic portion referred here as the P3 unit is characterized by a feldspathic pyroxenite containing higher Al2O3, Na2O, K2O, albite, hypersthene and SiO2 and the top most portion of the P4 unit comprising CaO, Diopside, ilmenite, anorthite, apatite and P2O5 that can be interpreted to have formed by three separate magma pulses. Considering the possibility that the P4 unit is a hybrid melt of assimilated Platreef that interacted with intruding Main Zone magma, this reduces the number of magma pulses to two. The classification of P1, P2, P3 and P4 units of the Platreef at Akanani shows that the criteria used by mining personnel to classify the four lithological units is not definitive and therefore are not highly reliable. Although various multivariate statistical techniques were employed relatively similar elemental associations were obtained highlighiting the importance of this approach. The strongly positive correlation between sulphides, PGEs and chromite at Akanani is consistent with an orthomagmatic deposit that had been disturbed by significant hydrothermal activity, while in places a good BMS-PGE relationship is commonly associated with the main chromitite stringers in P1. Mineral and whole rock compositions of silicate rocks highlight the strongly magnesian nature of the ultramafic P2 unit. Mineral chemistry studies of chromite, orthopyroxene, olivine, clinopyroxene and plagioclase are consistent with the multi- emplacement model. Convective exchange resulted in the enrichment of iron at the bottom of the stagnant chamber, while incompatible elements migrated upwards consistent with iron depletion with stratigraphic height. Injection of P1 magma and subsequent mixing with country rocks gave rise to the formation of chromitites and addition of plagioclase component to the intruding magma. A normal fractionation trend is suggested between P2 and P3 consistent with enrichment of MgO in P2 and enrichment of Al2O3, Na2O, SiO2 and K2O in P3. The An% of 84.4 of plagioclase coupled with CaO enrichment in P4 is suggestive of some Main Zone influence and can be interpreted as resulting from partial melting and recrystallization of P3 in response to the intrusion of the Main Zone magma is suggested for the formation of the P4 unit. There exists a good correlation between the modal mineralogy and mineral chemistry as determined optically, the norm as determined by the CIPW norm and the whole-rock geochemical results as determined by multivariate statistics and conventional methods.

Please read the abstract in the section 00front of this document / Thesis (PhD)--University of Pretoria, 2009. / Geology / unrestricted

Geochemical, mineralogical and tenor variation studies were carried out on the cores from UMT040, UMT064 and UMT063, located in the Flatreef on Turfspruit, in the southern sector of the Platreef. The investigation comprised three objectives (1) to identify controls on mineralisation in the upper section of the Platreef, (2) to construct a 3D PGE tenor model, and (3) to test whether the new geological interpretation on Turfspruit correlates with the eastern and western limbs of the Bushveld Complex. The above-mentioned holes were used for geochemical analyses of major and trace elements; and UMT064 was also used for orthopyroxene microprobe analyses. For construction of the tenor model, a total of 276 drill holes were used. The distance between drill holes for geochemical studies is 145 m and 175 m respectively; and for the tenor model is approximately 100 m. The outcomes of the study have demonstrated that the upper section of the Platreef comprise at least four lithological units i.e. the topmost portion of T1, lowermost portion of T1, T2 Upper and T2 Lower that can be interpreted to have been formed by four separate pulses of magma. Considering the possibility of the T2 Lower being metamorphosed calc-silicates, this reduces the number of magma pulses to three. This is supported by the mineralogy, geochemical content and tenor variations. The T1 is made up of an orthopyroxenite (feldspathic in places), the T2 Upper comprised a pegmatoidal orthopyroxenite (also feldspathic in places) and the T2 Lower is made up of a harzburgite. High grade PGE, Ni and Cu mineralisation was found to occur within two zones in the upper section of the Platreef i.e. the T1m and T2 (Upper and Lower). Mineralisation occurs in the form of base metal sulphides such as pyrrhotite, pentlandite and chalcopyrite; and PGEs are dominated by amphoterics (PGE-arsenides, tellurides, antimonides and bismuthinides). These amphoterics are associated with base metal sulphides. The sulphides in both the T1m and T2 are interstitial. PGE minerals such as michenerite, sperrylite, hollingworthite and cooperite are present in the study area. In the T2, an increase in sulphide content and PGE grades are generally associated with the presence of the “main” chromitite stringer/ seam at the contact between a feldspathic pyroxenite (T1) and the coarse-grained to pegmatoidal pyroxenite (T2 Upper). Several other chromitites might be present above and below this contact, and it has been noted that not all of those chromitites are associated with an increase in sulphide content and higher PGE grades. PGE grades were found to be higher in T2 Upper than in T2 Lower, whereas, the base metals (particularly Ni) are generally higher in T2 Lower. In the T1m, mineralisation occurs close to the contact between the feldspathic pyroxenite and orthopyroxenite, but only the orthopyroxenite hosts the sulphides. Chromitite stringers rarely occur in the T1m. Where present, they generally occur at the top of the mineralised zone. The sulphides in both the T1m and T2 are thought to have resulted from separate and different processes. Those in the T1m are thought to have resulted from a fractional segregation process, whereas the sulphides in the T2 were thought to have been emplaced in bulk or as a mush. The 3D PGE tenor model has demonstrated that the tenor in both the T1 and T2 are higher than previously thought for the northern limb of the Bushveld Complex. Tenors in the T1 reach up to 700 ppm, whereas tenors of about 1000 ppm were recorded in the T2. These tenors are comparable to the tenors measured from the sulphide melt inclusions elsewhere in the northern limb. Tenors are the highest in the northwestern part of Turfspruit and they gradually decrease towards the southeast. Both the T1 and T2 are dominated by a tenor of about 100 ppm. In the T1, a tenor of 250 ppm is dominant in the northwestern and southeastern parts of the study area, whereas in the T2 it is only dominant in the northwestern part. Vertical variation in tenors has shown that the tenors are the highest in the topmost portion of the T1 and at the top of T2 Upper (below the T1-T2 contact). The T1 has been found to be comparable with the Merensky Reef due to the following: (a) similarities with respect to major and trace element compositions of whole rock analyses; (b) Cr/MgO ratios which are greater than 80; and (c) similarities in the pyroxene content excluding the MgO/((MgO)+FeO) ratio and CaO contents; and in the PGE tenor of the sulphides. In addition, the T1 has many of the characteristics of the model proposed by Naldrett et al (2009) for the formation of the Merensky Reef in the western Bushveld. However, the differences between the T1 and the Merensky Reef were also noted i.e. the MgO/((MgO)+FeO) ratios in this study are lower (averaging 0.71) than the Mg# reported for the Merensky Reef (Mg#78-83), the upper Critical Zone (Mg#78-84) and elsewhere in the Platreef north of Turfspruit. The CaO levels (representing the wollastonite component of the orthopyroxene) at Turfspruit are higher (>2 wt %) compared to the Merensky Cyclic Unit and other parts of the northern limb where the CaO levels are below 2 wt %. This is an indication that the pyroxene composition at Turfspruit is more evolved compared to the Merensky Reef.

Le Platreef est une formation noritique contenant des minéralisations en Éléments du Groupe du Platine. Elle se situe en bordure de la partie septentrionale du complexe du Bushveld. Afin de définir les spécificités de cette unité marginale, nous avons tout d'abord étudié des échantillons pouvant servir de point de comparaison : ils proviennent d'une zone centrale de l'intrusion, le forage de Bellevue. Les données en isotopie de l'oxygène indiquent des valeurs de δ18O proches de 6,5 à 7 ‰ et homogènes à travers la pile magmatique. Ces valeurs, plus lourdes de 1 à 1,5 ‰ que celles des autres produits issus du manteau du Kaapvaal, sont l'indice d'une contamination crustale à l'échelle de tout le complexe. L'isotopie de l'hydrogène et les teneurs en eau témoignent de cumulats peu ou pas altérés. <br /><br />Sur la base de critères pétrographiques et géochimiques, le Platreef apparaît beaucoup plus affecté par des phénomènes d'assimilation et de circulations de fluides. Il a été échantillonné sur 4 sites, en contact avec différentes roches encaissantes : granites Archéens, dolomies, quartzites et cornéennes. Les xénolithes calco-silicatés sont omniprésents dans ces portions du Platreef. Une contamination par des liquides de fusion partielle du granite est également mise en évidence. Les cumulats les plus affectés par l'altération se trouvent au contact des granites, qui constituent l'encaissant le plus fracturé. <br /><br />À l'échelle du complexe, le rapport fluide/roche des interactions est très faible : les circulations ont été confinées à des chenaux préférentiels. Les caractéristiques isotopiques et géochimiques des fluides ne correspondent pas à celles des eaux météoritiques. Ils étaient probablement originaires des formations sédimentaires proches et ont été expulsés lors de la perturbation thermique due à la mise en place des magmas du Bushveld. Ils contenaient du chlore et du CO2 leur permettant de jouer un rôle dans la distribution des PGE.

>Magister Scientiae - MSc / The Platreef, is a contact-type pyroxenitic reef in the Northern Limb of the Bushveld Complex, enriched in platinum group elements (PGE) and base metal sulfides (BMS). Relatively subdued mining in the Platreef, compared to RLS, has been attributed to limited knowledge regarding irregular distribution, complex style and genesis of PGE mineralisation in the Platreef. This study was, therefore, aimed at investigating the petrogenesis of the Platreef, particularly to evaluate whether the formation of the ore reefs resulted from a single or multiple sill-like magma intrusions. The study also sought to unveil the interplay of fractional crystallisation, hydrothermal fluid activities, floor rock and crustal contamination on the formation of Platreef types, PGE mineralisation and the magma source.