The Pliocene, a geologic epoch spanning ~2.6-5.3 million years ago (Ma), was a period in Earth’s history where temperatures were several degrees warmer than today and atmospheric CO2 was close to modern levels, making it an analogue for future climate change. Following this interval, the planet’s climate shifted to the familiar glacial-interglacial cycles of the Pleistocene (~0-2.6 Ma), beginning with the development of extensive Northern Hemisphere ice sheets at ~2.7 Ma. In response to these changes through the Plio-Pleistocene, several components of the Earth System, particularly related to East Asia and the North Pacific Ocean, varied both temporally and spatially, further modifying regional and global climate through various feedbacks. In this thesis, I utilize a combination of geochemical proxies derived from North Pacific marine sediments as well as a regional climate model to better understand the evolution of the westerly winds, North Pacific Ocean circulation, and East Asian desert landscapes, across the last five million years. In Chapter 1, I reconstruct Pliocene dust fluxes at two different sites in the North Pacific using the constant flux proxy extraterrestrial 3He (3HeET), the first of such records in the Pliocene. Along with 3HeET-derived export productivity fluxes and sea surface temperatures from the westernmost core, I show that the Northern Hemisphere westerly winds, were shifted poleward and weaker during much of the warm Pliocene. Coinciding with the intensification of Northern Hemisphere Glaciation, the westerlies shifted equatorward and strengthened at ~2.7 Ma, and during subsequent glacial periods thereafter. Combining my dust flux record with others from different ocean basin, I find that these changes in the westerly winds were globally synchronous. Chapter 2, entitled “Pliocene Variability of Active Pacific Meridional Overturning Circulation: Reevaluating North Pacific Productivity and Redox Conditions from ~2.5-6 Ma”, presents additional 3HeET-based export productivity flux data, as well as redox element concentrations, from the central subarctic North Pacific through the Pliocene. The new records suggest elevated North Pacific export production during the interval spanning ~4-5.5 Ma, followed by a decrease in the mid-Pliocene (~3.5-4 Ma). Combining this new data with previously published records and modeling output, I provide additional evidence for an active Pacific meridional overturning circulation during the warmer-than-present Pliocene, and add constraints on its variability under various climatic conditions. In Chapter 3, I bring together two constant flux proxy-derived dust flux datasets from the same core in the western North Pacific Ocean to provide novel insight into Quaternary dust dynamics in East Asia. By utilizing constant flux proxies, and accounting for inputs of volcanic material, I show for the first time that dust input to the North Pacific decreased over the last ~2.7 Myr, particularly during glacial periods. While quite different from other previously published dust datasets, this finding is consistent with our current understanding of East Asian dust production mechanisms, and acts as a strong impetus to perform more comprehensive studies of dust fluxes to the North Pacific and other depositional areas downwind of arid regions. Chapter 4 transitions to a terrestrial setting, in which I investigate the impacts of shifting arid region surface albedo on the atmospheric boundary layer using the Hami Basin, China, as a test location. Combining new simulations from the Weather Research and Forecasting base model and available geologic data, I report a previously undescribed “wind-albedo-wind” feedback process. Specifically, I propose that wind erosion, in conjunction with surficial sediments of various albedos, leads to altered wind speeds, and eventually fluctuations in erosion itself. In Chapter 5, I expand upon the work in the preceding chapter by coupling the Weather Research and Forecasting model with a chemistry component to simulate dust emissions. In addition, along with albedo, I characterize previously interpreted surface changes through time to reflect shifts in erodibility and surface roughness. I conclude that although albedo does ultimately influence near-surface wind speeds and dust emissions as predicted in my earlier study, the effects of variable surface roughness and erodibility dominate. Integrating these results with an updated interpretation of the geologic evolution of the Hami Basin, we find that during various periods of the last ~700 ky, the Hami Basin, and likely the greater stony Gobi Desert, could have been much more important dust sources than today.

The waters of the Indian Ocean southeast of Africa are a crucial junction for surface and deep ocean processes that serve as vital controls on Earth’s climate system. At the surface, the Agulhas Current, its retroflection, and Agulhas Leakage transfer water from the Indian and South Atlantic. The addition of this heat and salt to the Atlantic Basin helps drive the Meridional Overturning Circulation and the formation of deep water in the North Atlantic Ocean. On the timescales of centuries, the Meridional Overturning Circulation ultimately returns this water back to the Indian Ocean in the form of North Atlantic Deep Water. Proxy reconstructions show that the vigor of ocean overturning is immensely important to the global climate system, driving changes in atmospheric CO₂ concentrations and temperature and precipitation patterns across the planet. I use x-ray fluorescence core scanning, sediment provenance techniques, and core images from International Ocean Discovery Program Site U1474, located in the Natal Valley of the southwest Indian Ocean, to investigate past changes in the Agulhas Current and North Atlantic Deep Water. 40K/40Ar provenance ages measured on the clay fraction of sediment from Site U1474 indicate that, despite its great distance from the core site, the Zambezi is the most important factor influencing the deposition of terrigenous sediment in the Natal Valley. We present these results in a quantitative way, reinforcing the conclusions of previous studies. However, a comparison to newly available proxy records influenced by current speed and hydroclimate suggests that the strength of the Agulhas does not have a major influence on terrigenous sediment sources, at least at the headwaters of the Agulhas Current. Instead, I suggest that low-latitude hydrologic processes driven by zonal and meridional temperature gradients in conjunction with sea level are responsible for sediment source variability. In core photos, I found evidence for deep water variability in the Natal Valley in the form of millimeter-to-centimeter scale layers of olive-green sediment. To an overwhelming extent, these layers are formed during glacial periods, especially at their termination. I complement observations at Site U1474 with published proxy data for oxygen concentrations and measurements of total organic carbon percent in the Natal Valley and by extending our search for these green layers to core sites around the world. With these data, it is possible to confidently connect these layers to organic carbon concentrations in the sediment, reduction-oxidation processes in sediments following burial, and the local concentration of dissolved oxygen in the deep water. There are comparable fluctuations in the abundances of green layers in core sites in the path of North Atlantic Deep Water during glacial cycles, where more frequent and more intense green layer formation is driven by higher bottom water oxygen concentrations. Peaks in the abundance of green layers approximately 250 ka and 900 thousand years ago coincide with global scale excursions toward isotopically light benthic carbon isotopes. Connecting the green layers to the release of isotopically light organic carbon from sediments leads me to propose that long-observed fluctuations in the carbon cycle may be attributable to deep ocean oxygenation.

Located in the far western equatorial Pacific, the Western Pacific Warm Pool (WPWP) is a greater than 10 million km² area of the warmest water on the planet. The WPWP therefore facilitates intense atmospheric convection and participates in coupled ocean-atmosphere climate phenomena such as El Niño Southern Oscillation, regional monsoons, and the shifting Intertropical Convergence Zone. The WPWP is also a water mass crossroads where thermocline-depth western boundary currents (WBCs) such as the New Guinea Coastal Undercurrent (NGCUC) facilitate the transfer of mass, heat, and nutrients vertically, zonally, and meridionally in the ocean. In this dissertation I focus mostly on reconstructing WPWP upper ocean temperature, salinity, nutrient, and productivity dynamics via a suite of physical and geochemical paleoclimate proxies. I apply these proxies in bulk sediments and planktic foraminifera from International Ocean Discovery Program (IODP) Site U1486 over the Pleistocene (2580 ka to 11.7 ka) and Holocene (11.7 ka to present). Site U1486 is located at 2°22’S, 144°36’E in the Bismarck Sea north of New Guinea in the southern WPWP, and is ideally situated to track changes to the WPWP upper water column forced by the South Pacific. The presence of glacial-interglacial (G-IG) variability within WPWP records is particularly important for determining local versus high-latitude climatic influences on the WPWP – with climate shifts such as the mid-Pleistocene Transition (MPT; ~1250 – 700 ka) and mid-Brunhes Event (MBE; ~430 ka) of particular interest in the long-term records I present. In chapter 1, I explore the paleoceanography of the low-latitude Pacific via upper ocean nitrate dynamics. I present a new bulk sediment ẟ¹⁵N record from Site U1486 that spans from 1420 to 0.67 ka – over a million years longer than any nearby records. Via analysis of orbital variability and secular trends at Site U1486 and in records directly along the equator in the Pacific, I find that nitrate dynamics were largely unrelated in the two regions in the Middle and Late Pleistocene. Whereas ẟ¹⁵N at Site U1486 is in line with patterns of eastern Pacific denitrification, increasing ẟ¹⁵N after the MPT at sites located directly along the equator appears linked to increasing Southern Ocean nitrate utilization. Enhanced nitrate utilization is an indicator of a strengthened biological pump – a major contributor to the reduction of atmospheric 𝑝CO₂ during the last glacial. A post-MPT increase in nitrate utilization may therefore point to the Southern Ocean biological pump as a driver for the deeper and longer glacial periods of the 100-kyr world after the MPT. In Chapter 2, I investigate changes in the vertical temperature and salinity structure of the southern sector of the WPWP in relation to the upper ocean’s response to climate change. When combined with Mg/Ca paleotemperatures and δ¹⁸O_sw, my 670-kyr record of Δẟ¹⁸O between the surface-dwelling foraminifera Globigerinoides ruber (sensu stricto) and the thermocline-dwelling foraminifera Pulleniatina obliquiloculata and Globorotalia tumida suggests enhanced thermocline shoaling and a progressively increasing vertical salinity gradient commencing near 240 ka. This secular change in upper water column dynamics does not appear to be associated with previously documented changes in G-IG variability such as the MPT or MBE. Via comparison to other records, I identify widespread cooling of the thermocline in the equatorial Pacific after ~240 ka. After combining these reconstructions with ²³⁰Th-derived focusing factors I validate previous model results indicating obliquity-driven strengthening of low-latitude ocean currents and extend this to imply the periodic increased transport of high-salinity thermocline water masses. These results strengthen previous evidence that the structure of the WPWP thermocline is relatively independent from the drivers of climate at the surface and support that variability in WPWP thermocline circulation is substantially influenced by obliquity. Because of the nitrate dynamics in the Bismarck Sea, bulk sediment ẟ¹⁵N cannot be used to reconstruct productivity. However, chapter 3 constrains variability in productivity via the analysis of new ²³⁰Th-normalized records of preserved biogenic flux and its components at Site U1486 over the last 138 kyr. Here, I assess the drivers of variability in paleo-productivity by reconstructing paleo-stratification, as in the modern Bismarck Sea productivity is stimulated by the delivery of nutrients to the surface during increased upwelling (reduced stratification). Paleo-stratification is approximated by calculating upper ocean density gradients between the calcification depths of G. ruber, P. obliquiloculata, and G. tumida using Mg/Ca temperatures and δ¹⁸O_sw-estimated salinity. Decreased paleo-stratification (a reduced vertical density gradient) was associated with increased productivity and is generally in phase with maximum orbital precession. Paleo-productivity therefore appears to respond to monsoonal increases in coastal upwelling when the Intertropical Convergence Zone (ITCZ) was at its southernmost extent. This illustrates that the unique and more direct method of constraining stratification presented here, which is subject to greater uncertainty, yields results consistent with our current understanding of upper ocean dynamics. I also identify a period between 100 and 60 ka during a potential reorganization of the upper water column in which variability in productivity occurs at a higher frequency than that of precession. Finally, while also related to ITCZ shifts, a nearby record closer to the equator is phase-lagged from Site U1486 – emphasizing the fine-scale regional differences in the drivers of primary productivity in the WPWP.

Seafloor sedimentary depositional and erosional processes create a record of near and far-field climatic and tectonic signals adjacent to continental margins and within oceanic basins worldwide. In this dissertation I study both modern and paleo-seafloor surface processes at three separate and distinct study sites; Cascadia offshore Oregon, U.S.A., the Eastern North American Margin from south Georgia in the south to Massachusetts in the north, and the Deep Galicia Margin offshore Spain. I have the advantage of using modern geophysical methods and high power computing resources, however the study of seafloor processes at Columbia University's Lamont-Doherty Earth Observatory (LDEO) stretches back over ~80 yrs. Specifically I use data collected during a variety of geophysical research cruises spanning the past ~50 yrs.-the majority of which can be directly attributed to seagoing programs managed by LDEO. The modern seafloor is the integrated result of all previous near and far field processes. As such, I look below the seafloor using multi-channel seismic reflection data, which is the result of innumerable soundings stacked together to create an image of the sub-seafloor (paleo) horizons. I map, analyze and interpret the sub-seafloor sedimentary horizons using a variety of both novel and established methods. In turn, I use multi-beam sonar data, which is also the result of innumerable soundings to map, analyze, and interpret the modern seafloor topography (bathymetry). Additionally, I look to the results from academic ocean drilling programs, which can provide information on both the composition and physical properties of sediments. The sediment composition alone can provide important information about both near and far-field processes, however when supplemented with physical properties (e.g., density/porosity) the results become invaluable. In my second chapter, I use a compilation of multi-beam sonar bathymetry data to identify and evaluate 86 seafloor morphological features interpreted to represent large-scale erosional scours not previously recognized on the Astoria Fan offshore Oregon, U.S.A. The Astoria Fan is primarily composed of sediments transported from the margin to the deep ocean during Late Pleistocene interglacial periods. A significant portion of the sediments have been found to be associated with Late Pleistocene outburst flood events attributed to glacial lakes Bonneville and Missoula. The erosional scours provide a record of the flow path of the scouring event(s), which if well understood can provide important information for the study of past earthquakes as the sedimentary record remains intact outside of the erosional force created by the massive flood events. I design and implement a Monte Carlo inversion to calculate the event(s) flow path at each individual scour location, which results in a comprehensive map of Late Pleistocene erosion on the Astoria Fan. The results indicate that at least 4 outburst flood events are recorded by the scour marks. In my third chapter, I build a stratigraphic framework of the Eastern North American margin using a compilation of multi-channel seismic data. Horizon Au is a primary horizon within the stratigraphic framework and is thought to represent a significant margin wide bottom-water erosional event associated with subsidence of the Greenland-Scotland Ridge and opening of Fram Strait in the late Eocene/early Oligocene. A recent study found that the bottom-water was enriched in fossil carbon, leading us to hypothesize that the bottom-water erosion recorded by horizon Au may have been facilitated by chemical weathering of the carbonate sediments. I use sediment isopach(s) to build a margin-wide model of the late Eocene/early Oligocene continental margin in order to estimate the volume of sediments eroded/dissolved during the event marked by horizon Au. The results indicate that ~170,000 km3 of sediments were removed with a carbonate fraction of 42,500 km³, resulting in 1.15e18 mol CaCO₃ going into solution. An influx of this magnitude likely played a role in significant climatic changes identified at the Eocene-Oligocene transition (EOT). In my fourth chapter, I use a combination of 3D multi-channel seismic and multi-beam sonar bathymetry data collected during the Galicia 3D Seismic Experiment in 2013. The Galicia Bank is the largest of many crustal blocks and is located 120 km west of the coast on the Iberian Margin. The crustal blocks have been attributed to the opening of the North Atlantic Ocean in the Late Triassic/Middle Jurassic. The Galicia Bank is the source for the majority of sediments delivered to the Deep Galicia Margin, the focus of this study. I map the seafloor and 5 paleo-seafloor surfaces in order to study controls on sediment delivery provided by the crustal blocks. The results show that the crustal blocks begin as a barrier to and remain a primary control on sediment delivery pathways to the Deep Galicia basin. Additionally, the paleo-seafloor surfaces record morphological structures that can inform us on both near and far field past climatic and tectonic events e.g., the Alpine Orogeny and Pleistocene inter-glacial periods.

We use sedimentary structures, fossil evidence, sediment petrophysical properties, and geochemistry to investigate past climate. In the first two chapters, we outline a toolkit to identify the presence of ice rafted debris in lake sediments using a combination of grain size analysis, computed tomography and image analysis. We apply this toolkit to sediments from the early Mesozoic, paleo-Arctic Junggar Basin, and describe the first evidence of continental freezing from this time period. We also discuss characteristics of algae rafted debris; clusters of coarse sediment suspended in a fine sediment matrix can be deposited without freezing conditions and may be a confounding factor in the geological record. In chapters three and four, we examine sediment cores from the coast of New York and the effects of sea level rise after the last deglaciation. New AMS radiocarbon dates from submerged terrestrial sediments on the US Atlantic continental shelf provide key constraints on the timing of marine transgression following the retreat of the Laurentide Ice Sheet. We use sediment elevation tables (SETs) and sediment cores to measure the accretion rate in a Hudson River tidal wetland to determine its vulnerability to sea level rise. We find that SETs overestimate accretion and underestimate vulnerability on timescales relevant to coastal flooding risk. Together, these chapters outline novel tools and approaches in imaging, geochemistry, and micro-stratigraphy broadly applicable for investigations on paleoclimate research through time and space.