This study focuses on determining the quality of soil and groundwater at the Onderstepoort Municipal Solid Waste (MSW) landfill site. The study area is situated in Pretoria North, a jurisdiction of City of Tshwane Metropolitan Municipality (CTMM). Samples were collected from three different spheres (i.e. leachate, soil and water) in the study area, to determine the concentration of metals accumulated in each sphere. The three spheres provided an overview of the contaminants found in leachate, soil and water. The laboratory analyses using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) indicated that soils in the site have been severely contaminated with heavy metals. Higher concentrations of heavy metals occurred in the soils compared to the groundwater surrounding the landfill site and this may be due to the ability of the soil strata to absorb the contaminants caused by the landfill leachate. In essence, the measurements indicated that leachate soil has very high pollutant levels (0.21 to 2505.61 mg/kg); soil was characterised by fairly-high pollutant levels (0.03 to 638.27 mg/kg); leachate solution has given rise to moderate pollutant levels (0.01 to 2.296 mg/L) and water resources have low-moderate pollutant levels (<0.0001 to 0.456 mg/L) depending on the location. Furthermore, the findings indicated that the soil was contaminated with lead, cadmium, copper, zinc and nickel, and the concentration increases particularly where the generation of leachate is taking place. Groundwater, particularly in Borehole 2 has been moderately contaminated with nitrite, calcium and manganese. The findings also indicated that the concentrations of contaminants become high in borehole located close to the waste dump and decrease further away from the waste dump. The chemical analysis of this groundwater indicated that the concentrations of chemical properties have increased since the year 2009. This was determined through the comparison of groundwater study undertaken in 2009 to the current study results obtained. The site geological formation, Rustenburg Layered Suite is known to contain the anomalies of nickel, chromium, vanadium, copper, arsenic, lead and zinc but these are less toxic and less distributed. Therefore, the primary source of pollution at the study area could be the landfill operation through the generation of leachate affecting both soil and water / College of Agriculture and Environmental Sciences / M. Sc. (Environmental Sciences)

Dissertation submitted in compliance with the requirements for the Master's Degree in Technology: Biotechnology, Durban Insititute of Technology, 2003. / Stimulated by the findings of international researchers, that the sulfate-reducing microorganism Desulfovibrio desulfuricans could be incriminated in the process of mercury bio-methylation, it was decided to test this hypothesis on sediments from selected areas of Durban Bay where elevated levels of the bio-hazardous heavy metal had previously been detected. The Environmentek Division of the Council for Scientific and Industrial Research (Durban) is involved in an ongoing chemical assessment of heavy metal contamination (including levels of mercury) in the sediments of this estuary, but nothing is currently understood about the form in which mercury exists or the biological processes that could be determining its fate. The purpose of this project was to attempt to answer some of these questions. The study involved attempting to isolate, identify and quantify microorganisms of the species Desulfovibrio desulfuricans, Escherichia coli and Clostridium perfringens in one hundred and eighty sediment samples taken from three designated sites in the bay. Each sample was additionally analysed for total and methyl mercury and sulfate content, as well as a number of physical parameters. Based on the outcome of the initial survey, it was envisaged that further laboratory experimentation would be conducted to determine whether or not isolates were responsible for the production of the highly toxic organic mercury and whether this process was occurring in situ in the sediments. The findings of this project were contrary to what had been expected. Total mercury concentrations (apart from one instance) did not appear to be appreciably elevated in the areas under study. Similarly, the levels of methyl mercury were fourrd to be either diminished or absent. Numbers of D. desulfuricans were low and not uniformly distributed throughout the sediments. Cl. perfringens was more in evidence, but counts were not perceptibly increased. Sulfate levels were consistently high, indicating significantly impaired rates of sulfate reduction. Difficulty experienced in sub-culturing / M

M.Sc. / Victoria Lake also known as Germiston Lake is an urban impoundment which is situated east of Johannesburg. This Lake is used for a number of recreational activities and can be viewed as an important feature of this area. It is a natural perennial pan and has several inlets (inflows) which drain a part of Germiston's business area and surrounding residential areas. In the past various studies have focused on the water quality as well as other aspects of the ecology of the Lake that may influence recreational activities and the physical-chemical quality of the water. However, information on the physical-chemical quality of the inflow water is poorly investigated and needs further attention. This study gathered further data on the water quality and associated problems within the major inlets to the Lake. Six inlets were monitored monthly for a year. The water samples that have been collected were analyzed for several physical and chemical constituents. In general it seemed as if the waters of the inlets around Victoria Lake were more polluted in comparison to the surface waters of the lake Sites 1, 4 and 5 seemed to be the most polluted inlets and it should be closely monitored in future. Most of the water quality constituents that have been compared with the water quality criteria exceeded the acute effect values given by the South African Water Quality Guidelines. Waste is thus continually dumped into the Victoria Lake via the major inlets resulting in water pollution. The quality of this resource is therefore diminishing rapidly. If Victoria Lake is to be successfully used and managed in order to limit the impact on the environment, all further development and management should take place in terms of sustainable development.

A dissertation submitted to the Faculty of Science, University of the Witwatersrand in fulfilment of the requirements for the degree of Master of Science Johannesburg 2017. / The development of the economy of South Africa and many other countries has been highly dependent on mining industries. Minerals such as gold, platinum, diamond and many others have been mined and continue to be mined. Despite the importance of these minerals, their processing comes with social and environmental problems. During the processing of these minerals, trace elements such as copper, chromium, nickel, mercury, uranium, molybdenum and many others are released as wastes into the environment either, directly or indirectly. The release of the elements into the soil is of concern due to the possibility of groundwater system contamination. The presence of these elements in the groundwater system poses serious challenges to the wellbeing of life forms, due to their toxicity, when they exceed threshold limits. From the processing plants, these elements could be released onto the soil, and mobilise to groundwater, increasing the already existing environmental crisis due to water pollution. Once these elements are in the water, access to living organisms becomes easier through the food chain. Some of these elements are not biodegradable and thus persist in the environment as well as in the bodies of living organisms. They can cause serious health problems because of their toxicity effect. In humans, these elements can be carcinogenic, and also cause chronic disorders, kidney failures, defects in infants, bone and vascular diseases which could also be lethal. It is therefore of importance that these elements are neither bioavailable nor bioaccessible to living organisms. When these elements are mobile in the soil, the probability of reaching groundwater increases. Water, an important natural resource should always be protected from such pollutants. The demand for unpolluted water has been rising every year in the world due to increasing population, extended droughts and improper disposal. This research was dedicated to determining the behaviour of elements in an agricultural soil impacted by mining activities. Agricultural soils are sometimes exposed to pollutants that could originate from dust fallout or precipitation; fertilisers and manure; pesticides; and water used for irrigation. Understanding the iv processes that control the distribution of these pollutants in agricultural soils is an important risk assessment measure, considering that such pollutants have the potential of being taken up by crops and vegetables or transported to groundwater. In this study, a soil on a farm that grows vegetables for commercial purpose. Cabbage, spinach, carrots and potatoes are some of the vegetables grown on the plot and sold to markets in Pretoria and Johannesburg. The plot is in the vicinity of smelting operations in the North West Province. The mobility of trace elements in the soil can be controlled, depending on the type and properties of soil. Hence in this research, the ability of the soil to adsorb elements entering the soil is studied. The batch experimental work was performed to determine the effect of pH, initial concentration (5 - 100 mg/L), competing ions (Fe3+, Ca2+, Co2+, Mg2+, K+, Ni2+ and Zn2+), fertilisers (ammonium nitrate, ammonium phosphate and calcium chloride) and plant exudates (acetic acid, citric acid and oxalic acid as well as ethylenediaminetetraacetic acid (EDTA) which is often used as proxy organic ligand (found in manure)) on the adsorption of cadmium (Cd), copper (Cu) and chromium (Cr) onto an agricultural soil. The PHREEQC geochemical modelling code was used to complement experimental methods in predicting processes and to further assess the leaching behaviour of the elements. Powder X-ray diffraction (PXRD) and X-ray fluorescence (XRF) were used to determine the mineralization of the soil. The structural features of the soil were determined using Fourier Transform Infrared spectroscopy (FTIR) and the element content was determined using Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES). The point of zero charge (PZC) of the soil was found to be 8.3 and the cation exchange capacity (CEC) of 51.6 meq/ 100g. In the absence of fertilisers and plant exudates, the soil exhibited a similar high adsorption for elements at all initial concentrations by all the elements. Most (> 90%) of the elements were adsorbed within the first 3 minutes of contact with the soil. Langmuir, Freundlich and Dubinin-Radushkevich adsorption isotherms were used to describe the experimental data for the elements. Kinetic rates were modelled using pseudo first-order and pseudo second-order equations. Pseudo v second-order gave the best fit for all the elements (R2 >0.999) indicating chemisorption. The effect of pH on Cd and Cu was insignificant however, the adsorption of Cr decreased with pH. The presence of competing ions decreased the adsorption of cadmium more than that of the other analyte elements. The soil was generally effective in adsorbing and retaining the elements. However, the retention was highly dependent on elemental speciation and prevailing conditions e.g. pH (as in the case of Cu and Cr). Such changes in conditions would have implications for groundwater quality. The effect of plant exudates and EDTA was studied and the results showed that low molecular weight organic acids (LMWOAs) viz acetic acid (AA), citric acid (CA) and oxalic acid (OA) and EDTA significantly (p < 0.05) decreased the adsorption capacity of the elements onto the agricultural soil. AA had the least effect on the adsorption capacity of the elements whereas OA and EDTA strongly prevented the adsorption of the elements. Moreover, some of the elements which were already in the soil including those which were not under study such as Ca and Mg were desorbed from the soil by OA and EDTA. Thus, the mobility of the elements was increased by the presence of plant exudates, increasing groundwater contamination and consequently threatening the health of living organisms. Agrochemicals such as fertilisers, stabilizers and pesticides are constantly applied to agricultural soils to improve the fertility of the soil for better crop production however; their presence may affect the mobility and bioavailability of elements in the soil. The effect of ammonium nitrate and ammonium phosphate as well as calcium chloride on the adsorption of Cd, Cu and Cr onto an agricultural soil was studied. The effects of initial concentrations of the elements (5 – 50 mg/L), concentrations of fertilisers (0.01 – 0.1 mol/L) and pH (3 - 8) on the adsorption of Cd, Cu and Cr were studied. The initial concentration of the elements and the concentration of fertilisers had no significant effect (p > 0.05) on the adsorption capacities of Cu and Cr at pH 5. But, ammonium nitrate and calcium chloride decreased the adsorption capacity of Cd. The adsorption of Cd onto the soil was reduced as the concentration of fertilisers increased. The adsorption of Cd was lower than that of Cu and Cr at all pH values. The agricultural soil was found to vi be an effective adsorbent in preventing the mobility of Cu and Cr in the presence of fertilisers but not for Cd whose adsorption was significantly affected by the presence of ammonium nitrate and calcium chloride. A continuous flow fixed-bed column script with specified conditions simulating the natural environment was utilised in PHREEQC for column studies. The geochemical computer model PHREEQC can simulate solute transport in soil surfaces. The effect of initial concentration (100 and 300 mg/L) of the elements, column bed depth (5 and 10 cm) and pH (3, 5, 7 and 10) were considered in this study. The adsorption capacity was affected by initial concentration of the elements since the breakthrough curves at higher analyte concentrations were reached at lower pore volumes than at low concentrations. This can be attributed to the fast occupation of active sites of the soil at higher concentrations. The results from PHREEQC indicated that the conditions used would lead to the oxidation of Cr3+ to Cr6+ leading to the formation of HCrO4- and Cr2O72- which were not favoured for adsorption by soil surfaces due to high solubility. This could have potential implications on the quality of groundwater in regions with similar conditions. Thus, the leaching of Cr6+ onto the agricultural soil will be high in areas where remediation techniques are not applied. The changing of bed depth from 5 to 10 cm did not have an effect on the adsorption of the elements. The ability of the soil surfaces to adsorb Cd and Cu even at lower bed depth implies that the soil will be effective in preventing the leaching of the elements to groundwater due to strong surface interactions of the elements with the soil. The results from PHREEQC showed that the adsorption of Cd and Cr onto the soil surface was not affected by pH. The results for Cr were contradicting with those obtained from laboratory experiments which could be due to the conditions used in PHREEQC. The change in the speciation of Cu at basic conditions decreased the ability of Cu adsorption onto the soil surfaces. The Cu2+ was converted to Cu(OH)2 which were large in size and thus only a small amount could be adsorbed since the other adsorption sites were covered by the large species. This research had notable outputs in the form of publications which will form an important repository of information. / LG2017

Annually, the global environment receives enormous amounts of persistent organic pollutants (POPs) that include polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs), in addition to polycyclic aromatic hydrocarbons (PAHs). Their ubiquity has made them identifiable contaminants in almost every environmental compartment of the global system. In particular, aquatic systems have been adversely affected by these pollutants. Therefore, effective monitoring, both in ground and surface water, that can reliably assess their environmental impacts is required. Passive samplers have been proposed as suitable options to the traditional grab/spot/bottle sampling approach because they simultaneously sample, isolate and enrich target analytes. Moreover, apart from successfully detecting very low water dissolved analyte concentrations (trace and sub-trace levels), the devices can also provide time weighted average (TWA) concentrations that take into account episodic events. This is usually not practical with other sampling techniques.

Thesis (MTech (Environmental Management))--Cape Peninsula University of Technology, 2010 / Freshwater scarcity and river pollution has become a serious challenge for governments and scientists. Worldwide, governments have a responsibility to provide their populations with enough clean water for their domestic needs. Scientists will have an enormous task to find a way to purify polluted water, because of its vital role in human lives and an increasing demand for water consumption due to population growth. Although the water from the Bottelary River is used on a daily basis for farming activities, its pollution level as well as spatial distribution of effluents in the catchment is unknown. In the present study, I took monthly water samples from six sampling points for laboratory analysis. The laboratory determined concentration levels of phosphorous, chloride, nitrate, and nitrate nitrogen (N03N), as well as the chemical oxygen demand (COD) and suspended solids from the samples. On the same occasion's pH, dissolved oxygen, electrical conductivity and temperature were measured in-situ using a multi-parameter reader. The results were then compared with the South African Water Quality Guidelines for Aquatic Ecosystems and for irrigation (DWAF, 1996a, 1996c). The non-point pollution source (NPS) model was used to generate predictions of the pollution level from the land-uses and use the data obtained from the field to validate the model predictions. Finally, I performed a two-factorial A One-way Analysis of Variance (ANOVA) without replication to assess the spatial and temporal variation of the measured variables along the river. The findings of the study have shown that the concentration levels of some compounds are below the Target Water Quality Range (TWQR) set by the Department of Water Affairs and Forestry (DWAF, 1996a, 1996b, 1996c) while, the concentrations of chloride, total nitrogen and water quality variables such as electrical conductivity, suspended solids, are higher than the TWQR (DWAF, 1996a, 1996b, 1996c). Based on the above findings water of the Bottelary River can have negative effects on the environment and human lives because of the concentration level of these compounds. It was therefore recommended that, environmentally friendly measures and practices must be undertaken in order to decrease the pollution and avoid further pollution of the river.

A dissertation submitted in fulfilment of the requirements for the degree of Master of Environmental Science. with Witwatersrand University, Johannesburg, South Africa, (School of Geography, Archaeological and Environmental Science within the Faculty of Science) 2nd June 2017. / Hydraulic fracturing in the Karoo is said to be a game changer of energy sector in South Africa, but it is said to pose potential groundwater contamination. Therefore the aim of the study was to investigate the extent to which current institutional set up in South Africa can deal and address potential environmental challenges that are associated to fracking. The study was particularly interested in investigating the institutional capabilities in the context of water management. The literature review of this study showed that water resource is a major environmental concern that revolves around hydraulic fracturing, including the water resources use and potential contamination. In addition, it should be considered that hydraulic fracturing is a new mining process in South Africa and Africa as a whole with controversial mining techniques and environmental impacts involved within this process. The review indicates that the biggest issue with proposed hydraulic fracking mining process in the Karoo is if the South African Government has taken into consideration the resources, infrastructures and skills to execute the process successfully. The literature asserts that even if proper enforcement of any regulations on this rapidly expanding industry will still be difficult as the regulation is insufficient due to certain explicit exemptions. In South Africa, the starting point for hydraulic fracturing and the associated regulations that governs fracking, is the recognition of an argument that South Africa does not possess any fracking specific laws, guidelines or even polices. Research participants were asked to give their views on the research topic by answering the semi structured interview questions. Data from the semi-structured interviews and literature review was analysed and discussed to address the research questions. The results of the investigation confirmed that there was no any legislation in place to govern this mining process in South Africa. Currently there are legislations which are under review and development to also address hydraulic fracking and the protection of water resources. The government should also involve other research institutes in the drafting and decision making of the legal institute governing hydraulic fracking to ensure that all gaps are identified before fracking can be permitted in the Karoo. / MT 2017

A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg, in fulfilment of the requirements for the degree of Doctor of Philosophy. Johannesburg, August 2015. / Petrol and diesel fumes are known to be anthropogenic sources of air pollutants that have a negative impact on both environmental and human health. In developing countries, attendants are still employed to pump fuel for customers. In South Africa gas pump attendants refuel vehicles with various octane unleaded petrol, lead replacement petrol (LRP) and diesel on a daily basis. Attendants are particularly at risk to adverse health effects associated with inhalation of hazardous air pollutants (HAPs). Of increasing concern in recent years are the volatile organic compounds (VOCs), with particular reference to the six aromatic hydrocarbons (benzene, toluene, ethyl benzene and three isomeric xylenes), namely the BTEX.

Thesis (MTech. degree in Environmental management.)-Tshwane University of Technology, 2008. / Aims to generate information on the quality of water from boreholes and the Steelpoort river in order to ascertain the level of pollution within the vicinity of Vantech mine. The information is envisaged to help a better water management within the area. The following objectives were pursued: to measure water quality parameters ; to investigate the extent of the pollution plume movement ; to study the composition and geological factors in the area in relation to mobility of groundwater and to determine the impacts of Geo hydrological characteristics.

Amongst others, the South African National Water Act No. 36 of 1998 acknowledges that access to sufficient safe and clean water is a basic right to all South Africans. However, it is well known that millions of inhabitants of rural communities in South Africa are still deprived of this right. Many rural communities in South Africa are thus consuming unsafe, untreated water everyday, thereby exposing themselves to waterborne diseases. The main reason of concern however is the fact that, nevertheless, little is known about rural water quality in South Africa as most water quality work is being undertaken in urban areas. The study's aim is twofold: first, the study examines the impact of Black rural communities' land-use and related activities on water quality and second is specifically, to study the washing practices of the rural communities in the upper Kat River area. To understand the potential impacts of the upper Kat River Black village communities and their associated land-use practices on the quality of upper Kat River catchment, prominent land-use and related activities in the area were investigated. Study area maps were studied and field surveys undertaken to observe major land-use and related activities in the area. The results of the study show that most used land in the area is being utilised for agricultural activities. Settlements and commercial forestry also occupy considerable areas of land. The literature survey suggests that such land-use could have a considerable degrading impact on the quality of both surface and groundwater. The study also investigated the impact of the in-stream use of detergents on water quality in the upper Kat River valley, Eastern Cape - South Africa. In-stream washing practices of certain communities in the upper Kat River valley were investigated and the impact of detergents on water quality was assessed. Recovery of the flow from the input of detergents was also measured. During the study, it has been ascertained that doing laundry by the stream is the common practice in the study area. Water quality analysis results show a remarkable increase on the levels of chloride, turbidity, and electrical conductivity in water as a consequence of direct input of detergents practice into the river during the washing. The recovery of the water quality at a distance of 1km from site of input was almost complete. Water quality monitoring programme was undertaken to establish a link between land-use and the quality of water. In a water quality study routine carried out for a period of 40 weeks on a twice monthly frequency, the state of the flows of the river was determined; water samples were collected at pre-determined points; and the in situ analysis of selected water quality variables (with the exception of the faecal coliforms whose analysis was carried out in the biotechnology laboratory) was carried out. Results of the study showed that the concentration of the studied water quality variables in the area varied widely with time. A clear distinction in concentration of variables such as electrical conductivity, turbidity, pH, total hardness, chloride, and nitrate was evident at the high compared to the low flow period of the study. The concentration of the studied water quality variables in the upper Kat River catchment area also seemed to vary over space. The concentration of variables such as electrical conductivity, pH, total hardness, chloride, nitrate, potassium, number of faecal coliform bacteria per 100ml was observed to be higher in most of the tributary streams than the main river. Turbidity however was orders of magnitude higher in the Kat River than the rest of the tributaries. Most importantly however, results of the study showed that there is a strong link between the quality of water and land-use and related activities in the area. The spatial results of the study showed a strong connection between some land-use and the concentrations of water quality variables. For example, areas of intense grazing were noted with high concentrations of nutrients like nitrate and a higher number of faecal coliform bacteria per 100 ml of water. It was established during the study that land-use and related activities in the upper Kat River valley are negatively impacting on the quality of water thereby rendering it less fit for use for domestic purposes. The continued use of the polluted water by the communities is thus accompanied by a danger of the outbreak of waterborne diseases like cholera. When the concerned communities met in a workshop to discuss the issue of quality of their water, they committed themselves to: • shunning water polluting activities, • at least boiling their drinking water before consuming it. The communities also requested a meeting with the Department of Water and Forestry officials to request a treated, piped supply of water. / KMBT_363 / Adobe Acrobat 9.54 Paper Capture Plug-in