The project deals with a new building of a polyfunctional house in Hodonín. The object has four overground floors. Two law offices and three garages are designed on the ground floor. The other floors will house a total of 5 flats. The object is projected from the KM Beta system. The roof is flat.

The subject of the master´s thesis is a design of polyfunctional residential building. The residential building is partly basament and has four floors and ten flats. Two flats are maisonettes. On the first floor are a cosmetics salon and a massages salon. The thesis contains a dispositional and building construction design and elaboration of the given part of implementary project documentation.

Following the surrounding local urban structure I have designed the block structure of buildings. One of the blocks were chosen for polyfunctional building that include mix of urban dwellings – shopping floor in ground floor and offices in the second floor. These functions are supplemented by three floors of rent apartments, senior living and apartments in public ownership. The central part of building is courtyard surrounded by porch, terraces and balconies.

Diploma thesis deals with the new use of the former Franciscan monastery and the modification of the so-called Roman Square in Brno. This district was once Jewish quarter and still has a unique genius loci. The main new function of the monastery is a new branch of the diocesan museum. The Roman Square is a set of diverse places no longer found in the center of Brno. Interventions in its structure are kept to a minimum, in particular the addition of buildings at the gaps. A valuable passage element in the northeastern sector remains accessible through the arcade on the ground floor of the block of flats no. 2. In addition, a new passage will be created in the northwest sector with a covered market. Thanks to these interventions, the whole space of the square will be revived and made more attractive with regard to monument restoration.

Design of residental house with coffee bar, gallery and commercial pit, that divides site on public sace, semi-public space and part with flats. Due to narrow site is most of flats maisonette, with built-on gallery. Most important is quality of flats and urban design concept of integration new building to old structures.

The project of multifunctional building on Křížová street solves building over a gap at the end of the street next to the Mendel Square. The idea was to create a building that would usefully complement the existing block structure. The concept of urban multipurpose derives from the specific shape of the parcel as defined in the terms on which stands the main dark structure. This mass is penetrated by irregular cell structure of flats, which grid influences the whole interior layout. The whole building has four floors of underground parking, a ground floor with a café and shops and six floors of residential apartments from studio flats to 3 bedroom flats and luxury apartments on the roof.

The subject of the Master's Thesis is a site located in Stare Brno district, close to the city centre. It deals with a corner gap-site defined by the streets Pekařská and Anenská. The proposed buildings complete the surrounding streets and they react to neighbouring buildings by their mass and height. The polyfunctional buildings are divided into four objects. On the most prominent place of the corner there is an office building with a café on the ground floor. Three apartment buildings open to the courtyard with greenery by loggias.

Le travail présenté dans ce manuscrit concerne la conception et les études magnéto-structurales de nouveaux systèmes de Fe(II) à transition de spin (TS), en particulier ceux faisant intervenir les tétraazamacrocycles fonctionnalisés et les ligands de type 4-R-1,2,4-triazole. L’objectif principal est l’étude de l’effet de substitution ou de solvants (ou mélange de solvants) sur le comportement élastique de ces matériaux originaux. Dans un premier temps, nous avons étudié l’effet de solvant et contre-ions sur les propriétés de commutation, dans une série des complexes [Fe(L2)](X).nH2O (L2 = 1,8-bis(2’-pyridylméthyl)-1,4,8,11-tétraaza-cyclotétradécane, X = 2(tcm)- = 2[C(CN)3]-, n = 2 (1) ; X = [Ni(CN)4]2-, n = 1 (2) ; X = (BF4)-, n = 1 (3)). Cette étude a clairement élucidé l’effet crucial des interactions hydrogène, à travers les contre-ions et les molécules de solvants, sur la coopérativité observée dans la série des trois sels. Dans un second temps, l’utilisation des ligands de type 4-R-1,2,4-triazole nous a permis l’étude de deux systèmes commutables : (i) le premier concerne un complexe trinucléaire de formule [Fe3(furmetrz)6(tcnsme)6] (furmetrz = 4-(furan-2-ylmethyl)-1,2,4-triazole ; (tcnsme)- = 1,1,3,3-tétracyano-2- thiométhylpropenure), pour lequel les études magnétiques ont mis en évidence une transition thermique en deux étapes et un effet LIESST avec une T(LIESST) de 58 K. La comparaison de ce dérivé à d’autres systèmes similaires, mais présentant une transition de spin en une seule étape, révèle que la présence de deux étapes est favorisée par de fortes interactions le long de l’axe du trimère ; (ii) le second système concerne l’étude de plusieurs séries de matériaux polyfonctionnels exhibant la transition de spin et la photoluminescence. Le résultat le plus marquant concerne la synthèse et l’étude du complexe mononucléaire [Fe(naphtrz)6](tcnsme)2.4CH3CN (naphtrz = N-(1,2,4-triazol-4-yl)-1,8-naphthalimide) pour lequel les études magnétiques et optiques ont montré l’existence des deux propriétés, d’une manière synergétique. Ce résultat prouve la possibilité de contrôler, sans ambiguïté, les propriétés optiques par des excitations extérieures telles que la température, la pression, la lumière, … Au-delà de l’aspect fondamental, ce travail ouvre aussi des perspectives très originales pour l’utilisation de ces matériaux comme capteurs ou étalons de température. / This work is dedicated to the design and magnetostructural studies of new Fe(II) spin crossover (SCO) systems, in particular those involving the functionalized macrocycle and the 4-R-1,2,4-triazole triazole ligands.The principal objective concerns the study of the substitution and solvent effects on the SCO characteristics. In the first step, we have studied the solvent and the counter-ion effects, on the SCO behavior, in the series [Fe(L2)](X).nH2O (L2 = 1,8-bis(2’-pyridylméthyl)-1,4,8,11-tétraaza-cyclotétradécane, X = 2(tcm)- = 2[C(CN)3]-, n = 2 (1) ; X = [Ni(CN)4]2-, n = 1 (2) ; X = (BF4)-, n = 1 (3)), based on the macrocycles ligands. We have clearly shown in this study that the strong cooperative effects are mediated by the water solvent molecules and the counter-ions involved in the hydrogen bonding in the crystal packing. In the second step, the use of the 4-R-1,2,4-triazole fuctionalized triazole ligands led us to two original switchable systems: (i) the first one concerns the trinnuclear complex of formulae Fe3(furmetrz)6(tcnsme)6] (furmetrz = 4-(furan-2-ylmethyl)-1,2,4-triazole; (tcnsme)- = 1,1,3,3-tetracyano-2- thiométhylpropenide), for which the magnetic study reveals a two-step SCO transition and a LIESST effects with a T(LIESST) of 58 K. Examination of the intermolecular interactions in this complex and other parent trinuclear systems exhibiting complete one-step spin transition, revealed that the presence of the two-step behavior is clearly favored by strong inter-trimer interactions along the trimer axis; (ii) the second system the design and syntheses of to several series of polyfunctional materials exhibiting SCO and luminescent behaviors. In this new way, the most significant result concerns an original discrete Fe(II) complex of formulae [Fe(naphtrz)6](tcnsme)2.4CH3CN (naphtrz = N-(1,2,4-triazol-4-yl)-1,8-naphthalimide), for which the magnetic and photoluminescent studies showed that this material exhibits synergetic SCO and luminescent behaviors. This proves the possibility to control the luminescent properties through simple external perturbations such as temperature, pressure, light irradiation,… In addition, beyond the fundamental aspect, this work open new innovative perspectives for the use of such original materials as sensors or standards of temperature.

This diploma thesis solves the project of polyfunctional apartment building in Habrovany village in the scope of the documentation for the realization of the building. The building is designed in accordance with the custom of building the region with the greatest possible elegance and modern design. The project includes two classic flats 3+kk and 5+1 and is one above-standard attic apartment 5+1 with a large roof terrace. The house belongs to two premises in the 1. floor and two office units in the 2. floor. The solution of parking on the land for residents and shop visitors and a smaller grassy park behind the house.

This diploma thesis deals with the design of the new polyfunctional residency building in Olomouc. Object has square shape and five upper floors and basement. Building is designed as a stand-alone building comprising three operational units. In the first floor is located a café and a bookstore and separate building entry. In the second floor are located offices and the rest of the building is formed with total 12 housing units with different layouts and sizes. In the basement are located cellars for housing units and utility room. The object is designed with separate parking lot. Vertical support system is formed by reinforced concrete skeleton and filling masonry from ceramic fittings Porotherm. Horizontal support system is formed by beams and ceiling slabs from reinforced concrete. Object is based on foundation footings made from reinforced concrete. Roof is designed as a single-shell flat roof. Object is insulated with mineral wool and a ventilated facade made of fiber-cement slabs is designed. The work contains a documentation and design part and is processed as a documentation for the costruction execution.