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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
31

Controllable association of polyelectrolytes in dilute solution. / CUHK electronic theses & dissertations collection

January 2001 (has links)
Peng Shufu. / Thesis (Ph.D.)--Chinese University of Hong Kong, 2001. / Includes bibliographical references. / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Mode of access: World Wide Web. / Abstracts in English and Chinese.
32

Laser light scattering studies of poly(N-isopropylacrylamide).

January 1996 (has links)
by Shui-Qin Zhou. / Publication date from spine. / Thesis (Ph.D.)--Chinese University of Hong Kong, 1995. / Includes bibliographical references (leaves 152-157). / Acknowledgments --- p.i / Abstract --- p.ii / Contents --- p.vi / Abbreviation --- p.viii / List of Figures --- p.xi / List of Tables --- p.xvi / Chapter 1. --- Introduction --- p.1 / Chapter 1.1. --- Project's Significance --- p.1 / Chapter 1.2. --- Research background.....................................: --- p.1 / Chapter 1.2.1. --- Linear PNIPAM chains in aqueous solution --- p.2 / Chapter 1.2.1.1. --- Origins of the LCST --- p.2 / Chapter 1.2.1.2. --- Experimental studies --- p.4 / Chapter 1.2.2. --- PNIPAM gels --- p.9 / Chapter 1.2.2.1. --- Origins of the volume phase transition --- p.10 / Chapter 1.2.2.2. --- Experimental studies --- p.11 / Chapter 1.2.3. --- Surfactant effects --- p.13 / Chapter 1.3. --- The objective of the project --- p.15 / Chapter 1.4. --- Experimental difficulties --- p.17 / Chapter 2. --- Basic Theory --- p.20 / Chapter 2.1. --- Laser light scattering (LLS) --- p.20 / Chapter 2.2. --- Polymer chains in solution --- p.23 / Chapter 2.3. --- Swollen polymer gels --- p.27 / Chapter 3. --- Results and Discussion --- p.32 / Chapter 3.1. --- Linear PNIPAM chains --- p.32 / Chapter 3.1.1. --- D = kDM-αD for PNIPAM in THF and water --- p.32 / Chapter 3.1.2. --- Coil-to-globule transition of single PNIPAM chains in water --- p.46 / Chapter 3.1.3. --- Additional chain-conformation broadening of the line-width distribution in dynamic LLS --- p.64 / Chapter 3.1.4. --- Internal motions of long linear PNIPAM chains --- p.72 / Chapter 3.1.5. --- Structural model of spherical water/AOT/n-hexane microemulsion --- p.80 / Chapter 3.2. --- Spherical PNIPAM microgels --- p.94 / Chapter 3.2.1. --- Volume phase transition of PNIPAM microgels --- p.94 / Chapter 3.2.2. --- Internal motions of short PNIPAM subchains inside the gel networks --- p.107 / Chapter 3.2.3. --- Surfactant effects on the volume phase transition --- p.113 / Chapter 3.2.4. --- Swelling and drying kinetics of a very thin PNIPAM gel film --- p.129 / Chapter 4. --- Conclusions --- p.141 / Chapter 5. --- Experimental --- p.145 / Chapter 5.1 --- Sample preparation --- p.145 / Chapter 5.2 --- Physical measurement --- p.149 / Chapter 6. --- References --- p.152
33

NMR and laser light scattering studies of polymer microgels. / CUHK electronic theses & dissertations collection

January 1998 (has links)
by Gao Yibing. / Thesis (Ph.D.)--Chinese University of Hong Kong, 1998. / Includes bibliographical references. / Electronic reproduction. Hong Kong : Chinese University of Hong Kong, [2012] System requirements: Adobe Acrobat Reader. Available via World Wide Web. / Mode of access: World Wide Web.
34

Polarizability and interaction of polyelectrolyte-colloid complexes. / 高分子電解質-膠體複合體系的相互作用和極化率 / Polarizability and interaction of polyelectrolyte-colloid complexes. / Gao fen zi dian jie zhi- jiao ti fu he ti xi de xiang hu zuo yong he ji hua lu

January 2005 (has links)
Cheng Kwok Kei = 高分子電解質-膠體複合體系的相互作用和極化率 / 鄭國基. / Thesis submitted in: November 2004. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2005. / Includes bibliographical references (leaves 68-73). / Text in English; abstracts in English and Chinese. / Cheng Kwok Kei = Gao fen zi dian jie zhi-jiao ti fu he ti xi de xiang hu zuo yong he ji hua lü / Zheng Guoji. / Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Polyelectrolyte Colloid Complex --- p.1 / Chapter 1.2 --- Image charges --- p.3 / Chapter 1.3 --- Objective of the thesis --- p.3 / Chapter 2 --- Equations for induced image charges (Review) --- p.5 / Chapter 2.1 --- Introduction --- p.5 / Chapter 2.2 --- Image effect --- p.6 / Chapter 2.2.1 --- The potential --- p.6 / Chapter 2.2.2 --- Surface charge density --- p.8 / Chapter 2.2.3 --- Potential energy --- p.9 / Chapter 3 --- Polarizability of a polyelectrolyte colloid complex --- p.11 / Chapter 3.1 --- Introduction --- p.11 / Chapter 3.2 --- The Simulation Model --- p.12 / Chapter 3.2.1 --- Energy of the Complex --- p.13 / Chapter 3.2.2 --- Dipole of the Complex --- p.15 / Chapter 3.2.3 --- Thermal Energy --- p.18 / Chapter 3.3 --- Calculating Method --- p.18 / Chapter 3.3.1 --- Monte Carlo Simulation --- p.19 / Chapter 3.3.2 --- Partition Function Calculation --- p.20 / Chapter 3.4 --- Polarizability --- p.22 / Chapter 3.4.1 --- Compare polarizability of the complex with a permanent dipole --- p.22 / Chapter 3.4.2 --- Results and Discussion --- p.23 / Chapter 3.5 --- Effect of image charges for the complex --- p.33 / Chapter 3.6 --- Conclusion --- p.37 / Chapter 4 --- Correlation and Interaction of complexes - without induced charges --- p.38 / Chapter 4.1 --- Introduction --- p.38 / Chapter 4.2 --- The Simulation Model --- p.39 / Chapter 4.2.1 --- Energy of the system --- p.40 / Chapter 4.2.2 --- Dipole Moment --- p.42 / Chapter 4.3 --- Results and Discussion --- p.43 / Chapter 4.3.1 --- Polarizability of complex --- p.43 / Chapter 4.3.2 --- Correlations between two complexes --- p.46 / Chapter 4.3.3 --- Potential of mean force --- p.50 / Chapter 4.4 --- Conclusion --- p.52 / Chapter 5 --- Correlation between Two Complexes - with induced charges --- p.53 / Chapter 5.1 --- Introduction --- p.53 / Chapter 5.2 --- Induced Surface Charges --- p.54 / Chapter 5.2.1 --- Surface charges --- p.54 / Chapter 5.2.2 --- Energy of system --- p.55 / Chapter 5.2.3 --- Dipole Moment --- p.57 / Chapter 5.3 --- Results and Discussion --- p.58 / Chapter 5.3.1 --- Polarizability of complexes --- p.59 / Chapter 5.3.2 --- Correlation between two complexes --- p.61 / Chapter 5.3.3 --- Potential of mean force --- p.63 / Chapter 5.4 --- Conclusion --- p.64 / Chapter 6 --- Summary --- p.66 / Bibliography --- p.68 / Chapter A --- Mathematical calculation of the dipole moment of a complex --- p.74 / Chapter A.1 --- Equation of mean squared dipole --- p.74 / Chapter A.2 --- z-component of dipole and squared dipole --- p.76
35

Direct measurement of depletion force between two surfaces with total internal reflection microscopy.

January 2009 (has links)
Xing, Xiaochen. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. / Includes bibliographical references. / Abstract also in Chinese. / Abstract (Chinese) --- p.i / Abstract --- p.iii / Contents --- p.v / Acknowledgement --- p.ix / Chapter Chapter1 --- Introduction and background / Chapter 1.1 --- Overview of Studies in Colloid-Polymer mixture --- p.1 / Chapter 1.2 --- Depletion Force in Colloid-Polymer Mixture --- p.1 / Chapter 1.2.1. --- Depletion Interaction in Monodisperse and Neutral Polymer-Colloid Mixtures: Theory --- p.3 / Chapter 1.2.1.1. --- An Exact Result: the Interaction between Parallel Plates due to Ideal Polymer Chains --- p.3 / Chapter 1.2.1.2. --- Penetrable Hard Sphere (PHS) Approach --- p.4 / Chapter 1.2.2. --- Early Experimental Findings of Depletion Interaction --- p.6 / Chapter 1.3 --- References and Notes --- p.8 / Chapter Chapter2 --- Principle of Total Internal Reflection Microscopy (TIRM) and Instrumentation / Chapter 2.1 --- Introduction of Total Internal Reflection Microscopy (TIRM) --- p.10 / Chapter 2.2 --- The Principle of TIRM Technique --- p.11 / Chapter 2.2.1 --- Total Internal Reflection --- p.11 / Chapter 2.2.2 --- Details on Scattering of the Evanescent Wave --- p.13 / Chapter 2.2.3 --- Data Analysis --- p.16 / Chapter 2.3 --- Instrumentation --- p.20 / Chapter 2.3.1 --- Apparatus --- p.20 / Chapter 2.3.2 --- Optical Tweezer --- p.23 / Chapter 2.3.3 --- Cleaning of the Slide Surface --- p.24 / Chapter 2.3.4 --- A Typical Potential Energy Profile --- p.25 / Chapter 2.4 --- Laser Light Scattering (LLS) --- p.26 / Chapter 2.5 --- Zeta-potential Measurements --- p.27 / Chapter 2.6 --- References and Notes --- p.28 / Chapter Chapter3 --- Depletion Attraction between a Polystyrene Sphere and a Hydrophilic Surface in a Pluronic Aqueous Solution / Chapter 3.1 --- Introduction --- p.30 / Chapter 3.2 --- Experimental Section --- p.34 / Chapter 3.2.1 --- Sample Preparation --- p.34 / Chapter 3.2.2 --- Total Internal Reflection Microscopy --- p.35 / Chapter 3.2.3 --- Laser Light Scattering --- p.36 / Chapter 3.3 --- Results and Discussion --- p.37 / Chapter 3.4 --- Conclusion --- p.48 / Chapter 3.5 --- References and Notes --- p.50 / Chapter Chapter4 --- pH-Controllable Depletion Attraction Induced by Microgel Particles / Chapter 4.1 --- Introduction --- p.53 / Chapter 4.2 --- Experimental Section --- p.54 / Chapter 4.2.1 --- Sample Preparation --- p.54 / Chapter 4.2.2 --- Total Internal Reflection Microscopy --- p.56 / Chapter 4.3 --- Results and Discussion --- p.58 / Chapter 4.4 --- Conclusion --- p.63 / Chapter 4.5 --- References and Notes --- p.64 / Publication List --- p.65
36

Emulsion droplets of controlled deformability: electrokinetics, colloid stability and polymer adsorption

Barnes, Timothy January 2003 (has links)
Emulsions are commonly found both in nature and industry. Due to the complex nature of emulsion systems, their interfacial properties and stability are poorly understood, particularly the influence of droplet deformability on the colloid and interfacial behaviour. This study has highlighted the role of emulsion droplet cross-linking (deformability and penetrability) on droplet surface chemistry, droplet colloidal stability and adsorption at the droplet-water interface and provides insight into methods for enhancing the performance of emulsion formulations.
37

Novel pH-responsive microgels and nanogels as intelligent polymer therapeutics

Fisher, Omar Zaire, 1979- 10 September 2012 (has links)
Disease processes that are currently among the leading causes of death now require much more than just a stethoscope for diagnosis and a pill for treatment. The next generation of therapeutics needs to possess a degree of intelligence; the ability to sense and respond to their environment. Biomedical hydrogels have the ability to sense and respond to external stimulus and with the advent of nanotechnology; these polymers can be fabricated on the same size scale as cellular and sub-cellular processes. Throughout the body gradients in pH are used at the cellular level to regulate processes such nutrient transport and to fight infection. Sites of damage or disease within the body are associated with both a change in pH and abnormal nanoporous vasculature. pH-Responsive microgels and nanogels are small enough to access these locations within the body, sense the change in environment, and locally release a therapeutic agent In this work heterogeneous, photoinitiated free radical polymerizations were developed to synthesize novel pH-responsive microgels and nanogels that could be loaded with macromolecular therapeutics and could respond to either a basic or acidic change in pH. A novel photo-dispersion polymerization scheme was developed to synthesize poly(ethylene glycol) grafted poly(methacrylic acid) (P(MAA-g-PEG)) polycomplexation gels for oral protein delivery. These ranged in size from 100- 300 nm in diameter and could swell up to a 17-fold increase in volume, in response to a rise in pH. This property allowed them to protect insulin at low pH and release the protein at neutral pH. In this way the carriers could be used to transport proteins through the stomach to the small intestine for absorption. A novel photo-emulsion polymerization scheme was developed to synthesize poly(ethylene glycol) grafted poly[2-(diethylamino)ethyl methacrylate] nanogels, between 70-150 nm in diameter. These could swell up to a 22-fold increase in volume, in response to a drop in pH. These nanostructures were able to successfully target clathrin-dependent endocytosis and deliver macromolecules to the cytosol. / text
38

Perturbation studies of excitable media

Seagraves, Lisa Elizabeth, January 1900 (has links)
Thesis (M.S.)--West Virginia University, 1998. / Title from document title page. "December 10, 1998." Document formatted into pages; contains viii, 64 p. Vita. Includes abstract. Includes bibliographical references (p. 60-62).
39

Enzymatic formation of supramolecular hydrogels based on self-assembly of DNA derivatives

Chen, Junpeng. January 2009 (has links)
Thesis (M.S.)--Brandeis University, 2009. / Title from PDF title page (viewed on August 9, 2009). Includes bibliographical references.
40

PEG hydrogels as anti-fouling coatings for reverse osmosis membranes

Sagle, Alyson Conner. January 1900 (has links)
Thesis (Ph. D.)--University of Texas at Austin, 2009. / Title from PDF title page (University of Texas Digital Repository, viewed on Sept. 9, 2009). Vita. Includes bibliographical references.

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