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Unreinforced masonry walls subjected to blast loading are vulnerable to collapse and fragmentation. The objective of this thesis is to conduct experimental and analytical research for developing a blast retrofit methodology that utilizes polyurea. A total of four unreinforced masonry walls were constructed and tested under various shock tube induced blast pressures at the University of Ottawa Shock Tube Testing Facility. Two of the retrofitted walls had surface-sprayed polyurea. The results indicate that the use of polyurea effectively controlled fragmentation while significantly increased the load capacity and stiffness of masonry walls. Polyurea proved to be an excellent retrofit material for dissipating blast induced energy by providing ductility to the system and changing the failure mode from brittle to ductile. Single degree of freedom (SDOF) dynamic analyses were conducted as part of the analytical investigation. The results show that the analytical model provides reasonably accurate predictions of the specimen response.

Unreinforced masonry walls subjected to blast loading are vulnerable to collapse and fragmentation. The objective of this thesis is to conduct experimental and analytical research for developing a blast retrofit methodology that utilizes polyurea. A total of four unreinforced masonry walls were constructed and tested under various shock tube induced blast pressures at the University of Ottawa Shock Tube Testing Facility. Two of the retrofitted walls had surface-sprayed polyurea. The results indicate that the use of polyurea effectively controlled fragmentation while significantly increased the load capacity and stiffness of masonry walls. Polyurea proved to be an excellent retrofit material for dissipating blast induced energy by providing ductility to the system and changing the failure mode from brittle to ductile. Single degree of freedom (SDOF) dynamic analyses were conducted as part of the analytical investigation. The results show that the analytical model provides reasonably accurate predictions of the specimen response.

This work presents a fracture mechanics analysis of the cathodic delamination problem for the polyurethane/titanium and polyurea/steel interfaces. The nonlinear behavior of both polymers was investigated. The recent Marlow model was used to define the strain energy function of the polymers. Viscoelastic effects of the polyurea were also studied. The Marlow model was associated with a nine-term Prony series. This model was seen to represent experimental data relatively well for a wide range of strain rates both in tension and compression. The driving force for delamination, the strain energy release rate G, is presented for both interfaces. Cathodic delamination data for several temperatures are presented as crack growth rate as a function of crack driving force. The approach recognizes that both temperature and stress can be used as accelerated life testing parameters. / text

Terrorism has become a serious threat in the world, with bomb attacks carried out both inside and outside buildings. There are already many unreinforced masonry buildings in existence, and some of them are historical buildings. However, they do not perform well under blast loading. Aiming on protecting masonry buildings, retrofitting techniques were developed. Some experimental work on studying the effect of retrofitted URM walls has been done in recent years; however, these tests usually cost a significant amount of time and funds. Because of this, numerical simulation has become a good alternative, and can be used to study the behaviour of masonry structures, and predict the outcomes of experimental tests. This project was carried out to find efficient retrofitting technique under blast loading by developing numerical material models. It was based on experimental research of strengthening URM walls by using retrofitting technologies under out-of-plane loading at the University of Adelaide. The numerical models can be applied to study large-scaled structures under static loading, and the research work is then extended to the field of blast loading. Aiming on deriving efficient material models, homogenization technology was introduced to this research. Fifty cases of numerical analysis on masonry basic cell were conducted to derive equivalent orthotropic material properties. To study the increasing capability in strength and ductility of retrofitted URM walls, pull-tests were simulated using interface element model to investigate the bond-slip relationship of FRP plates bonded to masonry blocks. The interface element model was then used to simulate performance of retrofitted URM walls under static loads. The accuracy of the numerical results was verified by comparing with the experimental results from previous tests at the University of Adelaide by Griffith et al. (2007) on unreinforced masonry walls and by Yang (2007) on FRP retrofitted masonry walls. To study the de-bonding behaviours of retrofits bonded to masonry, and find appropriate solution to protect certain masonry walls against blast loading, various retrofitting technologies were examined. The simulation covers explosive impacts of a wide range of impulses. Based on this work, pressure-impulse diagrams for different types of retrofitted URM walls were developed as a design guideline for estimating the blast effect on retrofitted masonry walls. The outcomes of this research will contribute to the development of numerical simulation on modelling retrofitted URM walls, improving the technique for explosion-resistant of masonry buildings, and providing a type of guideline for blast-resistant design. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1349719 / Thesis (M.Eng.Sc.) - University of Adelaide, School of Civil, Environmental and Mining Engineering, 2009

Terrorism has become a serious threat in the world, with bomb attacks carried out both inside and outside buildings. There are already many unreinforced masonry buildings in existence, and some of them are historical buildings. However, they do not perform well under blast loading. Aiming on protecting masonry buildings, retrofitting techniques were developed. Some experimental work on studying the effect of retrofitted URM walls has been done in recent years; however, these tests usually cost a significant amount of time and funds. Because of this, numerical simulation has become a good alternative, and can be used to study the behaviour of masonry structures, and predict the outcomes of experimental tests. This project was carried out to find efficient retrofitting technique under blast loading by developing numerical material models. It was based on experimental research of strengthening URM walls by using retrofitting technologies under out-of-plane loading at the University of Adelaide. The numerical models can be applied to study large-scaled structures under static loading, and the research work is then extended to the field of blast loading. Aiming on deriving efficient material models, homogenization technology was introduced to this research. Fifty cases of numerical analysis on masonry basic cell were conducted to derive equivalent orthotropic material properties. To study the increasing capability in strength and ductility of retrofitted URM walls, pull-tests were simulated using interface element model to investigate the bond-slip relationship of FRP plates bonded to masonry blocks. The interface element model was then used to simulate performance of retrofitted URM walls under static loads. The accuracy of the numerical results was verified by comparing with the experimental results from previous tests at the University of Adelaide by Griffith et al. (2007) on unreinforced masonry walls and by Yang (2007) on FRP retrofitted masonry walls. To study the de-bonding behaviours of retrofits bonded to masonry, and find appropriate solution to protect certain masonry walls against blast loading, various retrofitting technologies were examined. The simulation covers explosive impacts of a wide range of impulses. Based on this work, pressure-impulse diagrams for different types of retrofitted URM walls were developed as a design guideline for estimating the blast effect on retrofitted masonry walls. The outcomes of this research will contribute to the development of numerical simulation on modelling retrofitted URM walls, improving the technique for explosion-resistant of masonry buildings, and providing a type of guideline for blast-resistant design. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1349719 / Thesis (M.Eng.Sc.) - University of Adelaide, School of Civil, Environmental and Mining Engineering, 2009

Terrorism has become a serious threat in the world, with bomb attacks carried out both inside and outside buildings. There are already many unreinforced masonry buildings in existence, and some of them are historical buildings. However, they do not perform well under blast loading. Aiming on protecting masonry buildings, retrofitting techniques were developed. Some experimental work on studying the effect of retrofitted URM walls has been done in recent years; however, these tests usually cost a significant amount of time and funds. Because of this, numerical simulation has become a good alternative, and can be used to study the behaviour of masonry structures, and predict the outcomes of experimental tests. This project was carried out to find efficient retrofitting technique under blast loading by developing numerical material models. It was based on experimental research of strengthening URM walls by using retrofitting technologies under out-of-plane loading at the University of Adelaide. The numerical models can be applied to study large-scaled structures under static loading, and the research work is then extended to the field of blast loading. Aiming on deriving efficient material models, homogenization technology was introduced to this research. Fifty cases of numerical analysis on masonry basic cell were conducted to derive equivalent orthotropic material properties. To study the increasing capability in strength and ductility of retrofitted URM walls, pull-tests were simulated using interface element model to investigate the bond-slip relationship of FRP plates bonded to masonry blocks. The interface element model was then used to simulate performance of retrofitted URM walls under static loads. The accuracy of the numerical results was verified by comparing with the experimental results from previous tests at the University of Adelaide by Griffith et al. (2007) on unreinforced masonry walls and by Yang (2007) on FRP retrofitted masonry walls. To study the de-bonding behaviours of retrofits bonded to masonry, and find appropriate solution to protect certain masonry walls against blast loading, various retrofitting technologies were examined. The simulation covers explosive impacts of a wide range of impulses. Based on this work, pressure-impulse diagrams for different types of retrofitted URM walls were developed as a design guideline for estimating the blast effect on retrofitted masonry walls. The outcomes of this research will contribute to the development of numerical simulation on modelling retrofitted URM walls, improving the technique for explosion-resistant of masonry buildings, and providing a type of guideline for blast-resistant design. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1349719 / Thesis (M.Eng.Sc.) - University of Adelaide, School of Civil, Environmental and Mining Engineering, 2009

Unreinforced masonry walls subjected to blast loading are vulnerable to collapse and fragmentation. The objective of this thesis is to conduct experimental and analytical research for developing a blast retrofit methodology that utilizes polyurea. A total of four unreinforced masonry walls were constructed and tested under various shock tube induced blast pressures at the University of Ottawa Shock Tube Testing Facility. Two of the retrofitted walls had surface-sprayed polyurea. The results indicate that the use of polyurea effectively controlled fragmentation while significantly increased the load capacity and stiffness of masonry walls. Polyurea proved to be an excellent retrofit material for dissipating blast induced energy by providing ductility to the system and changing the failure mode from brittle to ductile. Single degree of freedom (SDOF) dynamic analyses were conducted as part of the analytical investigation. The results show that the analytical model provides reasonably accurate predictions of the specimen response.

The temperature profile needed to complete the reaction between the sodium-diamine complex and the isocyanate terminated prepolymer has been established. The sodium diamine complex has the advantage of blocking the nearly instantaneous reaction between the diamine and isocyanate from taking place until it is released at elevated temperatures. Because of its low melting temperature (~40 °C) and its low molecular weight (low viscosity), this chain extension reaction is not dependent on the participation of the prepolymer. Instead, the rate of reaction is dependent on the dissolution of the 4,4’-methylenedianiline (MDA) complex into the system. The dissolution of the MDA complex has been demonstrated to be strongly dependent on particle size. Both the plasticizer Bis(2-ethylhexyl) adipate and the quaternary ammonium compound found in soy lecithin play crucial roles for this reaction. The quaternary ammonium compound is crucial in the dissolution of the complexes. Although the plasticizer has been shown to dissolve the complex to a small extent, the principal role of the plasticizer is to disperse the complexes and to prevent their agglomeration. Other additives such as Dimethyl Sulfoxide (DMSO) have demonstrated to be highly efficient in dissolving the complex. However its effectiveness limits the mixing window needed before reaction take place, resulting in a disadvantage.

The research described in this thesis originated from an idea to develop new body protection for the sport of fencing. The ultimate goal is to develop body armour which would be flexible, wearable, washable, light and breathable, offer protection from injuries and cover the entire body of a sportsman. A new material which exhibits shear thickening behaviour has been specially developed for this purpose in the process of this investigation. The material was designed and synthesised as a soft polymeric system which is flexible, chemically stable and able to increase the value of its modulus of elasticity upon impact at a high strain rate, while remaining in its soft gel-like elastomeric state when low strain rate deformation is applied. The polymeric system that has been developed is based on interpenetrating polymeric networks (IPN) of immiscible polyurethane/urea-ester/ether and poly(boron)n(dimethylsiloxane)m (where on average m ≈ 16 n). In addition, as the polydimethylsilane (PDMS) based polymeric system strongly tends to phase separation, the siloxane polymeric network was chemically cross-linked to the polyurethane polymeric network through polyurethane chemical cross-link-bridges. In order to introduce polyurethane cross-links to a siloxane-based polymeric network, some of the attached methyl groups in the PDMS polymeric backbone were substituted by ε-pentanol groups. The resulting polymeric system combines properties of an alternating copolymer with IPN. The actual substitution of the methyl groups of PDMS into alternating ε-pentanol groups was performed by Grignard reaction of trifunctional chlorosilane monomers, magnesium and 1,5-dibromopentane. Chemical analytical techniques like FT-IR, 13C NMR and 1H NMR spectroscopy were used to reveal the chemical structure of the synthesised polymeric network. The mechanical and dynamical properties of the obtained polymeric system were analysed by dynamic mechanical analysis (DMA). This part of the investigation indicated that the novel polymeric system exhibited shear thickening behaviour, but only at a narrow diapason of deformations (i.e., deformations between 2 to 3 % of the length of the sample). At this limited diapason of deformation an effective increase of the modulus of elasticity from 6 MPa (at lower frequencies, i.e., up to ≤6 Hz of the applied oscillating stress) to 65 MPa (at frequencies between 12.5 to 25 Hz) was obtained. However, no increase in the modulus of elasticity was recorded at deformations below 1.5 % or above 3.5 % of length of the sample at the same frequencies (0 to 25Hz) of the applied oscillating stress.