An adsorbent suitable for adsorption desalination cycles is essentially characterized by a hydrophilic and porous structure with high surface area where water molecules are adsorbed via hydrogen bonding mechanism. Silica gel type A++ possesses the highest surface area and exhibits the highest equilibrium uptake from all the silica gels available in the market, therefore being suitable for water desalination cycles; where adsorbent’s adsorption characteristics and water vapor uptake capacity are key parameters in the compactness of the system; translated as feasibility of water desalination through adsorption technologies. The adsorption characteristics of water vapor onto silica gel type A++ over a temperature range of 30 oC to 60 oC are investigated in this research. This is done using water vapor adsorption analyzer utilizing a constant volume and variable pressure method, namely the Hydrosorb-1000 instrument by Quantachrome. The experimental uptake data is studied using numerous isotherm models, i. e. the Langmuir, Tóth, generalized Dubinin-Astakhov (D-A), Dubinin-Astakhov based on pore size distribution (PSD) and Dubinin-Serpinski (D-Se) isotherm for the whole pressure range, and for a pressure range below 10 kPa, proper for desalination cycles; isotherms type V of the International Union of Pure and Applied Chemistry (IUPAC) classification were exhibited. It is observed that the D-A based on PSD and the D-Se isotherm models describe the best fitting of the experimental uptake data for desalination cycles within a regression error of 2% and 6% respectively. All isotherm models, except the D-A based on PSD, have failed to describe the obtained experimental uptake data; an empirical isotherm model is proposed by observing the behavior of Tóth and D-A isotherm models. The new empirical model describes the water adsorption onto silica gel type A++ within a regression error of 3%. This will aid to describe the advantages of silica gel type A++ for the design of adsorption desalination processes where reducing capital cost and footprint area are highly important parameters to take into account.

A systematic NMR cryo-porometry and -diffusometry study using nitrobenzene as a probe liquid is carried out in order to characterise pore structures of hierarchically-organised porous silica monolith possessing mesopores along with a 3D bicontinuous macropore network. The result obtained from NMR cryoporometry shows the presence of a relatively wide mesopore size distribution of 10-35 nm. Furthermore, NMR cryodiffusometry indicates that whilst the mesopores are highly tortuous (Tmeso ≈6), they have little influence on the overall tortuosity of the material (Tmacro ≈1.5), which is largely dominated by the macropores (Toverall ≈1.7).

No description available.

No description available.

Lime has been used in construction for millennia, and its value, especially in the field of conservation architecture, has only recently been rediscovered. Lime mortars harden through carbonation, and this thesis is a study of that process. The research conducted has resulted in the development of two novel techniques for the measurement and detection of carbonation. The first technique is a method of thermogravimetric analysis which allows the carbonation profile to be measured within an acceptable time-frame. The second technique is the use of drilling resistance measurement to visualise the carbonation profile. The potential of elemental analysis to measure the carbonation profile has also been identified. It has been demonstrated that the lime/water ratio has less impact on the compressive strength of air lime mortars than had previously been supposed. The change in the pore size distribution of air lime mortars caused by carbonation has been studied, and a theory has been proposed to explain this phenomenon. Five different forms of air lime binder were studied. The impact of these on the structural performance of the resultant mortars has been assessed. It was concluded that mortars made with lime putties perform better than mortars made with dry lime hydrate. Mortars made with dispersed hydrated lime appear to perform as well as mortars made with lime putties, but at a slower rate of strength growth. The use of extra mature lime putty does not appear to confer structural performance benefits when compared with ordinary lime putty. It has been shown that the use of calcitic aggregates can produce air lime mortars which perform as well as moderately hydraulic lime mortars. It is theorised that this phenomenon is not directly related to carbonation, but rather to a complex interaction of the granulometry, mineralogy, chemistry and porosity of the aggregate with the binder.

Για τον προσδιορισμό της πορομετρικής καμπύλης των γεωυφασμάτων διατίθενται σήμερα τρία πρότυπα (ASTM D6767, EN ISO 12956 και ASTM D4751) που θεωρούνται “διεθνούς” αποδοχής. Το πιο πρόσφατο από αυτά (ASTM D6767) εγκρίθηκε το 2002, ορίζει μέθοδο με βάση τη ροή σε τριχοειδή και αποτελεί το κύριο αντικείμενο της παρούσας διατριβής. Ελέγχθηκαν 52 μη υφασμένα γεωυφάσματα κατασκευασμένα από ίνες πολυπροπυλενίου τόσο κατά ASTM D6767 όσο και κατά EN ISO 12956 (υγρό κοσκίνισμα) και ASTM D4751 (ξηρό κοσκίνισμα). Τα αποτελέσματα που προέκυψαν συγκρίθηκαν τόσο μεταξύ τους όσο και με φυσικές ιδιότητες των γεωυφασμάτων, με τιμές μεγεθών που παρέχουν οι κατασκευαστές αυτών των προϊόντων και με τιμές μεγεθών που υπολογίζονται θεωρητικά. Τα μεγέθη πόρων και οι πορομετρικές καμπύλες που προκύπτουν εργαστηριακά με εφαρμογή κάθε μίας από τις τρεις μεθόδους είναι διαφορετικά. Αυτό οφείλεται στις διαφορετικές παραδοχές ή υποθέσεις κάθε μεθόδου αλλά και στις διαδικασίες που προβλέπει η κάθε μέθοδος. Ειδικότερα, οι δύο βασικές υποθέσεις του προτύπου ASTM D6767 αφορούν τη γωνία επαφής, θ, μεταξύ ρευστού και στερεού (τίθεται ίση με μηδέν) και τη μορφή της διατομής των πόρων των γεωυφασμάτων (κυλινδρική). Λόγω της δομής των μη υφασμένων γεωυφασμάτων οι δύο παραπάνω υποθέσεις δεν είναι δυνατόν να επαληθευθούν. Για τον λόγο αυτό στην εξίσωση προσδιορισμού των μεγεθών πόρων του προτύπου ASTM D6767 εισάγεται διορθωτικός συντελεστής. Από την επεξεργασία των αποτελεσμάτων της παρούσας διατριβής προέκυψε ότι ο συντελεστής αυτός πρέπει να έχει τιμή ίση με 1/3 (για τη συγκεκριμένη συσκευή που χρησιμοποιήθηκε και τις διαδικασίες που εφαρμόστηκαν για την εκτέλεση των δοκιμών) ώστε τα αποτελέσματα να προσεγγίζουν ικανοποιητικά αυτά της δοκιμής κατά EN ISO 12956. / Three internationally accepted standards (ASTM D6767, EN ISO 12956 and ASTM D4751) are available today for determing the pore size distribution of geotextiles. The most recently approved standard (2002) is ASTM D6767 which defines a method based on capillary flow. Laboratory testing according to this standard is the main subject of this thesis. Fifty two nonwoven geotextiles, made of polypropylene fibers, were tested according to the three standardized methods (ASTM D6767, EN ISO 12956 – wet sieving and ASTM D4751 – dry sieving). Comparisons were made between the results obtained from each standardized method as well as between measured pore sizes and geotextile physical properties, manufacturer provided pore sizes and values obtained theoretically. Different pore sizes and pore size distribution curves are obtained when different laboratory standard methods are applied. This is due to the different assumptions on which each method is based and also due to the procedures that each method specifies. The two main assumptions of the Standard ASTM D6767 concern the contact angle, θ, between liquid and solid (equal to zero) and the pore shapes of the geotextiles (cylindrical). Due to the structure of the nonwoven geotextiles the effect of these assumptions is different to quantify. Accordingly, the computation of pore sizes according standard ASTM D6767 is based on the introduction of a correction coefficient in the pertinent equation. The results obtained during this correction coefficient should have a value equal to 1/3 for the particular device used and the procedures applied. Use of this correction coefficient fields results that approximate very well the results obtained from wet sieving tests according to Standard EN ISO 12956.

Made available in DSpace on 2014-06-11T19:33:39Z (GMT). No. of bitstreams: 0 Previous issue date: 2011-01-20Bitstream added on 2014-06-13T21:06:47Z : No. of bitstreams: 1 beraldo_jmg_dr_jabo.pdf: 1719744 bytes, checksum: a27050b0770082469a896d7df06651eb (MD5) / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) / O sistema de semeadura direta (SSD) proporciona melhores condições físicas do solo favorecendo o armazenamento de água no solo (ARM). A hipótese do trabalho foi que o Latossolo Vermelho argiloso, em sequências de culturas de verão e inverno sob SSD afeta o ARM em decorrência da modificação nos atributos físicos do solo e que o tensiômetro de punção digital (TDig) pode ser usado para medir o potencial mátrico da água no solo. Os objetivos foram avaliar o ARM e os atributos físicos do solo em sequências de culturas de verão e de inverno sob SSD e medir o potencial mátrico da água no solo por meio do tensiômetro de mercúrio e do TDig. O delineamento foi em blocos, com três repetições, no esquema em faixas. Os tratamentos foram constituídos por três sequências de culturas de verão (rotação soja/milho e monocultura de milho e soja) e sete culturas de inverno (milho, girassol, nabo forrageiro, milheto, guandu, sorgo e crotalária). Foram instalados tensiômetros nas camadas de 0,2; 0,4 e 0,6 m. Foi determinada a densidade do solo, a distribuição de poros por tamanho nas camadas de 0-0,1 e 0,1-0,2 m e a infiltração de água na superfície do solo. Os dados foram submetidos à análise de variância e as médias comparadas pelo teste de Tukey. O TDig pode ser usado para avaliar o potencial mátrico da água no solo. O ARM não diferiu entre as sequências de culturas de verão e nas culturas de inverno houve diferença, principalmente após período de menor disponibilidade hídrica. A densidade e a porosidade do solo não foram influenciadas pelas culturas de verão e inverno. O diâmetro de poros entre 0,075 - 0,05 e 0,03 - 0,0375 mm na camada de 0,0-0,1 m diferiu entre as sequências de verão. A distribuição de poros por tamanho não foi influenciada pelas sequências de culturas de inverno. A maior infiltração de água no solo ocorreu na parcela sob monocultura de soja / No tillage system provides soil physical properties improvements, and soil water storage. The hypothesis of this study was that a Red Latosol (Oxisol), in summer and winter crops sequences under no-tillage system, can have its soil water storage influenced by changes in soil physical properties and digital tensiometer can be used to measure soil water matric potential. This study aimed to measure the soil matric potential using both mercury and digital tensiometers and to evaluate the soil water storage and physical properties on summer and winter crops sequences under no-tillage system. A completely randomized block was designed with three replications on a strips plan. The treatments were the combination of three summer crops sequences (soybean/maize rotation, corn and soybean monocultures) and seven winter crops (maize, sunflower, oilseed radish, millet, pigeon pea, sorghum and sunn hemp). Tensiometers were installed at a depth of 0.20; 0.40; 0.60 meters. Bulk density and pores distribution curves were determined from layers 0-0.1 and 0.1-0.2 depth and water infiltration at the soil surface. The data were submitted to variance analysis and means were compared by the Tukey test. The hypothesis was confirmed, therefore digital tensiometer can be used to measure soil water matric potential. The results showed no difference regarding soil water storage in summer crops sequences, especially after a period associated with lower water availability. Soil porosity and bulk density were not influenced by summer and winter crops sequences. The results indicated that the pores with diameter between 0,075 - 0,05 e 0,03 - 0,0375 mm from layer 0-0.1 m differed on summer crops sequences. No difference was observed by pores distribution curves between summer and winter crops sequences. The largest water infiltration occurred under the soybean monocultures plot

Thermoporosimetry is a technique to determine small pore sizes based on melting and crystallization point depression. The temperature shift was measured by Differential Scanning Calorimetry (DSC). Development of thermoporosimetry was carried out on silica with a well-characterized narrow pore size distribution. Several parameters were studied, which a have a direct influence on melting and crystallization point depression (for example: a quality of the solvent, filling the pores with the solvent, time and frequency of centrifuging, superfluous solvent removal conditions, etc.). The optimum conditions for the thermoporosimetry method were developed using high porosity silica. The optimized experimental conditions found for silica were applied to polypropylene powder with much lower porosity. Several polypropylene powders were synthesized using different polymerization catalysts and their porosity determined. Polymer powder morphology and structure was characterized by standard methods. Powder porosity obtained by thermoporometry, gas sorption, and BET methods was compared.

NMR is gaining increasing interest in civil engineering for applications regarding microstructure characterization as e.g., to determine pore sizes or to monitor moisture transport in porous materials. This study reveals the capability of NMR as a tool for pore size characterization. Therefore, we measured floor screed and synthetic materials at partial and full saturation. For most examined materials, the pore size distribution was successfully determined using either a reference or a calibration method. Since diffusion effects were observed for some samples in single-sided NMR measurements, further tests employing an NMR core analyzer were carried out in a homogeneous magnetic field. The finally obtained surface relaxivity of floor screed (50 μm/s) resulted to be much higher than suggested by literature.

The topic of the Ph.D. thesis was focused on the process of sintering alumina and zirconia ceramic materials with the aim to compare kinetics of sintering sub-micro and nanoparticle systems. Zirconia ceramic powders stabilized by different amount of yttria addition in the concentration range of 0 – 8 mol% were used. The different crystal structure (secured by yttria stabilization) of zirconia, as found, did not play statistically proven role in the process of zirconia sintering. The possible influence was covered by other major factors as particle size and green body structure, which does affect sintering in general. According to the Herrings law, the formula predicting sintering temperature of materials with different particle size was defined. The predicted sintering temperatures were in good correlation with the experimental data for zirconia ceramic materials prepared from both, coarser submicrometer, and also nanometer powders. In case of alumina ceramics the predicted and experimentally observed sintering temperature values did not match very well. Mainly the nanoparticle alumina materials real sintering temperature values were markedly higher than predicted. The reason was, as shown in the work, strong agglomeration of the powders and strong irregularities of particle shape. The major role of green body microstructure in the sintering process was confirmed. The final density of ceramic materials was growing in spite of sintering temperature, which was decreasing together with pore - particle size ratio (materials with similar particle size were compared). Sintering temperature was increasing together with growing size of pores trapped in the green body structure. Clear message received from the above mentioned results was the importance of elimination of stable pores with high coordination number out off the green body microstructure during shaping ceramic green parts. Same sintering kinetics model was successfully applied on the sintering process of submicro- and also nanometer zirconia ceramics. Activation energy of nanometer zirconia was notably lower in comparison to submicrometer material. For the sintering of nanoparticle zirconia was typical so called “zero stage” of sintering, clearly visible on kinetic curves. It was found out, that processes running in zirconia “green” material during zero stage of sintering are heat activated and their activation energy was determined. Pores of submicrometer zirconia were growing in an open porosity stage of sintering just a slightly (1.3 times) compared to the nanoparticle zirconia, where the growth was much higher (5.5 times of the initial pore diameter). This difference was most probably caused by preferential sintering of agglomerates within the green bodies and by particle rearrangement processes which appears in the zero stage of sintering of nanoparticular ceramics. The technology of preparation of bulk dense ytria stabilized zirconia nanomaterial with high relative density of 99.6 % t.d. and average grain size 65nm was developed within the thesis research.