abstract: Potential induced degradation (PID) due to high system voltages is one of the major degradation mechanisms in photovoltaic (PV) modules, adversely affecting their performance due to the combined effects of the following factors: system voltage, superstrate/glass surface conductivity, encapsulant conductivity, silicon nitride anti-reflection coating property and interface property (glass/encapsulant; encapsulant/cell; encapsulant/backsheet). Previous studies carried out at ASU's Photovoltaic Reliability Laboratory (ASU-PRL) showed that only negative voltage bias (positive grounded systems) adversely affects the performance of commonly available crystalline silicon modules. In previous studies, the surface conductivity of the glass surface was obtained using either conductive carbon layer extending from the glass surface to the frame or humidity inside an environmental chamber. This thesis investigates the influence of glass surface conductivity disruption on PV modules. In this study, conductive carbon was applied only on the module's glass surface without extending to the frame and the surface conductivity was disrupted (no carbon layer) at 2cm distance from the periphery of frame inner edges. This study was carried out under dry heat at two different temperatures (60 °C and 85 °C) and three different negative bias voltages (-300V, -400V, and -600V). To replicate closeness to the field conditions, half of the selected modules were pre-stressed under damp heat for 1000 hours (DH 1000) and the remaining half under 200 hours of thermal cycling (TC 200). When the surface continuity was disrupted by maintaining a 2 cm gap from the frame to the edge of the conductive layer, as demonstrated in this study, the degradation was found to be absent or negligibly small even after 35 hours of negative bias at elevated temperatures. This preliminary study appears to indicate that the modules could become immune to PID losses if the continuity of the glass surface conductivity is disrupted at the inside boundary of the frame. The surface conductivity of the glass, due to water layer formation in a humid condition, close to the frame could be disrupted just by applying a water repelling (hydrophobic) but high transmittance surface coating (such as Teflon) or modifying the frame/glass edges with water repellent properties. / Dissertation/Thesis / M.S.Tech Engineering 2012

One of the most pressing problems nowadays is climate change and global warming. As it name indicates, it is a problem that concerns the whole earth. There is no doubt that the main cause for this to happen is human, and very related to non-renewable carbon-based energy resources. However, technology has evolved, and some alternatives have appeared in the energy conversion sector. Nevertheless, they are relatively young yet. Since the growth in renewable energies technologies wind power and PV are the ones that have taken the lead. Wind power is a relatively mature technology and even if it still has challenges to overcome the horizon is clear. However, in the PV case the technology is more recent. Even if it is true that PV modules have been used in space applications for more than 60 years, large scale production has not begun until last 10 years. This leaves the uncertainty of how will PV plants and modules age. The author will try to analyse the aging of a specific 63 kWp PV plant located in the roof of a building in Gävle, monitoring production and ambient condition data, to estimate the degradation and the new nominal power of the plant. It has been found out that the degradation of the system is not considerable. PV modules and solar inverters were studied, and even if there are more elements in the system, those are the principal ones. PV modules suffered a degradation of less than 5%, while solar inverters’ efficiency dropped from 95,4% to around 93%.