Thesis (Ph. D.)--University of Texas at Austin, 2000. / Vita. Includes bibliographical references (leaves 145-154). Available also in a digital version from Dissertation Abstracts.

Thesis (Ph. D.)--Florida State University, 2004. / Advisor: Dr. Jim Zheng, Florida State University, College of Engineering, Dept. of Mechanical Engineering. Title and description from dissertation home page (viewed June 15, 2004). Includes bibliographical references.

No description available.

archives@tulane.edu / Metal whisker formation has been an unwanted byproduct in electronics for the past 70 years. However, in that period, no one has come up with one mechanism that can explain all the collected data. This dissertation focuses on copper whisker formation in the presence of a sulfur-containing compound. Pulsed laser deposition is used to create a molybdenum disulfide thin film, and the resulting whiskers are analyzed with scanning electron microscopy and x-ray photoelectron spectroscopy. The copper whiskers are proven to be pure copper and can be several millimeters in length. The collected data supports a recrystallization-based mechanism, where the copper vapor on the surface recrystallizes at the base of the copper whisker, therefore, adding to the length of the whisker. / 1 / Megan Elizabeth Woods

Ti6Al4V is the most commonly used of the titanium alloys and is known for its high strength to weight ratio and superb corrosion resistance compared to conventional steels. Ti6Al4V is used in applications in the aerospace, biomedical, automotive, power generation and oil and gas fields. Laser metal deposition (LMD) is an additive manufacturing (AM) platform used to build 3-D metal shapes. LMD is one of the most researched topics within the laser processing field currently and is advancing continuously. The rapid growth in the AM field is driven by market demands to reduce manufacturing costs, shorter lead times and an increasing demand for customized products. One of the major challenges facing the production of Ti6Al4V components using LMD is the high resultant residual stresses, limiting build size due to delamination or distortion. At the commencement of this study, little data pertaining to the residual stress build up in larger LMD components was available. This research was conducted to create an understanding of the relationship between build height and surface residual stresses and how they influence the dimensional stability of a part. Additionally, the relationship between build height and static mechanical properties was analysed. The effects of laser power, scanning speed and powder mass flow rate on the deposition layer were evaluated. The number of defects and the deposition build height were evaluated to determine the optimum process parameters for multi-layer components. An increase in laser power resulted in an increase in build height for the parameter window selected for the study. Similarly, an increase in build height was observed with an increase in powder mass flow rate, while an increase in scanning speed resulted in a decrease in build height. As laser power and scanning speed had inverse effects on the build height, heat input was evaluated to determine the optimum combination of the 2 parameters. Multilayer samples were produced with a laser power setting of 1900 W, a scanning speed of 0.01 m/s and a powder mass flow rate of 8 g/min. Fully dense components were produced with no notable defects. These components were analysed to reveal the relationship between build height and surface residual stresses and showed that the minimum residual stress observed in a component was related to an actual height from the base and was not affected by the build height of the sample. Maximum residual stresses were observed closest to the base of the cylinder and the stresses were larger in larger samples for both hoop and longitudinal surface residual stress. The micro-hardness of the samples increased as build height increased. The tensile strength remained within constant range between 1080 MPa and 1050 MPa for all samples successfully tested. Brittle failures were observed on the upper sections of the larger samples, attributed to the high micro-hardness observed in these areas. The study successfully evaluated the relationship between build height and surface residual stresses as well as build height and static mechanical properties thereby increasing the knowledge within this field.

No description available.

Two synthesis pathways were employed throughout this work to create a variety of unique carbon materials. The first of these routes involves the photo-dissociation of liquids by direct irradiation with ultrashort laser pulses; while the second entails the bombardment of polycrystalline chemical layers by a pulsed laser induced carbon plasma. The pulsed laser irradiation (PLI) of liquid benzene (C6H6) was found to result in the formation of amorphous carbon nanoparticles consisting of clusters of sp2-bonded aromatic rings bridged by sp hybridized polyyne functionalities. In a complimentary experiment, liquid toluene (C6H5CH3) was irradiated under similar conditions leading to the synthesis of a series of free floating methyl capped polyynes, with chain lengths ranging from C10 – C20. The synthesis of polyynes is an active and cutting edge topic in material science and chemistry. In a more complex experiment, solutions of ferrocene and benzene were irradiated by fs-laser pulses resulting in highly ordered mesoscale structures exhibiting four unique geometries; ribbons, loops, tubes, and hollow spherical shells. After a purification process, the higher order structures were destroyed and replaced with nanoparticles consisting of three distinct species including; pure iron, and two phases in which part of the ferrocene molecule was bound to either carbon or iron/carbon complexes. This material is extremely interesting because it exhibits properties similar to that of an electret and is also ferromagnetic over a large temperature range. In the final liquid phase laser irradiation experiment, a new hybrid deposition technique was originated and used to coat stainless steel electrodes with disordered mesoporous nanocrystalline graphite. This method involves the laser induced breakdown of benzene and the subsequent electrodeposition of the resulting carbon ions. Another focus in this work involved the synthesis of a special class of polymer-like carbon nanomaterials using a new method that augments traditional pulsed laser deposition. This technique involves the plasma processing of frozen materials with a pulsed laser initiated graphitic plasma. We call this technique "pulsed laser induced plasma processing" or "PLIPP". Various thin film compositions were created by processing alkane and alkene ices. Finally, in a slight departure from the previous experiments, the effects of carbon ion bombardment on water ice were examined in an effort to understand certain astrophysical processes.

Two synthesis pathways were employed throughout this work to create a variety of unique carbon materials. The first of these routes involves the photo-dissociation of liquids by direct irradiation with ultrashort laser pulses; while the second entails the bombardment of polycrystalline chemical layers by a pulsed laser induced carbon plasma. The pulsed laser irradiation (PLI) of liquid benzene (C6H6) was found to result in the formation of amorphous carbon nanoparticles consisting of clusters of sp2-bonded aromatic rings bridged by sp hybridized polyyne functionalities. In a complimentary experiment, liquid toluene (C6H5CH3) was irradiated under similar conditions leading to the synthesis of a series of free floating methyl capped polyynes, with chain lengths ranging from C10 – C20. The synthesis of polyynes is an active and cutting edge topic in material science and chemistry. In a more complex experiment, solutions of ferrocene and benzene were irradiated by fs-laser pulses resulting in highly ordered mesoscale structures exhibiting four unique geometries; ribbons, loops, tubes, and hollow spherical shells. After a purification process, the higher order structures were destroyed and replaced with nanoparticles consisting of three distinct species including; pure iron, and two phases in which part of the ferrocene molecule was bound to either carbon or iron/carbon complexes. This material is extremely interesting because it exhibits properties similar to that of an electret and is also ferromagnetic over a large temperature range. In the final liquid phase laser irradiation experiment, a new hybrid deposition technique was originated and used to coat stainless steel electrodes with disordered mesoporous nanocrystalline graphite. This method involves the laser induced breakdown of benzene and the subsequent electrodeposition of the resulting carbon ions. Another focus in this work involved the synthesis of a special class of polymer-like carbon nanomaterials using a new method that augments traditional pulsed laser deposition. This technique involves the plasma processing of frozen materials with a pulsed laser initiated graphitic plasma. We call this technique "pulsed laser induced plasma processing" or "PLIPP". Various thin film compositions were created by processing alkane and alkene ices. Finally, in a slight departure from the previous experiments, the effects of carbon ion bombardment on water ice were examined in an effort to understand certain astrophysical processes.

No description available.

The deposition of WOx and FeOx thin films by reactive PLD and post-deposition annealing in an oxygen environment have been investigated. The influence of the deposition parameters on the growth and structure of WOx as well as the electronic and structural properties of FeOx thin films are presented. WOx thin films have been deposited onto native oxide Si (100) and SrTiO3 (100) substrates, whilst FeOx films were deposited onto glass and MgO (100). The films have been analysed using X-ray diffraction (XRD), texture pole figure analysis, X-ray reflectivity (XRR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), atomic force microscopy (AFM) and resistance vs temperature measurements. The WOx films deposited on both Si and SrTiO3 substrates were found to exhibit a dependence on the primary texture with fluence in the range of 5.3 J cm-2 to 14.7 J cm-2. The WOx films deposited on SrTiO3 were observed to exhibit a biaxial texture whilst the films on Si displayed a (002) WO3 out of plane fibre texture. The primary texture of the WOx films on SrTiO3 was observed to evolve from (200)/(020) WO3 to a single (002) WO3 texture with increasing fluence. The FeOx films deposited via reactive PLD onto glass substrates were found to exist in the Fe2O3 oxidation state for all parameters used. The production of Fe3O4 by post-deposition annealing of Fe films on glass and MgO (100) substrates in an oxygen environment is also presented. On both substrates it was necessary to use a two-stage anneal process to produce Fe3O4; an initial 175 °C oxygen anneal followed by a 500 °C vacuum anneal. The presence of Fe3O4 was confirmed by the existence of the Verwey transition at close to 120 K, during resistance vs temperature scans. The anneal parameters required to produce Fe3O4 are shown to be different for MgO substrates in comparison to glass.