Thesis. 1975. M.S.--Massachusetts Institute of Technology. Dept. of Earth and Planetary Sciences. / Bibliography: leaves 162-166. / by Susan Nygard. / M.S.

Thesis. 1977. Ph.D.--Massachusetts Institute of Technology. Dept. of Earth and Planetary Sciences. / Microfiche copy available in Archives and Science. / Vita. / Bibliography : leaves 315-344. / by Carlē Pieters. / Ph.D.

Gold-black has emerged as a popular absorptive coating for thermal radiation detectors in aerospace applications. The performance and accuracy of thermal radiation detectors largely depends on the surface optical properties of the absorptive coating. If the absorptivity of the layer is directional or wavelength dependent, then so will be the detector gain itself. This motivates our interest in the manufacture, physical characterization, and study of the wavelength and polarization sensitivity of the directional spectral absorptivity of gold-black. A first-principle model based on lossy antenna theory is presented to predict the polarization dependent directional spectral absorptivity of gold-black in the visible and near infrared. Results for normal spectral absorptivity are in good agreement with measurements reported in the literature. However, suitable experimental data were not available to validate the theory for directional spectral absorptivity. Therefore, an experimental campaign to fabricate and measure the directional spectral behavior of gold-black had to be undertaken to validate the first-principle model. New in-plane bidirectional reflectance distribution function (BRDF) measurements for two thicknesses (~4 μm and ~8 μm) of gold-black laid down on a gold mirror substrate are reported in the visible (532 nm) and near-infrared (800 and 850 nm) for p- and s-polarizations. The investigation is then extended to a three-layer sample, which is shown to exhibit off-specular reflectivity. Described are processes for laying down gold-black coatings and for measuring their in-plane BRDF as a function of thickness, wavelength, and polarization state. A novel method for retrieving the directional absorptivity from in-plane BRDF measurements is presented. The influence of polarization on directional absorptivity is shown to follow our earlier theory except at large incident zenith angles, where an unanticipated mirage effect is observed. / Doctor of Philosophy / Instruments called thermal radiation detectors play an important role in monitoring the global climate from space. Gold-black is often used as an absorptive coating to enhance the performance of these instruments. Users need to know how gold-black coatings influence instrument performance. In general, coating properties depend on the wavelength and direction of incident radiation, as well as on an optical phenomenon called polarization. This dissertation investigates the relationship between the creation of gold-black coatings and their performance. A physical model is postulated for predicting the optical behavior of gold-black in the visible and near infrared. The model produces results that are in good agreement with measurements reported in the literature. However, suitable directional measurements were not available to validate the theory. Therefore, an experimental campaign was mounted to fabricate gold-black coatings and measure their optical behavior in order to validate the mathematical model. We observed the optical behavior of several of our gold-black samples of various thickness and over a range of wavelengths. We also studied a three-layer sample which was found to exhibit an unexpected behavior called off-specular reflectivity. Described are processes for creating gold-black coatings and for measuring and explaining their optical performance. During the course of this investigation an unanticipated mirage effect was observed for the first time.

It has been found that traveling on the roadways at night is an inherently more dangerous task than driving during the daylight hours. Driving is primarily a visual task, and there are certain situations at night in which vision and safety may be compromised. The effects of glare produced by the headlamps of oncoming vehicles have become an interesting problem to many lighting researchers. Depending upon the opposing lighting design (beam distribution and intensity) and the lighting conditions inside the vehicle, oncoming headlamps can be both visually discomforting and disabling to drivers at night. In recent years, the newer High Intensity Discharge (HID) headlamps have raised some concern because of their increased light output and brighter appearance as opposed to traditional Halogen headlamps. The objective of this study was to evaluate the discomfort and disability glare produced by different oncoming headlamps under two driver light adaptation levels. This study took place on the Smart Road at the Virginia Tech Transportation Institute. During the Discomfort Glare portion, participants drove an experimental vehicle at 20mph past the oncoming headlamps and were asked to rate their overall discomfort with the subjective deBoer scale. The Disability Glare portion involved drivers detecting a static pedestrian in the roadway while approaching each different set of glare headlamps. It was hypothesized that there would be significant differences in detection distance and discomfort glare rating across the different glare headlamp and adaptation level combinations. It was also hypothesized that age would have a significant effect on detection distance, and the subjective ratings. The results of this study revealed many significant main effects and interactions for the discomfort and disability glare portions. The main effect of glare source was the only significant factor for discomfort glare. The main effects of age, glare source and pedestrian location were all significant for the disability portion. In addition, the interaction of pedestrian location and glare source was also significant. Overall, there was no clear relationship between subjective discomfort ratings and objective disability measures. The conclusions of this research will be valuable to the consumer as well as the manufacturers and designers of future headlamps in revealing how glare can affect drivers on the road at night. This information can help guide new designs to maximize forward visibility while minimizing glare. / Master of Science

Light reflectance from plants can be used as a non-invasive predictor of health and yield for many cropping systems, and has been investigated to a lesser extent with managed turfgrass systems. The frequent agronomic inputs associated with maintaining golf course grasses allow for exceptional stand quality under harsh growing conditions, but often expend resources inefficiently, leading to either stand loss or unnecessary inputs in localized areas. Turfgrass researchers have adopted some basic principles of light reflectance formerly developed for cropping systems, but field radiometric-derived narrow-band algorithms for turfgrass-specific protocols are lacking. Research was conducted to expand the feasibility of using radiometry to detect various turfgrass stressors and improve speed and geographic specificity of turfgrass management. Methods were developed to detect applied turfgrass stress from herbicide five days before visible symptoms developed under normal field growing conditions. Soil volumetric water content was successfully estimated using a water band index of creeping bentgrass canopy reflectance. The spectral reflectance of turfgrass treated with conventional synthetic pigments was characterized and found to erroneously influence plant health interpretation of common vegetation indices because of near infrared interference by such pigments. Finally, reflectance data were used to estimate root zone temperatures and root depth of creeping bentgrass systems using a gradient of wind velocities created with turf fans. Collectively, these studies provide a fundamental understanding of several turfgrass-specific reflectance algorithms and support unique opportunities to detect stresses and more efficiently allocate resources to golf course turf. / Ph. D.

Tissue optical clearing aims to increase the penetration depth of near-collimated light in biological tissue to enhance optical diagnostic, therapeutic, and cosmetic procedures. Previous studies have shown the effects of chemical optical clearing on tissue optical properties. Drawbacks associated with chemical clearing include the introduction of potentially toxic exogenous chemicals into the tissue, poor site targeting, as well as slow transport of the chemicals through tissue. Thus, alternative clearing methods have been investigated. Mechanical compression is one such alternative tissue optical clearing technique. The mechanisms of action of mechanical compression may be similar to those of chemical clearing, though they have yet to be investigated systematically. This research describes the design and execution of a number of procedures useful for the quantification of the tissue optical clearing effects of localized mechanical compression. The first experimental chapter presents the effects of compression on image resolution and contrast of a target imaged through ex vivo biological tissue. It was found that mechanical optical clearing allowed recovery of smaller targets at higher contrast sensitivity when compared to chemical clearing. Also, thickness-independent tissue clearing effects were observed. In the second experimental chapter, dynamic changes in tissue optical properties, namely scattering and absorption coefficients (?s' and ?a, respectively) were monitored during a controlled compression protocol using different indentation geometries. A reduction in ?s' and ?a was evident for all indentation geometries, with greater changes occurring with smaller surface area. Results indicate that localized mechanical compression may be harnessed as a minimally-invasive tissue optical clearing technique. / Master of Science

To understand the impact of N management on harvestable cover crop systems, seven research trials compared: 1) standard intensive management (SIM) (both fall and spring N application), 2) No fall N, a single spring N application, and 3) Cover N (no N application) effects on winter barley (Hordeum vulgare L.) plant biomass (PB), plant N uptake (PNU), grain yield, residual soil nitrate (RSN), and ammonium (RSA). In general, at winter dormancy, SIM resulted in increased PB and PNU but not RSN or RSA. At cover crop termination; SIM and the No fall N practices increased PNU, and at harvesting stage; they produced higher grain yields than the Cover N practice with little significant effect on RSN or RSA values, under normal climatic conditions. While overall yields for the No fall N treatment were lower (8%) than SIM yields, partial net return was similar due to decreased fertilizer input. Nitrogen use efficiency (NUE) of soft red winter wheat (SRWW) can be improved by characterizing genotypes for NUE using canopy spectral reflectance [(CSR), a cheap, rapid and non-destructive remote sensing tool]. The other objectives of this study were to evaluate the predictive potential of vegetative reflection indices for wheat nitrogen use efficiency (NUE) by genotype and the appropriate stages of CSR sensing. An elite panel of 281 regionally developed SRWW genotypes was screened under low and normal N regimes in two crop seasons for grain yield, N uptake, nitrogen use efficiency for yield (NUEY) and nitrogen use efficiency for protein (NUEP). The best models incorporating CSR data at wheat heading explained a significant proportion of total variation in grain yield, N uptake, NUEY and NUEP. Based on the best linear unbiased predictor values, genotypes were ranked and grouped into quartiles and the most efficient and responsive genotypes were identified. A significant proportion of the genotypes with high NUEY under high N conditions also had high NUEY under N stress; however, this was not the case for NUEP. Similarly, a significant proportion of genotypes with high NUEY also had high NUEP under both normal and low N conditions. / Ph. D.

Spectral reflectance-based, remote sensing technology has been used to adjust in-season nitrogen (N) fertilizer rates for wheat to account for spatial variability in grain yield potential at a sub-meter resolution. The objective of this study was to examine the relationships among spectral reflectance indices, corn tissue N content, chlorophyll measurements, plant size and spacing measurements, and grain yield to develop a similar strategy for variable-rate N management in corn. Irrigated and non-irrigated studies were conducted during the 2002 and 2003 growing seasons in eastern Virginia. Plots were treated with various rates of preplant, starter, and sidedress N fertilizer to establish a wide range of grain yield potential. Spectral measurements, tissue N, chlorophyll measurements, and plant physical measurements were collected at growth stages V6, V8, and V10. At maturity, grain yield was determined and correlated with in-season data and optimum N rate to calibrate in-season, variable-rate N fertilization strategies. Results from these studies indicate that spectral reflectance is well correlated with plant N uptake and chlorophyll meter readings and can also be correlated with final grain yield. These relationships may be used to develop a model to predict in-season, variable N application rates for corn production at a sub-meter resolution. / Master of Science

High resolution Optical Time Domain Reflectometry (OTDR) measurements have recently allowed spatial resolutions of less than one millimeter. These capabilities indicate that OTDR techniques may be suitable for non-conventional applications such as the determination of fiber strain. This thesis presents an investigation of how high resolution OTDR techniques can be used in such applications. The concept of fiber segmentation via partially reflective optical splices for local strain measurements is discussed both from a theoretical and practical standpoint. Experimental results demonstrating the feasibility of such local strain measurements are also given. Another part of this investigation considers the practical details of the proposed strain measurement technique, addressing such topics as launching conditions, and environmental factors. Possible applications of the local strain measurement techniques, such as two- and three-dimensional stress analysis, and strain determination of fiber optic cables, are also presented. These applications also include the development of small, easy to manufacture elastomeric optical splices, which were shown to yield acceptable performance < 0.2 dB losses) for multimode fibers. / Master of Science

The use of nitrogenous fertilizers in agricultural and forestry practices coupled with increased fossil fuel combustion and resulting nitrogen (N) deposition across the landscape have contributed to a near doubling of N inputs to terrestrial ecosystems.  With such dramatic changes have come adverse environmental consequences including the acidification of soil and water resources and an increased rate of biodiversity loss in both flora and fauna.  A method of rapidly predicting ecosystem susceptibility to N loss across large spatial scales would facilitate the identification of those systems most likely to contribute to potentially adverse environmental impacts.  To begin the development of such a framework, this research utilizes study sites located throughout the geographic ranges of Douglas-fir (Pseudotsuga menziesii) and loblolly pine (Pinus taeda) to explore relationships between hyperspectral remote sensing, N stable isotope ratios ("15N) and growth response to nitrogenous fertilizer.  In both species multiple linear regression models relating leaf-level reflectance to "15N showed strong predictive capabilities, with some models explaining more than 65% of the variance in "15N.  Significant correlations between "15N metrics and growth response to N fertilization were also observed in both species.  Additional exploratory analysis of the inclusion of "15N metrics with other environmental and edaphic variables to predict fertilizer growth response showed an increase in model performance with the addition of the enrichment factor (EF ="15NFol - "15NSoil).  This research demonstrates the ability of hyperspectral reflectance to predict "15N and reveals the potential of "15N to be included in future models to predict fertilizer growth response. / Master of Science