>Magister Scientiae - MSc / Aquifer vulnerability assessment is increasingly becoming a very significant basis in order to fulfil the water demands in South Africa. Knowledge of soil hydraulic properties that consists of the soil water retention and hydraulic conductivity functions is a prerequisite for predicting solution transport in soils. The overall objective of the study is to develop a database of hydraulic properties for collected undisturbed samples and to test selected models by making use of this database. Studies of the vadose zone are generally restricted to the top 1.2 meters; therefore this study aims at essentially improving the lack of measurements and modelling in the vadose zone. There exist several methods to determine hydraulic properties of soil that make use of hydraulic conductivity (K) determination in the vadose zone. The most accurate estimates of hydraulic conductivity are possible through direct measurements or measurements of the water retention curve. For this study, the drilling and sampling of five boreholes (maximum depth 20 m) proceeded during March and April 2005 at two typical sites in the Western Cape, namely the Berg river site (Riebeek West) and Ithemba site (Cape Flats). In total, 76 undisturbed core samples were collected from which the detailed borehole log descriptions were made. The determination of the soil water retention curves of the collected samples was based on laboratory techniques using Eijkelkamp drying and suction equipment (sand box and clay box). When modelling groundwater vulnerability, it is essential to look at the soil water retention curves with increased importance, as they provide graphical and mathematical confirmation of porosity, preferential flows, volumetric water content and unsaturated hydraulic conductivity. Therefore, a numerical model called RETC was used to determine soil hydraulic properties. The RETC model uses equations of Van Genuchten (Van Genuchten, 1980) and Brooks-Corey (Brooks and Corey, 1966) to determine parameters for soil water retention and the methods of Mualem (1976) and Burdine (1953) to determine unsaturated hydraulic conductivity functions. Saturated hydraulic conductivity values were estimated by using RETC soil database based on textural descriptions of collected samples. Using the soil hydraulic estimates obtained from RETC, sensitivity analyses were run with a one dimensional transport model, Macro 5.0 for two sites at iThemba and in the Berg river.

The most important characteristics of each soil is its hydro-physical properties, which include retention curve. Retention curve expresses the relationship between humidity and pressure head. It is course affected by many factors such as grain size and mineralogical composition, humus content, structure and bulk density of dry soil. This thesis deals with direct and indirect determination of one of the basic hydraulic characteristics of the soil, soil moisture retention curve. For laboratory determination of moisture retention curves were used for sand tank and pressure instruments. Measured body retention curves were optimized RETC program.For indirect determination of retention curves were used Pedotransfer function by Wösten et . al .(1998 ) , derived from the European soils and under HYPRES Šútora and Štekauerová (2000). As in the project Wösten et al . (1998), PTF were processed for arable land in the area. The accuracy of both models PTF was assessed by the correlation coefficient R and standard error RMSE. Simple models PTF provide estimates of retention curves with sufficient accuracy for practical use in the locality.