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No description available.

<p>An excessive input of nutrients to lakes and other water bodies has created a problem with eutrophication in Sweden. Untreated, or partially treated, domestic sewage is a major source for discharge of phosphorus (P), which is the nutrient most frequently responsible for eutrophication of most fresh waters and the Baltic Sea. The waste water can be cleaned by filter materials, which have a high P-retention ability and which after saturation may be used as fertilizers. Four potentially suitable filter materials were tested in batch- and column experiments in this study. In the batch experiments, the following materials were shaken with waste water in time series ranging from 5 seconds to 60 minutes: coarse (1-4 mm) and fine (0-2 mm) Polonite® (heated bedrock from Poland); Filtralite® (light expanded clay aggregates with limestone added before burning); water cooled blast furnace slag (BF-slag) and BF-slag mixed with 10% burned limestone. In the column experiment, the phosphorus sorption capacity in BF-slag and BF-slag mixed with burned limestone was observed under saturated and unsaturated flow conditions for 10 weeks. The waste water used in both experiments originated from the full scale testing site at Ångersjön in Sweden. After the column experiment was ended, the filter materials were investigated with XRD (X-ray diffraction) and SEM (scanning electron microscope) in order to figure out which chemical reactions that had taken place.</p><p>The results from the batch experiments show that fine Polonite® and BF-slag mixed with limestone have the fastest P sorption capacity. Already after 5 seconds of shaking the materials showed effective retention of P. The coarse Polonite®, Filtralite® and BF-slag showed similar sorption capacities, although the coarse Polonite® tended to be somewhat inferior. The column studies showed that the materials used in the columns had a sorption capacity of 98 % or more. The XRD and SEM indicated that an amorphous calcium-P-compound was created in the filter material.</p> / <p>I Sverige är reningen av fosfor i vatten från enskilda avlopp ofta bristfällig, vilket bland annat kan leda till övergödning av sjöar, hav och vattendrag. Sedan några år tillbaka har olika filtermaterial med speciella reaktiva egenskaper, som bland annat avskiljer fosfor från avloppsvatten, undersökts. Tanken med filtermaterialen är att de efter mättnad med näringsämnen ska kunnas användas som jordförbättringsmedel. I denna rapport har några olika filtermaterial, lämpade för fosforavskiljning, undersökts genom skak- och kolonnförsök. I skakförsök, där skaktiderna varierade mellan 5 sekunder och 60 minuter, testades Polonite®, Filtralite®, Hyttsand och Hyttsand blandad med 10 % bränd kalk. Polonite® är en upphettad form av bergarten opoka varav två olika kornstorleksfraktioner (0-2 mm och 1-4 mm) användes. Filtralite® och Hyttsand är antropogena filtermaterial. Filtralite® tillverkas i Norge och består av kalkhaltiga kulor av expanderad lera (Leca®). Hyttsand framställs genom vattenkylning av masugnsslagg som bildas vid framställningen av råjärn vid stålverket i Oxelösund. I kolonnförsöken, som utfördes under 10 veckor, studerades Hyttsand och Hyttsand blandad med 10 % bränd kalk under omättade och mättade flödesförhållanden. I samtliga experiment användes avloppsvatten från reningsverket vid Ångersjön, där Filtralite® och Hyttsand testas i fullskala. Efter kolonnförsöken avslutats undersöktes filtermaterialen med XRD (röntgendiffraktion) och SEM (svepelektron mikroskop) för att utreda vilka mekanismer som medverkat vid avskiljningen av fosfor.</p><p>Resultaten från skakförsöken visade att finkornig Polonite® och Hyttsand blandad med kalk avskiljer fosfor effektivt redan efter skakning i 5 sekunder. Grovkornig Polonite, ren Hyttsand och Filtralite® sorberade fosfor tämligen likartat, även om den grovkorniga Poloniten® tenderade att vara aningen sämre än de övriga. Resultaten från kolonnförsöken visade att fosfor kunde avskiljas till över 98 % i alla kolonner och att det bildats amorfa fosfatföreningar, främst med kalcium, under den 2,5 månader långa experimentperioden.</p>

An excessive input of nutrients to lakes and other water bodies has created a problem with eutrophication in Sweden. Untreated, or partially treated, domestic sewage is a major source for discharge of phosphorus (P), which is the nutrient most frequently responsible for eutrophication of most fresh waters and the Baltic Sea. The waste water can be cleaned by filter materials, which have a high P-retention ability and which after saturation may be used as fertilizers. Four potentially suitable filter materials were tested in batch- and column experiments in this study. In the batch experiments, the following materials were shaken with waste water in time series ranging from 5 seconds to 60 minutes: coarse (1-4 mm) and fine (0-2 mm) Polonite® (heated bedrock from Poland); Filtralite® (light expanded clay aggregates with limestone added before burning); water cooled blast furnace slag (BF-slag) and BF-slag mixed with 10% burned limestone. In the column experiment, the phosphorus sorption capacity in BF-slag and BF-slag mixed with burned limestone was observed under saturated and unsaturated flow conditions for 10 weeks. The waste water used in both experiments originated from the full scale testing site at Ångersjön in Sweden. After the column experiment was ended, the filter materials were investigated with XRD (X-ray diffraction) and SEM (scanning electron microscope) in order to figure out which chemical reactions that had taken place. The results from the batch experiments show that fine Polonite® and BF-slag mixed with limestone have the fastest P sorption capacity. Already after 5 seconds of shaking the materials showed effective retention of P. The coarse Polonite®, Filtralite® and BF-slag showed similar sorption capacities, although the coarse Polonite® tended to be somewhat inferior. The column studies showed that the materials used in the columns had a sorption capacity of 98 % or more. The XRD and SEM indicated that an amorphous calcium-P-compound was created in the filter material. / I Sverige är reningen av fosfor i vatten från enskilda avlopp ofta bristfällig, vilket bland annat kan leda till övergödning av sjöar, hav och vattendrag. Sedan några år tillbaka har olika filtermaterial med speciella reaktiva egenskaper, som bland annat avskiljer fosfor från avloppsvatten, undersökts. Tanken med filtermaterialen är att de efter mättnad med näringsämnen ska kunnas användas som jordförbättringsmedel. I denna rapport har några olika filtermaterial, lämpade för fosforavskiljning, undersökts genom skak- och kolonnförsök. I skakförsök, där skaktiderna varierade mellan 5 sekunder och 60 minuter, testades Polonite®, Filtralite®, Hyttsand och Hyttsand blandad med 10 % bränd kalk. Polonite® är en upphettad form av bergarten opoka varav två olika kornstorleksfraktioner (0-2 mm och 1-4 mm) användes. Filtralite® och Hyttsand är antropogena filtermaterial. Filtralite® tillverkas i Norge och består av kalkhaltiga kulor av expanderad lera (Leca®). Hyttsand framställs genom vattenkylning av masugnsslagg som bildas vid framställningen av råjärn vid stålverket i Oxelösund. I kolonnförsöken, som utfördes under 10 veckor, studerades Hyttsand och Hyttsand blandad med 10 % bränd kalk under omättade och mättade flödesförhållanden. I samtliga experiment användes avloppsvatten från reningsverket vid Ångersjön, där Filtralite® och Hyttsand testas i fullskala. Efter kolonnförsöken avslutats undersöktes filtermaterialen med XRD (röntgendiffraktion) och SEM (svepelektron mikroskop) för att utreda vilka mekanismer som medverkat vid avskiljningen av fosfor. Resultaten från skakförsöken visade att finkornig Polonite® och Hyttsand blandad med kalk avskiljer fosfor effektivt redan efter skakning i 5 sekunder. Grovkornig Polonite, ren Hyttsand och Filtralite® sorberade fosfor tämligen likartat, även om den grovkorniga Poloniten® tenderade att vara aningen sämre än de övriga. Resultaten från kolonnförsöken visade att fosfor kunde avskiljas till över 98 % i alla kolonner och att det bildats amorfa fosfatföreningar, främst med kalcium, under den 2,5 månader långa experimentperioden.

Thesis (M.S.)--Indiana University, 2007. / Department of Earth Sciences, Indiana University-Purdue University Indianapolis (IUPUI). Advisor(s): Philippe G. Vidon, Lenore P. Tedesco, Kathy J. Licht. Includes vitae. Includes bibliographical references (leaves 110-114).

Eutrophication is an increasing global concern as human effluent saturates lakes with an over abundance of nutrients. Phosphorus, generally being the limiting nutrient, is often the most impactful, allowing cyanobacteria populations to grow out of control leading to harmful blooms that can produce cyanotoxins, anoxic lake conditions, and mass fish kills. Utah Lake, a shallow highly eutrophic fresh water lake located in central Utah Valley, has experienced these harmful algal blooms for the last several years. The internal phosphorus cycle is a significant driver in Utah Lake's eutrophication, as the sediments act as both a sink and a source for phosphorus. Most of the phosphorus originates from external sources, gets captured by the sediment, and then through several physiochemical and biological process, gets released back into the surface water as a self sustaining eutrophication system. To determine the effects of the different physiochemical processes that drive the internal phosphorus system, we incubated 72 total sediment cores taken from two locations, chosen to best represent the lake's chemical and spatial variability, under aerobic, anaerobic, pH=9.5 and pH=7 conditions with various P concentrations (ambient, 0.5X, 2X, 4X) taking water samples at 0, 12, 24, and 72 hours. Dissolved oxygen (DO), pH, soluble reactive phosphorus (SRP), total dissolved phosphorus (TDP), and other major ions were measured for each sample. The highest P sediment release occurred under aerobic conditions, while the highest P sediment uptake occurred under anaerobic conditions. While pH did appear to have a mild effect on P flux, our study showed the lake has a remarkably stable bicarbonate buffer system making it unlikely that pH would contribute significantly under natural settings. Under all conditions the 2X and 4X cores experienced the highest P uptake, but final elevated P concentrations were still higher than initial ambient concentrations, indicating a probable delayed recovery time after external reductions occur.

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Eutrophication has long been an environmental problem and the effects from fertilizingarable land is a known source. The degree of phosphorus saturation (DPS)and easily soluble phosphorus (P) are different variables used in different countriesto try to predict the leaching of P from soils. The purpose of this master thesiswas to investigate what variable can be used as a predictor for leached P from soilsand to investigate what extent P leaching from the topsoil can be readsorbed inthe subsoil. The extraction method used for DPS was the Swedish standard lactateextraction and for easily soluble P were distilled water, CaCl2-solution and artificialrainwater with recipe from SMHI used. Three different soils in Sweden were used,two arable soils with different chemical properties and one forest soil. The soilswere filtered (2 mm) and put into columns since the texture was of interest ratherthan the structure. CaCl2-solution was used to saturate the samples and artificialrainwater was used for irrigation. The results showed that easily soluble P is areasonable indicator for leached P and that the subsoil affects the total leachingof P. However, no significant correlation was found between DPS and leached P,indicating that it may not be a suitable indicator of leaching. On the other hand,DPS can be seen as a reasonable indicator for easily soluble P since the correlationtest showed almost significant correlation. The results also showed that the electricconductivity in the leachate correlates to the leached P for the arable soils. For amore reliable result, more soils should be analyzed during more days.

Indiana University-Purdue University Indianapolis (IUPUI) / This study investigated nutrient export during three spring storm events in two different land use watersheds (agricultural and mixed land use) in a glacial till landscape of the Midwestern, USA. The objectives of the study were: (1) to determine how land use affects water, nitrate, soluble reactive phosphorus (SRP) and dissolved organic carbon (DOC) delivery (timing, amount) to streams during spring storms in two central Indiana watersheds with contrasting land use; and (2) to determine nitrate, SRP and DOC flow pathways to streams during spring storms. High frequency stream sampling of nutrients and cations, coupled with hydrograph separations using δ18O, was used to identify water flow pathways and event and pre-event water contributions to the streams. Data indicate land use and storm characteristics play a role in the export of water and nutrients. In the agricultural watershed (Watershed A), the storm hydrograph is dominated by pre-event water, whereas the mixed land use watershed (Watershed M) storm hydrograph is more event water dominated. Watershed A also contains higher nutrient concentrations, especially nitrate. High bulk precipitation and greater maximum intensity export more nitrate, SRP, and DOC to the streams. Results also indicate nitrate, DOC, and SRP concentrations display distinct temporal patterns during spring storm events. DOC concentration increased with stormflow and peaked on the rising limb/with maximum discharge regardless of land use or storm event. In Watershed A, SRP concentration followed a similar pattern to DOC during small storms; therefore they are believed to be exported together with flushing of saturated near-surface soil waters via macropores/overland flow. However, SRP likely has multiple flowpaths, one dominated over another depending on the storm. Nitrate concentrations matched Ca2+, Mg2+, and Na+ trajectories and decreased with stormflow, suggesting a tile drain/subsurface flowpath. Nitrate and SRP peak concentrations are delayed relative to DOC in Watershed M. The wet retention ponds in the headwaters are believed to delay the stormflow response, and therefore, the delivery of nutrients to the stream.

The aim of this diploma thesis was to clarify the differences among three different ponds (Bolevecký, Třemošenský, Šídlovský) situated in Pilsen. All of the above mentioned ponds are recreational areas where Bolevecký pond is best known for his water quality improvements since 2006 (after application of Fe and Al - colagulants and also fish - stock changes). The main difference was based on the growth of submersed water plants. The macrophytes were growing slowly or not at all in Bolevecký pond. There was a huge expansion of macrophytes (mainly Myriophyllum spicatum species) in Třemošenský and Šídlovský ponds therefore the water plants must be regulated during summer seasons by mechanical harvesting. The water in all three ponds proves the same qualities but the differences may be found in the nutrient composition of sediments. The fractionation analysis (the founders Psenner and Puczsko) confirmed the fact that all localities are poor in phosphorus however the differences were found in content of iron. The increased content of iron was observed in sediments of Šídlovksý and Třemošenský ponds (mainly in BD fraction - the iron was unstable under redox potential changes). The result of this analysis proves that phosphorus is potentially more available for macrophytes in sediments of Třemošenský and Šídlovský...