Today, a large quantity of waste is generated from the replacement of residential and commercial roofs. Many of the roofs being upgraded with previously constructed from asphalt shingles. Recycled Asphalt Shingles (RAS) contain nearly 30% of asphalt cement by mass, which can be a useful additive to asphalt pavements. In addition, shingles can offer significant potential savings through recycling and recovery as a construction material in flexible pavement. Currently, one and a half million tons of roofing shingle waste is generated each year in Canada related to the replacement of residential and commercial roofs and 90% of this valuable material is sent to landfills. If engineered properly, the addition of RAS into Hot Mix Asphalt (HMA) can provide significant benefits. The University of Waterloo’s Centre for Pavement and Transportation Technology (CPATT) is committed to working with public and private sector partners to develop sustainable technologies for the pavement industry. Using RAS in HMA can lead to economical, environmental and social benefits. Examples of which are reduced waste going to landfills and a reduction in the quantity of virgin material required. This research has involved the Ontario Centres of Excellence (OCE) and Miller Paving Limited. It was conducted to evaluate the performance of HMA containing RAS in both field and laboratory tests. A varying percentage of RAS was added to six common Ontario surface and binder layer of asphalt mixes. The intent was to determine if RAS could be added to improve performance and provide longer term cost savings. Laboratory testing was performed to evaluate the mix behavior. The elastic properties, fatigue life and resistance to thermal cracking were all evaluated at the CPATT laboratory. The characteristics of the mixes were evaluated by carrying out Dynamic Modulus, Resilient Modulus, Flexural Fatigue and Thermal Stress Restrained Specimen Test (TSRST) tests following American Association of State Highway and Transportation Officials (AASHTO) and American Society for Testing and Materials (ASTM) standards. Field test sections were constructed from HMA containing RAS to monitor the pavement behavior under natural environmental and traffic loading conditions. Evaluation of the field sites was performed using a Portable Falling Weight Deflectometer (PFWD) and carrying out distress surveys following the Ministry of Transportation Ontario (MTO) guidelines. The results to date show the sections performing very well with minimal to no distress developing. The results of the laboratory testing and field performance evaluations have shown encouraging results for the future use of RAS in HMA. If RAS can properly be engineered into HMA it can be a useful additive in both the surface and binder layers of the flexible pavement structure. Ultimately, the use of RAS in HMA can provide both an environmentally friendly and cost effective solution to the Ontario paving industry.

Today, a large quantity of waste is generated from the replacement of residential and commercial roofs. Many of the roofs being upgraded with previously constructed from asphalt shingles. Recycled Asphalt Shingles (RAS) contain nearly 30% of asphalt cement by mass, which can be a useful additive to asphalt pavements. In addition, shingles can offer significant potential savings through recycling and recovery as a construction material in flexible pavement. Currently, one and a half million tons of roofing shingle waste is generated each year in Canada related to the replacement of residential and commercial roofs and 90% of this valuable material is sent to landfills. If engineered properly, the addition of RAS into Hot Mix Asphalt (HMA) can provide significant benefits. The University of Waterloo’s Centre for Pavement and Transportation Technology (CPATT) is committed to working with public and private sector partners to develop sustainable technologies for the pavement industry. Using RAS in HMA can lead to economical, environmental and social benefits. Examples of which are reduced waste going to landfills and a reduction in the quantity of virgin material required. This research has involved the Ontario Centres of Excellence (OCE) and Miller Paving Limited. It was conducted to evaluate the performance of HMA containing RAS in both field and laboratory tests. A varying percentage of RAS was added to six common Ontario surface and binder layer of asphalt mixes. The intent was to determine if RAS could be added to improve performance and provide longer term cost savings. Laboratory testing was performed to evaluate the mix behavior. The elastic properties, fatigue life and resistance to thermal cracking were all evaluated at the CPATT laboratory. The characteristics of the mixes were evaluated by carrying out Dynamic Modulus, Resilient Modulus, Flexural Fatigue and Thermal Stress Restrained Specimen Test (TSRST) tests following American Association of State Highway and Transportation Officials (AASHTO) and American Society for Testing and Materials (ASTM) standards. Field test sections were constructed from HMA containing RAS to monitor the pavement behavior under natural environmental and traffic loading conditions. Evaluation of the field sites was performed using a Portable Falling Weight Deflectometer (PFWD) and carrying out distress surveys following the Ministry of Transportation Ontario (MTO) guidelines. The results to date show the sections performing very well with minimal to no distress developing. The results of the laboratory testing and field performance evaluations have shown encouraging results for the future use of RAS in HMA. If RAS can properly be engineered into HMA it can be a useful additive in both the surface and binder layers of the flexible pavement structure. Ultimately, the use of RAS in HMA can provide both an environmentally friendly and cost effective solution to the Ontario paving industry.

abstract: This research focused on the structure-property relationships of a rejuvenator to understand the comprehensive rejuvenation mechanism of aged asphalt binder. Aged asphalt such as recycled asphalt shingles (RAS) and reclaimed asphalt pavement (RAP) contain various amounts of asphalt binder. However, the asphalt binder in RAS and RAP is severely aged and inferior in properties compared to a virgin binder. To address this issue, liquid additives have been used under the general title of rejuvenators. That poses an additional challenge associated with the lack of clear metrics to differentiate between softeners and rejuvenators. Therefore, there is a need for a thorough study of rejuvenators. In this study, diverse-sourced rejuvenators have been used in RAS and RAP-modified binders as well as laboratory-prepared aged binders. The properties of the rejuvenated aged binder were characterized at a macro-level and molecular level. The study showed that the performance of the RAS-modified binder was significantly improved after bio-modification by a bio-rejuvenator. This study further evaluated laboratory-prepared aged asphalt rejuvenated with different rejuvenators. The results found that oxidized bitumen became soft after adding rejuvenators, regardless of their source. Molecular dynamics simulation showed that the effective rejuvenator restored the molecular conformation and reduced the size of asphaltene nanoaggregates. The study results showed that due to the specific chemical composition of certain rejuvenators, they may negatively impact the durability of the mixture, especially about its resistance to moisture damage and aging. Computational analysis showed that while the restoration capacity of rejuvenators is related to their penetration into and peptizing of asphaltene nanoaggregates, the durability of the restored aged asphalt is mainly related to the polarizability values of the rejuvenator. Rejuvenators with lower polarizability showed better resistance to aging and moisture damage. In summary, this study develops the rheology-based indicators which relate to the molecular level phenomenon in the rejuvenation mechanism. The rheology-based indicators, for instance, crossover modulus and crossover frequency differentiated the rejuvenators from recycling agents. Moreover, the study found that rejuvenation efficiency and durability are depended on the chemistry of rejuvenators. Finally, based on the learning of chemistry, a chemically balanced rejuvenator is synthesized with superior rejuvenation properties. / Dissertation/Thesis / Doctoral Dissertation Civil, Environmental and Sustainable Engineering 2020