Atlantic Canadian highways are vulnerable to impacts of climate change, including more frequent cycles of both wetting and drying, and freezing and thawing. These climate impacts coupled with continued increases in truck traffic can cause more severe and premature permanent deformation at high service temperature, fatigue and thermal cracking at low service temperatures, surface wear resistance, and ageing of the pavement. Such negative impacts can be mitigated with changes to the binder. However, replacing a local binder with a different imported binder can increase construction costs and cause supply problems. Alternatively, modifying agents can be used to adjust binder properties as required, but can also cause an increase in construction costs mainly due to their high cost and the need for highly specialized production techniques. The objective of this research project was to investigate the feasibility of utilizing underutilized household and packaging recycled plastics, that are generated in Atlantic Canada, as more cost effective alternatives or as co-modifiers to displace the amount of virgin modifiers used in hot mix asphalt application. The research study entailed analyzing physical characteristics of an array of modified binders and hot mix asphalt mixtures containing recycled low-density polyethylene, recycled polystyrene and the typical engineered virgin modifier (styrene-butadiene-styrene). The analysis included tests used commonly in pavement engineering to evaluate binders and asphalt mixtures. Results of this study suggests that these recycled plastics can be successfully utilized in asphalt binder as modifiers to enhance the functional properties of the mixture and reduce construction costs, thus creating an engineered value-added application of these underutilized resources as opposed to a disposal mechanism.

Wood plastic composites (WPCs) were made using matrices of recycled high-density polyethylene (rHDPE) and polypropylene (rPP) with sawdust (Pinus radiata) as filler. Corresponding WPCs were also made using virgin plastics (HDPE and PP) for comparison with the recycled plastic based composites. WPCs were made through melt compounding and hot-press moulding with varying formulations based on the plastic type (HDPE and PP), plastic form (recycled and virgin), wood flour content and addition of coupling agent. The dimensional stability and mechanical properties of WPCs were investigated. Durability performances of these WPCs were studied separately, by exposing to accelerated freeze-thaw (FT) cycles and ultraviolet (UV) radiation. The property degradation and colour changes of the weathered composites were also examined. Dimensional stability and flexural properties of WPCs were further investigated by incorporation of nanoclays in the composite formulation. To understand the changes in WPCs stability and durability performance, microstructure and thermal properties of the composites were examined. Two mathematical models were developed in this work, one model to simulate the moisture movement through the composites in long-term water immersion and the other model to predict the temperature profile in the composites during hot-press moulding. Both rHDPE and rPP matrix based composites exhibited excellent dimensional stability and mechanical properties, which were comparable to those made from virgin plastics. Incorporation of maleated polypropylene (MAPP) coupling agent in composite formulation improved the stability and the mechanical properties. The incorporation of 3 wt. % MAPP coupling agent to WPCs showed an increase in tensile strength by 60% and 35 %, respectively, for the rHDPE based and rPP based composites with 50 wt. % wood flour. Scanning electron microscopy (SEM) images of the fractured surfaces of WPCs confirmed that the MAPP coupling improved the interfacial bonding between the plastic and the wood filler for both series of composites. Long-term water immersion tests showed that the water transport mechanism within the WPCs follows the kinetics of Fickian diffusion. Dimensional stability and flexural properties of the WPC were degraded after 12 accelerated FT cycles as well as 2000 h of UV weathering for both recycled and virgin HDPE and PP based composites. However, the MAPP coupled composites had improved stability and flexural property degradation. The surface of the weathered composites experienced a colour change, which increased with the exposure time. The MAPP coupled composites exhibited less colour change as compared to non-coupled composites. Regarding the effect of the plastic type, the PP based composites experienced higher colour change than those based on HDPE. With weathering exposure, flexural strength and stiffness of the WPCs were decreased, but elongation at break was increased regardless of plastic type and wood flour content. MAPP coupled rPP and rHDPE based UV weathered WPCs lowered the degradation of stiffness by 50% and 75%, respectively compared to non-coupled WPCs. SEM images of the fractured surfaces of FT and UV weathered WPCs confirmed a decrease in the interfacial bonding between the wood flour and matrix. Thermal properties of weathered composites changed with weathering, but the extent of the changes depended on WPCs formulation and matrix type. From the experimental studies on nanoclay-filled rHDPE composites, it is found that stability, flexural properties of WPCs could be improved with an appropriate combination of coupling agent, and nanoclay contents processed by melt blending. Incorporation of 1-5 wt. % nanoclay in the maleated polyethylene (MAPE) coupled wood plastic composite improved the dimensional stability and flexural properties. The thermal properties changed with the addition of nanoclay and MAPE in WPCs. In this work, a hot press-moulding model was proposed based on the one-dimensional transient heat conduction to predict the temperature profile of the WPCs during hot pressing cycle. The results from this work clearly show that rHDPE and rPP can be successfully used to produce stable and strong WPCs, which properties and performances are similar to or comparable to composites made of wood and virgin plastics. Therefore, WPCs based on recycled PP and HDPE matrix could have potential to use as construction materials.

In the last three decades, the increased use of plastics is rapidly becoming a global environmental issue, resulting in growing landfills and pollution of air and water. The automotive industry, as a major demander of plastic materials, is starting to take responsibility with promised sustainability actions. One action relates to the concept of circular economy and closed loop thinking through the implementation of recycled plastics. However, the barriers of such implementations are still undiscovered, with research missing out on the challenges of strategic and business perspectives. The aim of this thesis is to asses and understand the challenges connected to implementing recycled plastics in the automotive industry, and to provide strategic recommendations. In order to identify the challenges, an empirical case study was carried out collecting data through 10 interviews with suppliers throughout the plastics refining chain. A cost calculation was also included, to highlight the economic potentials of recycled plastics. The findings address 6 themes as barriers for implementing recycled plastics in the automotive industry: economic, organizational, infrastructural, interactional, design and technical barriers. The barriers shed light on the challenges connected to the implementation of recycled plastics and concludes that the rate of recycled plastics in a car can be increased, which also increases sustainability and circular thinking. However, the rates could be further improved if managers were to consider the existing barriers when implementing higher rates of recycled plastics in their components.

This thesis investigates the suitability of thermo-kinetically recycled plastics for use in commercial product applications using finite element analysis and statistics. Different recycled material blends were tested and evaluated for their use in commercial product applications. There are six different blends of thermo-kinetically recycled plastics used for testing and CATIA is used for finite element analysis. The different types of thermo-kinetically recycled plastics blends are: pop bottles made of PolyethyleneTeraphthalate (PET), milk jugs made of High-Density Polyethylene (HDPE), Vinyl seats made of Poly Vinyl Chloride (PVC) and small amount of Polypropylene (PP) and Urethane, electronic scrap made of engineering resins like Acrylo-Nitrile-Butadiene Styrene (ABS), Polystyrene (PS) and Polycarbonate (PC), agriculture waste consisting of Low Density Polyethylene (LDPE), industrial waste consisting of Nylon (PA66) and PolyethyleneTeraphthalate (PET), household waste consisting of Polystyrene (PS). The methods employed during the study include three phases for each of six blends available: 1.Density, tensile and impact testing of each blend 2.Correlation of mechanical properties to blend 3.Finite element analysis of the service performance of a product made from each thermo-kinetically recycled plastic blend This thesis shows that some of the recycled plastics materials that were tested are qualified to be used in the pallet. Those materials that qualified were Industrial waste consisting of Nylon and PolyethyleneTeraphthalate, household waste consisting of Polystyrene.

The diploma thesis deals with the use of recycled polymers in asphalt mixtures. In the theoretical part of the thesis there is discussed the global issue of plastic waste including the experience of foreign countries, where this technology has already been introducted and used. The practical part is devoted to the proposal of using recycled plastic in asphalt mixture, description of used laboratory tests and the evaluating the effect of low-density polyethylen (LDPE) on the asphalt mixture type AC. There were performed tensile strenght tests, water resistant tests and stiffness modulus tests in the laboratory (E). The output of this work is an evaluation of measured values, processing of results and their interpretation depending on the possible use of this technology in Czech republic.

The diploma thesis deals with the use of recycled polymers in asphalt mixtures. In the theoretical part of the thesis there is discussed the global issue of plastic waste including the experience of foreign countries, where this technology has already been introducted and used. The practical part is devoted to the proposal of using recycled plastic in asphalt mixture, description of used laboratory tests and the evaluating the effect of low-density polyethylen (LDPE) on the asphalt mixture type AC. There were performed tensile strenght tests, water resistant tests and stiffness modulus tests in the laboratory (E). The output of this work is an evaluation of measured values, processing of results and their interpretation depending on the possible use of this technology in Czech republic.

Described in many studies as dangerous for the environment and potentially carcinogenic for humans, Chlorinated Paraffins (CPs) are easily widespread due to their substantial production and use in different products. Previous studies reported the presence of CPs in different plastic polymers. However, the impact of recycled content in plastic materials on the CPs levels hasn’t particularly been considered. Recycling plastics is becoming essential but the accumulative potential of pollutants, such as CPs, need investigations. The presence of CPs in both virgin and mixed recycled and virgin plastics was studied. Plastic pellets and plastic pieces from products made of three polymer types:Poly(methyl 2-methylpropenoate) (PMMA), Thermoplastic Rubber (TPR) and Thermoplastic Polyurethane (TPU) were analysed. A solid-liquid extraction assisted by ultrasonication was performed, followed by cleanup using silica. CPs in plastic extracts were analysed by Gas Chromatography Orbitrap High Resolution Mass Spectroscopy (GC-Orbitrap-HRMS). Because of the high volatility characteristic of long chain Chlorinated Paraffins (LCCPs), only short chain and medium chain Chlorinated Paraffins (SCCPs and MCCPs ) have been studied in this project. Interesting variations in the presence of SCCPs and MCCPs have been observed from one polymer type to another. In the results, we show that MCCPs were less frequently detected compared to SCCPs. A higher detection frequency of CPs was observed for samples containing recycled plastics. The results indicate that CPs are present in plastic polymers (TPU, PMMA and TPR) and that the content of recycled material has a direct impact on the levels of SCCPs and MCCPs.