Three laboratory studies were performed to elucidate the influence of soil texture, pH, and cation exchange capacity (CEC) on the concentration of ferrous Fe in soil solution and the resulting expression of soil redoximorphic features. The objectives were: 1) assess the buffering effects of CEC on ferrous Fe concentration in soil solution, 2) evaluate the effects of pH on the concentration of ferrous Fe in soil solution, and 3) observe the expression of redoximorphic features in soils with varying texture and CEC. The studies concentrated on seasonally wet soils from the Texas Gulf Coast Prairie. Selected soils included Alfisols and Vertisols with characteristics ranging from coarse-loamy to very-fine in texture, strongly acidic to neutral in soil reaction, and siliceous, mixed, and smectitic in mineralogy. The soils included the Pledger clay microlow (acidic, fine-textured), Pledger clay microhigh (neutral, fine-textured), China clay (acidic, fine-textured), Cieno loam (acidic, fine-loamy), Orelia sandy clay loam (neutral, fine-loamy), Gessner fine sandy loam (acidic, coarse-loamy), and Orelia fine sandy loam (neutral, coarse-loamy). The studies provided the following information: 1) fine-textured soils with higher CEC contained more ferrous Fe in solution, 2) ferrous Fe concentrations in the acidic fine-loamy and coarse-loamy soils were higher than the neutral soils for the same textural class, 3) acidic and neutral fine-textured soils contained more ferrous Fe in solution than the remaining soils, 4) the highest percentage of redox concentrations was observed in the acidic, fine-textured soil, 5) the acidic fine-loamy and coarse-loamy soils exhibited a greater percentage of Fe depletions, and 6) a higher percentage of redox features were observed by micromorphic analysis (i.e., point counts under a binocular stereoscopic microscope) than by macromorphic descriptions. This research showed that differing soil characteristics affect the reductive dissolution and translocation of Fe, and subsequent formation of redox features.

In recent years, the success of wetland mitigation projects and their ability to function as natural systems has been questioned. This study was conducted (i) to characterize and examine differences between mitigation and natural wetlands, (ii) to examine differences in soil morphology along a wetness gradient in mitigation and natural wetlands, and (iii) to observe changes in mitigation wetlands with time. Site characteristics, including soil properties, hydrology, and vegetation, were analyzed for three mitigation-reference wetland pairs located in the Virginia Coastal Plain. Hydrologic regimes of mitigation areas, when compared to reference areas, generally showed larger differentials between seasonal high and low watertables. Mitigation areas, dominated by herbaceous vegetation, tended to be lower in C and N levels and higher in soil pH, and much higher in bulk density than the mature forested reference wetland. Initially low levels of C and N did not increase significantly over the five-year study period. Soils in the mitigation area were more uniform and considerably less differentiated when compared to those of the reference area. Testing for Fe(II) with alpha-alpha, dipyridyl dye solution produced mixed results, obtaining both positive and negative reactions to saturated samples. Oxidized rhizospheres, associated with active root channels in surface horizons, formed in less than ten years under the current hydrologic conditions. These features were more abundant and more prominent in areas saturated at or above the surface for longer periods of time. Overall, site differences between mitigation and reference areas are mainly due to construction practices and a lack of organic matter accumulation. Better design methods should incorporate the addition of organic amendments, with attempts to minimize soil compaction. / Master of Science

Interpreting soil wetness in upland transported soils on flat broad summits in the central Piedmont of Virginia containing chroma ≥ 3 redoximorphic features (RMFs) can be difficult. It is imperative to understand their saturation regimes because onsite wastewater disposal systems, which are sited based upon soil evaluations, have failed prematurely when installed into these problematic soils. My objectives were to determine if soil morphology was an accurate predictor of soil wetness and permeability, to differentiate interpretations for colluvial soils from residual soils, and to determine the effect of canopy cover on seasonal wetness. Soil morphology, soil wetness regimes in open and wooded canopies, and in-situ saturated hydraulic conductivity were documented in transported Appomattox, Bentley, Brockroad, Catharpin, and Dothan and residual Clifford, Minnieville, and Penhook soil series at eight sites. Transported soils had average winter water levels, and met 30-day and 20-day NRCS oxyaquic criteria at 81, 66, and 91 cm, respectively. Transported soils with depleted ped faces, Fe- concentrations, and chroma 3 depletions were saturated an average of 41, 23, and 41% of the winter, respectively. Residuum found ≥ 1.5 m beneath transported soils exhibited little saturation, thus confirming epiaquic conditions. Residual soils did not perch water for extended periods; and were saturated for significantly (p<0.001) shorter durations and shallower depths (average 93 and 82 cm for 30-day and 20-day oxyaquic criteria, respectively). Transported soils under clear cuts had significantly (p<0.001) shallower average water levels (79 cm) and 30-day and 20-day oxyaquic conditions (51 and 88 cm, respectively) than wooded locations (87 and 83 cm average water levels and 30-day oxyaquic water table, respectively). In-situ hydraulic testing confirmed the presence of low permeability layers as determined by soil evaluation. Restrictive layers were thicker and less permeable in transported soils than in residual soils. In summary, water perches seasonally for extended periods over thick impermeable layers in transported soils. A recommended best management practice for problematic transported soils would be to not install septic systems in zones of saturation and low permeability, including the 1.5 m below a discontinuity. Drainfield designs should utilize permeable saprolite beneath transported material and an upslope curtain drain. / Ph. D.

O Pantanal é a maior planície continental inundável do mundo, englobando um mosaico de diferentes habitats, sustentando grande diversidade vegetal, animal e de solos. É constituído por onze sub-regiões, sendo uma delas a do Pantanal de Barão de Melgaço, que está localizado ao nordeste dessa bacia sedimentar quaternária. Apresenta uma heterogeneidade espacial de solos que está relacionada com a diversidade de feições geomórficas. Estas, adicionadas aos tipos de inundação, geram uma grande diversidade de microhabitats: Cordilheiras, Paleodiques, Murunduns, constituem as formas de relevo raramente inundáveis, enquanto que as Planícies fluviais, Campos, Baías, Corixos e Vazantes apresentam inundações anuais ou permanentes. No Pantanal de Barão de Melgaço, as altitudes variam de 100 a 150m e a declividade é inexpressiva. O material de origem dos solos é formado por sedimentos arenosos, síltico-arenosos, argilo-arenosos e arenoconglomeráticos semiconsolidados a consolidados a Formação Pantanal. Contém uma diversidade única de solos, freqüentemente com mineralogia 2:1, cuja morfologia reflete as condições de regime hídrico de cada microambiente: Planossolos, Plintossolos, Planossolos Nátricos, Vertissolos e Neossolos Flúvicos se distribuem de acordo com as feições geomórficas encontradas, sendo na grande maioria afetados por processos redoximórficos. O objetivo desta dissertação foi caracterizar e conhecer os processos pedogenéticos dos solos de um sistema pedológico Planossolo-Plintossolo em duas das principais feições geomórficas do Pantanal de Barão de Melgaço. O estudo foi realizado na RPPN (Reserva Particular do Patrimônio Natural) SESC Pantanal, no município de Barão de Melgaço, Estado de Mato Grosso. No sistema pedológico estudado foram identificados quatro solos da classe dos Plintossolos Argilúvicos e Háplico e dois Planossolos Nátricos. A transição dos Planossolos Nátricos para os Plintossolos é evidencia a pela perda gradual do caráter sódico e aumento do processo de plintização. À medida que ocorre a redução da saturação por Na+, a CTC dos solos torna-se saturada por Al3+. A presença de solos com caráter sódico ou nátrico nas partes altas da paisagem, pode ser uma evidência das mudanças climáticas que ocorreram no Pantanal, neste caso tratando-se de solos reliquiais. As principais causas da manutenção dos altos teores de Na nos Planossolos Nátricos, são a porosidade muito fechada dos horizontes subsuperficiais e as elevadas taxas de evapotranspiração no Pantanal, mesmo ocorrendo em posição mais elevada na paisagem local. Os Nódulos de Fe e Mn que ocorrem nesses solos não são pedorelíquias. Foram formados e continuam se formando em condições climáticas atuais. / The Pantanal is the largest continental flood plains, comprising a mosaic of different habitats, maintaining plant diversity, animal and soil. It consists of eleven sub-regions, one of which the of the Pantanal of Barão de Melgaço, which is located north of the Quaternary sedimentary basin. It presents a spatial heterogeneity that is related to the diversity of geomorphic features. This, added to the types of flooding and soil, generate a wide variety of microhabitats: Cordileira paleoriverbanks, termite hills, the forms of relief are rarely flooded, while the Plains river, Grasslands, Bays, Corixo and present ebb Annual floods or permanent. In the Pantanal of Barão de Melgaço, the above sea level ranging from 100 to 150m and the slope is negligible. The parent material of the soil is composed of sandy sediment, síltico-sand, clay-sandy and sandyconglomerate semiconsolidados the consolidated Training Pantanal. It contains a unique diversity of soils, often with 2:1 mineralogy, whose morphology reflects the conditions of water regime of each microenvironment: Planosols, Plinthosols, Solonetz, Vertisols and Fluvisols are distributed according to the geomorphic features found, and the great most affected by processes redoximorphic. The goal of this dissertation was to characterize and identify the processes pedogenetic soil of a system pedological Solonetz-Plinthosol in two of the main geomorphic features of the Pantanal of Barão de Melgaço. The study was conducted in RPPN (Private Reserve of Natural Heritage) SESC Pantanal, in the Barão de Melgaço county, State of Mato Grosso from Brazil. The transition of Solonetz for Plinthosol is given by the gradual loss of sodium and increase character of the plintização. As is the reduction of the saturation of Na+, the CEC soil becomes saturated by Al3+. The presence of soil character natric in the hillslope is an evidence of climate changes that occurred in the Pantanal, where the soils relic. The main causes of maintenance of high levels of Na in Solonetz are very closed the porosity of subsurface horizons and high rates of evapotranspiration in the Pantanal. The nodules of Fe and Mn that occur in these soils are not relic and were formed and are still forming in weather conditions to actually.

O Pantanal é a maior planície continental inundável do mundo, englobando um mosaico de diferentes habitats, sustentando grande diversidade vegetal, animal e de solos. É constituído por onze sub-regiões, sendo uma delas a do Pantanal de Barão de Melgaço, que está localizado ao nordeste dessa bacia sedimentar quaternária. Apresenta uma heterogeneidade espacial de solos que está relacionada com a diversidade de feições geomórficas. Estas, adicionadas aos tipos de inundação, geram uma grande diversidade de microhabitats: Cordilheiras, Paleodiques, Murunduns, constituem as formas de relevo raramente inundáveis, enquanto que as Planícies fluviais, Campos, Baías, Corixos e Vazantes apresentam inundações anuais ou permanentes. No Pantanal de Barão de Melgaço, as altitudes variam de 100 a 150m e a declividade é inexpressiva. O material de origem dos solos é formado por sedimentos arenosos, síltico-arenosos, argilo-arenosos e arenoconglomeráticos semiconsolidados a consolidados a Formação Pantanal. Contém uma diversidade única de solos, freqüentemente com mineralogia 2:1, cuja morfologia reflete as condições de regime hídrico de cada microambiente: Planossolos, Plintossolos, Planossolos Nátricos, Vertissolos e Neossolos Flúvicos se distribuem de acordo com as feições geomórficas encontradas, sendo na grande maioria afetados por processos redoximórficos. O objetivo desta dissertação foi caracterizar e conhecer os processos pedogenéticos dos solos de um sistema pedológico Planossolo-Plintossolo em duas das principais feições geomórficas do Pantanal de Barão de Melgaço. O estudo foi realizado na RPPN (Reserva Particular do Patrimônio Natural) SESC Pantanal, no município de Barão de Melgaço, Estado de Mato Grosso. No sistema pedológico estudado foram identificados quatro solos da classe dos Plintossolos Argilúvicos e Háplico e dois Planossolos Nátricos. A transição dos Planossolos Nátricos para os Plintossolos é evidencia a pela perda gradual do caráter sódico e aumento do processo de plintização. À medida que ocorre a redução da saturação por Na+, a CTC dos solos torna-se saturada por Al3+. A presença de solos com caráter sódico ou nátrico nas partes altas da paisagem, pode ser uma evidência das mudanças climáticas que ocorreram no Pantanal, neste caso tratando-se de solos reliquiais. As principais causas da manutenção dos altos teores de Na nos Planossolos Nátricos, são a porosidade muito fechada dos horizontes subsuperficiais e as elevadas taxas de evapotranspiração no Pantanal, mesmo ocorrendo em posição mais elevada na paisagem local. Os Nódulos de Fe e Mn que ocorrem nesses solos não são pedorelíquias. Foram formados e continuam se formando em condições climáticas atuais. / The Pantanal is the largest continental flood plains, comprising a mosaic of different habitats, maintaining plant diversity, animal and soil. It consists of eleven sub-regions, one of which the of the Pantanal of Barão de Melgaço, which is located north of the Quaternary sedimentary basin. It presents a spatial heterogeneity that is related to the diversity of geomorphic features. This, added to the types of flooding and soil, generate a wide variety of microhabitats: Cordileira paleoriverbanks, termite hills, the forms of relief are rarely flooded, while the Plains river, Grasslands, Bays, Corixo and present ebb Annual floods or permanent. In the Pantanal of Barão de Melgaço, the above sea level ranging from 100 to 150m and the slope is negligible. The parent material of the soil is composed of sandy sediment, síltico-sand, clay-sandy and sandyconglomerate semiconsolidados the consolidated Training Pantanal. It contains a unique diversity of soils, often with 2:1 mineralogy, whose morphology reflects the conditions of water regime of each microenvironment: Planosols, Plinthosols, Solonetz, Vertisols and Fluvisols are distributed according to the geomorphic features found, and the great most affected by processes redoximorphic. The goal of this dissertation was to characterize and identify the processes pedogenetic soil of a system pedological Solonetz-Plinthosol in two of the main geomorphic features of the Pantanal of Barão de Melgaço. The study was conducted in RPPN (Private Reserve of Natural Heritage) SESC Pantanal, in the Barão de Melgaço county, State of Mato Grosso from Brazil. The transition of Solonetz for Plinthosol is given by the gradual loss of sodium and increase character of the plintização. As is the reduction of the saturation of Na+, the CEC soil becomes saturated by Al3+. The presence of soil character natric in the hillslope is an evidence of climate changes that occurred in the Pantanal, where the soils relic. The main causes of maintenance of high levels of Na in Solonetz are very closed the porosity of subsurface horizons and high rates of evapotranspiration in the Pantanal. The nodules of Fe and Mn that occur in these soils are not relic and were formed and are still forming in weather conditions to actually.

Hypersaline tidal flats (HTFs) are transitional ecosystems commonly occurring in arid and semiarid coastal areas. (e.g. Australia and New Caledonia), Africa (e.g. Senegal, Gambia, and Madagascar), Central America (e.g. Nicaragua), South America (e.g. Ecuador and on the north, northeast, and southeast Brazilian coasts). Due to their location, HTFs might exert biogeochemical control over cycling of nutrients (e.g. Fe and Si) across the land to ocean transition, accelerating or retarding the nutrient export to the ocean and other adjacent ecosystems. This biogeochemical control is governed by soil physicochemical conditions (e.g. pH and salinity) and pedogenesis (e.g. redox processes). Thus, study of the soil coloidal fraction, the pedogenic processes, and the distribution of Si in the different soil components can provide a detailed characterization of HTF soils and give insights into the Si dynamics in these environments. In view of this, two HTFs on the Brazilian coast were studied on the Brazilian coast and the data are presented here. The first chapter aims to investigate the pedogenesis in HTF soils based on detailed morphological descriptions and Fe and Mn sequential extractions. The second chapter discusses silicon geochemistry in HTF soils based on sequential extractions, SEM, and XRD modeling of the fine clay fraction. And lastly, the third one reports the characteristics, distribution, and genesis of clay minerals in HTF soils on the basis of XRD modeling, TEM-EDS, FTIR, and XRF analysis. Redox reactions control the pedogenic evolution in HTF soils. These processes lead to a mobilization of Fe2+ and Mn2+ upward in the soils profiles, followed by oxidation and precipitation of Fe and Mn oxyhydroxides. These reactions, along with pyrite oxidation, lead to a transformation of the deeper soil horizons. Formation of Fe oxyhydroxides in the uppermost soil horizons exerts control on Si dynamics by co-precipitation and adsorption reactions. Together, Si associated with Fe oxyhydroxides and amorphous silicates are the main components of the readily soluble Si pool in HTF soils. The environmental conditions are conducive to clay transformations in the soils. Our data indicate that kaolinite is progressively altered to Mg-rich smectite through mixed-layering, withdrawing Si from the soil porewater. / Planícies hipersalinas costeiras (PHCs) são ecossistemas transicionais comumente encontrados em regiões áridas e semiárias. Estes ambientes são encontrados em várias regiões do mundo, tais como Oceania (e.g. Austrália e Nova Caledónia), África (e.g. Senegal, Gambia e Madagascar), América Central (e.g. Nicarágua), América do Sul (e.g. Equador e as costas norte, nordeste e sudeste do Brasil). Por estarem posicionados na transição entre os ecossistemas marinhos e de terras altas, os solos de PHCs devem exercer um controle biogeoquímico na ciclagem de nutrientes (e.g. Si e Fe), afetando o fluxo dos mesmo para o oceano e ecossitemas adjacentes. Este controle biogeoquímico é governado pelas condições fisico-químicas do meio (e.g. pH e salinidade) e pelos processos pedogenéticos atuantes nos solos (e.g. processos redox). Desta forma, o estudo da fração coloidal, da pedogênese e da distribuição do Si nos diferentes componentes do solo possibilita caracterizar detalhadamente os solos de PHCs e desvendar os processos que controlam a dinâmica de Si no ambiente. Portanto, duas PHCs localizadas na costa brasileira foram estudadas e os resultados estão apresentados em três capítulos nesta tese. O primeiro capítulo teve por objetivo investigar a pedogênese em PHCs com base em estudos morfológicos e extrações sequenciais de Fe e Mn. O segundo discute a geoquímica de silício nos solos com base em extrações sequenciais, MEV e modelagem de raios-X da fração argila fina. O terceiro capítulo discorre sobre as características, distribuição e gênese de argilominerais nos solos com base em modelagem de raios-X, MET-EDS, FTIR e FRX. As reações redox parecem controlar a evolução pedogenética nestes solos, as quais levam à mobilização ascendente de Fe2+ e Mn2+ nos perfis, oxidação da pirita e, consequentemente, transformação dos horizontes mais profundos. Estes processos também são responsáveis pela formação de oxihidróxidos de Fe e Mn nos horizontes superiores dos perfis de solo, levando à um controle do Si por reações de co-precipitação e adsorção envolvendo oxihidróxidos de Fe. O Si associado aos oxihidróxidos de Fe e silicatos amorfos são os principais componentes da fração mais solúvel de Si nos solos estudados. As condições ambientais nas PHCs são favoráveis às transformações minerais. Os dados indicam que a caulinita é alterada para esmectitas magnesianas por processos de interestratificação, removendo Si da solução do solo.

Hypersaline tidal flats (HTFs) are transitional ecosystems commonly occurring in arid and semiarid coastal areas. (e.g. Australia and New Caledonia), Africa (e.g. Senegal, Gambia, and Madagascar), Central America (e.g. Nicaragua), South America (e.g. Ecuador and on the north, northeast, and southeast Brazilian coasts). Due to their location, HTFs might exert biogeochemical control over cycling of nutrients (e.g. Fe and Si) across the land to ocean transition, accelerating or retarding the nutrient export to the ocean and other adjacent ecosystems. This biogeochemical control is governed by soil physicochemical conditions (e.g. pH and salinity) and pedogenesis (e.g. redox processes). Thus, study of the soil coloidal fraction, the pedogenic processes, and the distribution of Si in the different soil components can provide a detailed characterization of HTF soils and give insights into the Si dynamics in these environments. In view of this, two HTFs on the Brazilian coast were studied on the Brazilian coast and the data are presented here. The first chapter aims to investigate the pedogenesis in HTF soils based on detailed morphological descriptions and Fe and Mn sequential extractions. The second chapter discusses silicon geochemistry in HTF soils based on sequential extractions, SEM, and XRD modeling of the fine clay fraction. And lastly, the third one reports the characteristics, distribution, and genesis of clay minerals in HTF soils on the basis of XRD modeling, TEM-EDS, FTIR, and XRF analysis. Redox reactions control the pedogenic evolution in HTF soils. These processes lead to a mobilization of Fe2+ and Mn2+ upward in the soils profiles, followed by oxidation and precipitation of Fe and Mn oxyhydroxides. These reactions, along with pyrite oxidation, lead to a transformation of the deeper soil horizons. Formation of Fe oxyhydroxides in the uppermost soil horizons exerts control on Si dynamics by co-precipitation and adsorption reactions. Together, Si associated with Fe oxyhydroxides and amorphous silicates are the main components of the readily soluble Si pool in HTF soils. The environmental conditions are conducive to clay transformations in the soils. Our data indicate that kaolinite is progressively altered to Mg-rich smectite through mixed-layering, withdrawing Si from the soil porewater. / Planícies hipersalinas costeiras (PHCs) são ecossistemas transicionais comumente encontrados em regiões áridas e semiárias. Estes ambientes são encontrados em várias regiões do mundo, tais como Oceania (e.g. Austrália e Nova Caledónia), África (e.g. Senegal, Gambia e Madagascar), América Central (e.g. Nicarágua), América do Sul (e.g. Equador e as costas norte, nordeste e sudeste do Brasil). Por estarem posicionados na transição entre os ecossistemas marinhos e de terras altas, os solos de PHCs devem exercer um controle biogeoquímico na ciclagem de nutrientes (e.g. Si e Fe), afetando o fluxo dos mesmo para o oceano e ecossitemas adjacentes. Este controle biogeoquímico é governado pelas condições fisico-químicas do meio (e.g. pH e salinidade) e pelos processos pedogenéticos atuantes nos solos (e.g. processos redox). Desta forma, o estudo da fração coloidal, da pedogênese e da distribuição do Si nos diferentes componentes do solo possibilita caracterizar detalhadamente os solos de PHCs e desvendar os processos que controlam a dinâmica de Si no ambiente. Portanto, duas PHCs localizadas na costa brasileira foram estudadas e os resultados estão apresentados em três capítulos nesta tese. O primeiro capítulo teve por objetivo investigar a pedogênese em PHCs com base em estudos morfológicos e extrações sequenciais de Fe e Mn. O segundo discute a geoquímica de silício nos solos com base em extrações sequenciais, MEV e modelagem de raios-X da fração argila fina. O terceiro capítulo discorre sobre as características, distribuição e gênese de argilominerais nos solos com base em modelagem de raios-X, MET-EDS, FTIR e FRX. As reações redox parecem controlar a evolução pedogenética nestes solos, as quais levam à mobilização ascendente de Fe2+ e Mn2+ nos perfis, oxidação da pirita e, consequentemente, transformação dos horizontes mais profundos. Estes processos também são responsáveis pela formação de oxihidróxidos de Fe e Mn nos horizontes superiores dos perfis de solo, levando à um controle do Si por reações de co-precipitação e adsorção envolvendo oxihidróxidos de Fe. O Si associado aos oxihidróxidos de Fe e silicatos amorfos são os principais componentes da fração mais solúvel de Si nos solos estudados. As condições ambientais nas PHCs são favoráveis às transformações minerais. Os dados indicam que a caulinita é alterada para esmectitas magnesianas por processos de interestratificação, removendo Si da solução do solo.

Nesta pesquisa foram estudadas morfologias e posições do relevo que apresentam solos e depósitos com regimes hídricos caracterizados pela saturação temporária ou permanente, tendo os seguintes objetivos: (i) caracterização dos solos e depósitos presentes no setor inferior de vertentes e em fundos de vale, incluindo planícies fluviais, com ênfase em suas propriedades hidromórficas; (ii) identificação de graus de hidromorfia nos solos e depósitos desses setores e morfologias, e representação de sua variabilidade espacial; (iii) elaboração de proposições a respeito do regime de saturação hídrica nos setores estudados e de sua relação com os graus de hidromorfia identificados; (iv) elaboração de proposições sobre tendências espaciais hidrodinâmicas associadas à inundação fluvial nas áreas de planície. Sob o aspecto metodológico, a pesquisa foi desenvolvida de acordo com os princípios da abordagem geossistêmica, apresentando uma análise integrada que buscou identificar as inter-relações entre as variáveis pesquisadas. Para tal estudo, foram selecionados dois perfis transversais na Alta Bacia Hidrográfica do Rio Cotia, que abrangeram o setor inferior de vertentes e fundos de vale, um deles com planície fluvial. Ao longo desses perfis transversais foram realizados os seguintes levantamentos e procedimentos: (i) levantamento morfométrico e construção de gráficos dos perfis; (ii) descrição dos atributos morfológicos dos solos e depósitos; (iii) monitoramento dos níveis dágua do lençol freático ou lençol suspenso nos pontos de descrição. A caracterização e análise detalhadas das propriedades hidromórficas revelaram gradações de intensidade nas mesmas, e, a partir dessa base, desenvolveu-se uma proposta para classificação dos solos e depósitos segundo graus de hidromorfia. Foram construídas representações gráficas bidimensionais que ilustraram a sucessão vertical e lateral de horizontes pedogenéticos e camadas com diferentes graus de hidromorfia ao longo dos setores e morfologias estudadas. Desta maneira, foram identificadas tendências gerais no que se refere à distribuição espacial dos graus de hidromorfia e à relação desses graus com o regime de saturação hídrica. Um dos padrões identificados consistiu no aumento do grau de hidromorfia dos perfis verticais de solos e depósitos com o aumento da profundidade, que está associado a um maior tempo de duração das condições de saturação hídrica nos horizontes mais profundos. Também foram observadas diferenças significativas na intensidade das propriedades hidromórficas das vertentes, quando comparadas às áreas de fundos de vale, incluindo a planície fluvial. Neste sentido, foram identificados graus de hidromorfia mais baixos nos horizontes A e B dos pontos localizados nas vertentes, e graus mais elevados nos horizontes A e B dos pontos localizados nos fundos de vale. Essas diferenças na ocorrência dos graus de hidromorfia foram atribuídas a distintos regimes de saturação hídrica, sendo que, de maneira geral, os horizontes pedogenéticos e as camadas com graus de hidromorfia elevados estão sujeitos a condições de saturação hídrica de maior duração ou permanentes, quando comparados àqueles que possuem graus de hidromorfia mais baixos, nos quais os eventos de saturação hídrica tem menor duração e/ou ocorrem com menor frequência. Com relação às proposições referentes à inundação fluvial na planície estudada, foram identificadas morfologias que recebem preferencialmente os fluxos fluviais da inundação e apresentam taxas de deposição mais elevadas, e setores com taxas de deposição mais baixas nos quais a inundação é menos frequente e há predomínio da deposição de sedimentos finos. / In this research we studied morphologies and relief positions with soils and deposits with moisture regimes characterized by temporary or permanent water saturation, with the following objectives: (i) characterization of soils and deposits located in lower slope sectors and valley bottoms, with an emphasis on their hydromorphic properties; (ii) identification of degrees of hydromorphy in the soils and deposits of these sectors and morphologies, and representation of their spatial variability; (iii) development of propositions about the regime of water saturation in the studied areas and its relationship with the degrees of hydromorphy; (iv) development of propositions about the hydrodynamics of floods in the studied floodplain. Regarding the methodological aspect, the research was conducted according to the principles of the geosystemic approach, presenting an integrated analysis which considered the inter-relations among the studied variables. For this study, we selected two cross profiles in the Cotia Drainage Basin, comprising lower slope sectors and valley bottoms, including a floodplain. Along these cross profiles, the following surveys were conducted: (i) topographic survey and construction of cross section graphics; (ii) description of the morphological attributes of soils and deposits, including detailed description of their hydromorphic properties; (iii) monitoring the water levels of the water table and perched water tables in the sites of description. The detailed characterization and analysis of the hydromorphic properties revealed gradations of intensity in them, and, based primarily on this, we developed a proposal for classification the soils and deposits of the study area according to degrees of hydromorphy. We built two-dimensional graphical representations which illustrated vertical and lateral successions of pedogenetic horizons or layers with different degrees of hydromorphy. Thus, general trends were identified in respect to the spatial distribution of the degrees of hydromorphy and in respect to its relationship with the regime of water saturation. One of the patterns identified consisted in the increase of the degree of hydromorphy in the soil profiles with increasing depth, associated with a longer duration of water saturation conditions in the deeper horizons. It were also observed significant differences in the intensity of the hydromorphic properties of the slopes, when compared to the valley bottom areas, including the floodplain. In this regard, lower degrees of hydromorphy were identified in the A and B horizons in the slope sectors, and higher degrees in the A and B horizons in the valley bottom areas. Such differences in the degree of hydromorphy were ascribed to distinct regimes of water saturation, considering that, in general, the horizons and layers with higher degrees of hydromorphy are subject to water saturation conditions of longer duration, when compared to those classified according to lower degrees of hydromorphy, in which the water saturation events have shorter duration and/or have lower frequency. Concerning the propositions about the hydrodynamics of floods in the studied floodplain, we identified morphologies that preferentially receive the overflowing river flows and have higher deposition rates, and sectors with lower deposition rates, where flooding is less frequent and there is a predominance of fine sediments deposition.

Nesta pesquisa foram estudadas morfologias e posições do relevo que apresentam solos e depósitos com regimes hídricos caracterizados pela saturação temporária ou permanente, tendo os seguintes objetivos: (i) caracterização dos solos e depósitos presentes no setor inferior de vertentes e em fundos de vale, incluindo planícies fluviais, com ênfase em suas propriedades hidromórficas; (ii) identificação de graus de hidromorfia nos solos e depósitos desses setores e morfologias, e representação de sua variabilidade espacial; (iii) elaboração de proposições a respeito do regime de saturação hídrica nos setores estudados e de sua relação com os graus de hidromorfia identificados; (iv) elaboração de proposições sobre tendências espaciais hidrodinâmicas associadas à inundação fluvial nas áreas de planície. Sob o aspecto metodológico, a pesquisa foi desenvolvida de acordo com os princípios da abordagem geossistêmica, apresentando uma análise integrada que buscou identificar as inter-relações entre as variáveis pesquisadas. Para tal estudo, foram selecionados dois perfis transversais na Alta Bacia Hidrográfica do Rio Cotia, que abrangeram o setor inferior de vertentes e fundos de vale, um deles com planície fluvial. Ao longo desses perfis transversais foram realizados os seguintes levantamentos e procedimentos: (i) levantamento morfométrico e construção de gráficos dos perfis; (ii) descrição dos atributos morfológicos dos solos e depósitos; (iii) monitoramento dos níveis dágua do lençol freático ou lençol suspenso nos pontos de descrição. A caracterização e análise detalhadas das propriedades hidromórficas revelaram gradações de intensidade nas mesmas, e, a partir dessa base, desenvolveu-se uma proposta para classificação dos solos e depósitos segundo graus de hidromorfia. Foram construídas representações gráficas bidimensionais que ilustraram a sucessão vertical e lateral de horizontes pedogenéticos e camadas com diferentes graus de hidromorfia ao longo dos setores e morfologias estudadas. Desta maneira, foram identificadas tendências gerais no que se refere à distribuição espacial dos graus de hidromorfia e à relação desses graus com o regime de saturação hídrica. Um dos padrões identificados consistiu no aumento do grau de hidromorfia dos perfis verticais de solos e depósitos com o aumento da profundidade, que está associado a um maior tempo de duração das condições de saturação hídrica nos horizontes mais profundos. Também foram observadas diferenças significativas na intensidade das propriedades hidromórficas das vertentes, quando comparadas às áreas de fundos de vale, incluindo a planície fluvial. Neste sentido, foram identificados graus de hidromorfia mais baixos nos horizontes A e B dos pontos localizados nas vertentes, e graus mais elevados nos horizontes A e B dos pontos localizados nos fundos de vale. Essas diferenças na ocorrência dos graus de hidromorfia foram atribuídas a distintos regimes de saturação hídrica, sendo que, de maneira geral, os horizontes pedogenéticos e as camadas com graus de hidromorfia elevados estão sujeitos a condições de saturação hídrica de maior duração ou permanentes, quando comparados àqueles que possuem graus de hidromorfia mais baixos, nos quais os eventos de saturação hídrica tem menor duração e/ou ocorrem com menor frequência. Com relação às proposições referentes à inundação fluvial na planície estudada, foram identificadas morfologias que recebem preferencialmente os fluxos fluviais da inundação e apresentam taxas de deposição mais elevadas, e setores com taxas de deposição mais baixas nos quais a inundação é menos frequente e há predomínio da deposição de sedimentos finos. / In this research we studied morphologies and relief positions with soils and deposits with moisture regimes characterized by temporary or permanent water saturation, with the following objectives: (i) characterization of soils and deposits located in lower slope sectors and valley bottoms, with an emphasis on their hydromorphic properties; (ii) identification of degrees of hydromorphy in the soils and deposits of these sectors and morphologies, and representation of their spatial variability; (iii) development of propositions about the regime of water saturation in the studied areas and its relationship with the degrees of hydromorphy; (iv) development of propositions about the hydrodynamics of floods in the studied floodplain. Regarding the methodological aspect, the research was conducted according to the principles of the geosystemic approach, presenting an integrated analysis which considered the inter-relations among the studied variables. For this study, we selected two cross profiles in the Cotia Drainage Basin, comprising lower slope sectors and valley bottoms, including a floodplain. Along these cross profiles, the following surveys were conducted: (i) topographic survey and construction of cross section graphics; (ii) description of the morphological attributes of soils and deposits, including detailed description of their hydromorphic properties; (iii) monitoring the water levels of the water table and perched water tables in the sites of description. The detailed characterization and analysis of the hydromorphic properties revealed gradations of intensity in them, and, based primarily on this, we developed a proposal for classification the soils and deposits of the study area according to degrees of hydromorphy. We built two-dimensional graphical representations which illustrated vertical and lateral successions of pedogenetic horizons or layers with different degrees of hydromorphy. Thus, general trends were identified in respect to the spatial distribution of the degrees of hydromorphy and in respect to its relationship with the regime of water saturation. One of the patterns identified consisted in the increase of the degree of hydromorphy in the soil profiles with increasing depth, associated with a longer duration of water saturation conditions in the deeper horizons. It were also observed significant differences in the intensity of the hydromorphic properties of the slopes, when compared to the valley bottom areas, including the floodplain. In this regard, lower degrees of hydromorphy were identified in the A and B horizons in the slope sectors, and higher degrees in the A and B horizons in the valley bottom areas. Such differences in the degree of hydromorphy were ascribed to distinct regimes of water saturation, considering that, in general, the horizons and layers with higher degrees of hydromorphy are subject to water saturation conditions of longer duration, when compared to those classified according to lower degrees of hydromorphy, in which the water saturation events have shorter duration and/or have lower frequency. Concerning the propositions about the hydrodynamics of floods in the studied floodplain, we identified morphologies that preferentially receive the overflowing river flows and have higher deposition rates, and sectors with lower deposition rates, where flooding is less frequent and there is a predominance of fine sediments deposition.

Wetlands serve important ecosystem functions such as carbon sequestration but are often affected by disturbances like urban development, agriculture, and road building. For wetlands created to mitigate losses, it is important that the ecosystem functions successfully replicate those of natural wetlands. Created wetlands have frequently not provided these functions due to issues including low organic carbon (OC), high soil bulk density (BD), lost topsoil, incorrect hydrology, and failure of targeted vegetation establishment. Organic matter (OM) amendments help created wetlands attain these functions quicker, but, their long-term effects are seldom reported. This research's purpose was to measure the long-term effects of treatments at a sandy tidal freshwater wetland created in 2003 (WWE) and a fine-textured, non-tidal wetland created in 2002 (CCW). We tested OM treatments, topsoil amendment, and microtopography effects on soil and vegetation properties at WWE and OM treatments at CCW. Pedogenic changes in soil morphology, physical and chemical properties were detected by comparing data to previous studies at these sites. At both sites, litter and biomass parameters were measured to estimate total mass C. Herbaceous biomass was measured at WWE. At WWE, no long-term OM treatment effects from 78 or 156 Mg ha-1 were observed. Soils in pits had higher OC, lower BD, and lower chroma than soils on mounds. Sandy and loamy HSFI's developed at WWE within four years, but there were fewer sandy indicators after 12 years. Loamy HSFI's were lost at CCW from 2003 to 2016. Plots at WWE that were amended with topsoil had higher soil mass C than the sandy soil due to a finer texture, but total mass C did not vary. At CCW, long-term OM treatment effects were observed, including lower BD, higher soil mass C, and higher tree mass C with increasing compost rates up to 224 Mg ha-1. Overall, the ideal compost loading rate for constructed wetlands varied with wetland type and mitigation goals. Compost rates of 112 Mg ha-1 are sufficient for short term establishment of wetland vegetation and hydric soil properties, but higher rates near 224 Mg ha-1 may be required for effects that last over 10 years. / Ph. D. / Wetlands are unique habitats that provide environmental benefits such as carbon storage but are often negatively affected by human disturbances such as urban development and road construction. When wetlands are constructed to mitigate natural wetland losses, it is important that they successfully provide the benefits of the wetlands they replace. Created wetlands have frequently not functioned like natural wetlands due to soil issues including low organic carbon (OC) and high soil density (BD). Organic matter (OM) amendments such as composted yard waste help created wetlands attain these functions quickly after construction compared to unamnded wetlands. The purpose of this study was to measure long-term (greater than 10 years) effects of OM treatments on soil and vegetation properties at two different created wetlands. The two wetlands were a sandy tidal freshwater wetland created in 2003 (WWE) and a fine-textured, compacted, non-tidal wetland created in 2002 (CCW). Previous soil data were compared to recent soil samples to detect changes in physical and chemical soil properties over time. At WWE, soils in pits accumulated more OM, were higher in carbon, lower in BD, and had greyer color than soils in mounds. Hydric soil field indicators developed from upland soil within four years after construction at WWE. There were no long term compost effects on soil properties compared to a fertilized control, but the compost rates used were low compared to other recommendations, and the wetland was constructed carefully to avoid compaction. There were much higher rates of compost applied at CCW, which produced lower BD, higher soil mass C, and higher tree biomass. We recommend applying OM and avoiding compaction during wetland construction. Ideal OM loading rate depends on wetland type (soil texture, hydrology) and mitigation goals. In the fine-textured, compacted wetland studied here, compost rates of 112 Mg ha⁻¹ are ideal for short term establishment of wetland vegetation and soil properties, but higher rates near 224 Mg ha⁻¹ may be required for long term effects.