The influence of yielding foundations on the mechanical behaviour of reinforced soil walls including wall deformations and loads (strains) in the reinforcement layers is very complex. Based on a review of the literature, there is a need to quantify and isolate the influence of foundation boundary type and magnitude of foundation stiffness on deformations and reinforcement loads in geosynthetic reinforced soil walls. This thesis presents the results of a series of 1/6-scale reinforced soil wall model tests that were carried out to examine the influence of horizontal and vertical toe compliance and vertical foundation compressibility on wall behaviour. The heavily instrumented walls were constructed in a strongbox that was 1.2 m high by 1.6 m wide and retained soil to a distance of 2.3 m behind the facing. The models were uniformly surcharged in stages following construction. The experimental program consisted of three groups of tests. Group 1 tests involved five walls. One wall was constructed with a very stiff horizontal restraint, and three walls were constructed with different horizontal toe stiffness using combinations of coiled springs. The remaining wall in this series was constructed without any horizontal toe restraint. Group 2 was comprised of three walls. One wall was a control wall with a rigid toe. The other two walls were constructed with different vertical toe stiffness support using different combinations of rubber blocks. Group 3 included a control wall with a rigid foundation and a companion wall constructed with a compressible foam and rubber layers below the backfill soil and the wall facing. The results demonstrate that the quantitative behaviour of the models was affected by the type and magnitude of foundation stiffness. For example, as horizontal toe stiffness increased a greater portion of the total horizontal earth load against the wall facing was carried by the toe. The data showed that the shape of facing lateral deformation profiles changed from rotation about the toe for the case of a very stiff horizontal toe to a more uniform profile for the unrestrained toe case. For the case of a rigid vertical footing support below the facing, vertical toe loads were greater than those computed from facing self-weight alone due to down-drag forces developed at the facing–reinforcement connections as the wall facing moved outward. As vertical toe support stiffness decreased with respect to foundation compressibility below the soil backfill, the magnitude of soil down-drag forces diminished resulting in a decrease in vertical toe load. / Thesis (Master, Civil Engineering) -- Queen's University, 2007-10-27 12:15:56.027

Reducing tillage in Canadian organic cropping systems is a priority to preserve soil quality and increase long term sustainability. Novel methods for management of cover crops offer farmers the opportunity to reduce both tillage and herbicide use during this phase of the crop rotation but require further investigation across a range of cropping systems. The objective of this study was to compare the blade roller, flail mower and wide blade cultivator (noble blade) with standard tillage for management of an annual pea-barley (Pisum sativum L. – Hordeum vulgare L.) green manure in the Canadian prairies. The experiment was conducted twice at Carman, Manitoba (long-term organic management) and Lethbridge, Alberta (previous herbicide and fertilizer use) from 2010-2012. The green manure was planted in spring of year 1 and grown until pea full bloom when five management treatments were applied; 1) standard tillage with a field disc 2) blade roller, 3) blade rolled once plus tillage in late fall and spring, 4) wide blade cultivator and 5) flail mower. Spring wheat (Triticum aestivum L.) was planted in spring of year 2. The effect of management treatment on surface residue, soil nitrogen, soil microclimate, weed population dynamics and subsequent spring wheat yield was evaluated. At Carman, managing green manure without tillage (blade roller or flail mower) significantly increased winter annual and perennial weed pressure and reduced soil nitrate availability; these factors contributed to wheat yield reductions in both years compared to standard tillage. Wide blade cultivation and blade rolling plus tillage maintained crop yield at one and both years, respectively, compared to tillage. Without sufficient mulch for weed suppression, soil disturbance was required to control weeds and ensure adequate nitrogen uptake in the crop. Replacing one tillage operation with blade rolling reduces energy costs and erosion risk without sacrificing yield. At Lethbridge, previous herbicide and fertilizer use masked the effect of green manure management. Markedly different results from Carman and Lethbridge emphasize that the adaptability of reduced tillage green manure management is site-specific due to differences in climate and cropping history. This research highlights important differences in the efficacy, erosion risk, weed control, nitrogen availability, main crop yield and energy savings associated with each management method.

No description available.

The primary objective of this work is to develop an approach for evaluating GHG mitigation strategies that considers the detailed operation of the electricity system in question and to ascertain whether considering the detailed operation of the electricity system materially affects the assessment. A secondary objective is to evalute the potential benefit of flexible CO2 capture and storage. An electricity system simlator is developed based upon a deregulated electricity system containing markets for both real and reserve power. Using the IEEE RTS ???96 as a test case, the performance of the electricity system is benchmarked with GHG regulation. Two different implementations of CO2 capture are added to the electricity system ??? fixed CO2 capture and flexible CO2 capture ??? and the impact of having CCS is assessed. The results indicate that: - the assessment of GHG mtigation strategies for the electricity generation subsector should consider the detailed operation of the electricity system in question, - cost of generation alone is not necessarily a good indicator of the economic impact of GHG regulation or the deployment of a GHG mitigation strategy, - adding CCS, at even a single generating unit, can significantly reduce GHG emissions and moderate the ecnomic impact of GHG regulation relative to the cases where CCS is not present, and - a generating unit with a flexible CCS processes participates preferentially in the reserve market enabling it to increase its net energy benefit. It is conclued that there is a significant potential advantage to generating units with flexible CCS processes. The flexibiity of existing and novel CCS process should be an assessment and design criterion, respectively, and the development of novel CCS processes with optimial operability is a suggested area of future research activity. A reduced-order model of a coal-fired generating unit with flexible CO2 capture is developed and integrated into the MINLP formulation of an economic dispatch model. Both of these efforts, not observed previously in the literature, constitute an important contribution of the work as the methodology provides a template for future assessmments of CCS and other electricity mitigation strategies in the electricity generation subsector.

Reducing tillage in Canadian organic cropping systems is a priority to preserve soil quality and increase long term sustainability. Novel methods for management of cover crops offer farmers the opportunity to reduce both tillage and herbicide use during this phase of the crop rotation but require further investigation across a range of cropping systems. The objective of this study was to compare the blade roller, flail mower and wide blade cultivator (noble blade) with standard tillage for management of an annual pea-barley (Pisum sativum L. – Hordeum vulgare L.) green manure in the Canadian prairies. The experiment was conducted twice at Carman, Manitoba (long-term organic management) and Lethbridge, Alberta (previous herbicide and fertilizer use) from 2010-2012. The green manure was planted in spring of year 1 and grown until pea full bloom when five management treatments were applied; 1) standard tillage with a field disc 2) blade roller, 3) blade rolled once plus tillage in late fall and spring, 4) wide blade cultivator and 5) flail mower. Spring wheat (Triticum aestivum L.) was planted in spring of year 2. The effect of management treatment on surface residue, soil nitrogen, soil microclimate, weed population dynamics and subsequent spring wheat yield was evaluated. At Carman, managing green manure without tillage (blade roller or flail mower) significantly increased winter annual and perennial weed pressure and reduced soil nitrate availability; these factors contributed to wheat yield reductions in both years compared to standard tillage. Wide blade cultivation and blade rolling plus tillage maintained crop yield at one and both years, respectively, compared to tillage. Without sufficient mulch for weed suppression, soil disturbance was required to control weeds and ensure adequate nitrogen uptake in the crop. Replacing one tillage operation with blade rolling reduces energy costs and erosion risk without sacrificing yield. At Lethbridge, previous herbicide and fertilizer use masked the effect of green manure management. Markedly different results from Carman and Lethbridge emphasize that the adaptability of reduced tillage green manure management is site-specific due to differences in climate and cropping history. This research highlights important differences in the efficacy, erosion risk, weed control, nitrogen availability, main crop yield and energy savings associated with each management method.

The current trend in the wind power industry is to develop wind turbines of constantly increasing size and rated power, as well as wind farms of growing size and installed wind power. A careful study of the behaviour of the wind turbines during their operation is of crucial importance in the planning phase and in the design stage of a wind farm, in order to minimize the risks deriving from a non accurate prediction of their impact in the electric grid causing sensible faults of the system. To analyze the impact of the wind turbines in the system, motivates the development of accurate yet simple models. To be able to practically deal with this topics, a simple model of a wind turbine system is investigated and developed; it has the aim to describe the behaviour of a wind turbine in operation on a mechanical standpoint. The same reduced order simple model can also be employed for control system studies; the control system model that can’t be used in generation, can use the reduced model. Together with the analytical description of such model, is realized a MatLab code to numerically analyse the response of the system, and the results of the simulation through such code are presented. The objective of this thesis has been to provide a simple benchmark tool in MatLab for grid integration and control studies for interested researchers.

Forest rings are large features common in Ontario’s boreal forests that comprise circular topographic depressions in carbonate mineral soil that are filled with peat. This thesis documents differences in peat and soil chemistry along transects across the “Bean” and “Thorn North” rings, which are centered on accumulations of CH4 and H2S, respectively. Within the mineral soil, ring edges are characterized by strong negative anomalies in pH, ORP and carbonate, as well as positive anomalies of Al, Fe and Mn in the results of aqua regia and hydroxylamine-hydrochloride digestions. Within the peat, positive carbonate and pH anomalies are recorded. This antithetic relationship suggests vertical migration of carbonate species from clay to peat. An inverse relationship exists between ORP, versus redox inferred from aqua regia. Strong ORP lows occur where oxidized products show highest concentrations. This is interpreted to reflect the proliferation of autotrophic organisms occupying the strong redox gradient at the ring edge.

Small quantities of reduced sulphur compounds (RSCs) emitted from Kraft pulp mills can affect air quality due to low odour thresholds. Chromatographic methods were developed for individual RSCs at ppt to ppb concentrations. Analyses of ambient air samples showed that while H2S, CH3SH, DMS and DMDS were linked to the pulp mill, the majority of COS and CS2 was due to other sources unrelated to the mill. The fluxes of individual RSCs from kraft wastewater clarifiers were quantified for the first time. DMDS and DMS were the major RSCs emitted from the primary and secondary clarifiers, respectively. RSC fluxes were one to three orders of magnitude higher at the primary clarifier than at the secondary one. Clarifier emissions were, however, insignificant compared to point sources in the mill. Statistically significant correlations were found between the DMS emission and BOD, COD, as well as TSS in the secondary treatment system.

Because of its high theoretical specific capacity (4200mAh/g) and natural abundance (2nd most abundant element on earth), silicon is considered a promising anode candidate for high energy density lithium-ion batteries. However, the dramatic volume changes (up to 400%) that occur during lithiation/delithiation and the relative low electrical conductivity of silicon prevent the implementation of this material. In this work, a nano-silicon/polyaniline/reduced graphene oxide composite was synthesized via a two-step process: in-situ polymerization of polyaniline (PANi) in the presence of nano-silicon followed by combination of the prepared n-Si/PANi binary composite with reduced graphene oxide (RGO), to form a n-Si/PANi/RGO composite. Electron microscopy reveals the unique nano-architecture of the n-Si/PANi/RGO composite: silicon nanoparticles are well dispersed within a PANi matrix, which in turn is anchored to the surface of RGO sheets. The n-Si/PANi/RGO ternary composite delivered an initial capacity of 3259 mAh/g and 83.5% Coulombic efficiency. The new composite displayed better rate performance and capacity recovery than either nano-Si or n-Si/PANi. Structural and morphological studies combined with AC impedance analysis suggest that the n-Si/PANi/RGO composite has higher electrical conductivity than the other two component materials, yielding better performance at high current densities or C rates. The good rate performance, high initial specific capacity and stable Coulombic efficiency of n-Si/PANi/RGO make it a promising anode material for high energy density lithium-ion batteries.

Because of its high theoretical specific capacity (4200mAh/g) and natural abundance (2nd most abundant element on earth), silicon is considered a promising anode candidate for high energy density lithium-ion batteries. However, the dramatic volume changes (up to 400%) that occur during lithiation/delithiation and the relative low electrical conductivity of silicon prevent the implementation of this material. In this work, a nano-silicon/polyaniline/reduced graphene oxide composite was synthesized via a two-step process: in-situ polymerization of polyaniline (PANi) in the presence of nano-silicon followed by combination of the prepared n-Si/PANi binary composite with reduced graphene oxide (RGO), to form a n-Si/PANi/RGO composite. Electron microscopy reveals the unique nano-architecture of the n-Si/PANi/RGO composite: silicon nanoparticles are well dispersed within a PANi matrix, which in turn is anchored to the surface of RGO sheets. The n-Si/PANi/RGO ternary composite delivered an initial capacity of 3259 mAh/g and 83.5% Coulombic efficiency. The new composite displayed better rate performance and capacity recovery than either nano-Si or n-Si/PANi. Structural and morphological studies combined with AC impedance analysis suggest that the n-Si/PANi/RGO composite has higher electrical conductivity than the other two component materials, yielding better performance at high current densities or C rates. The good rate performance, high initial specific capacity and stable Coulombic efficiency of n-Si/PANi/RGO make it a promising anode material for high energy density lithium-ion batteries.