The electrification of passenger vehicles has been a step towards the reduction of greenhouse gas emissions by automobiles; however, in the United States many plug-in hybrid electric vehicles (PHEVs) and battery electric vehicles (BEVs) must still be plugged in to a grid that is heavily reliant on the burning of fossil fuels to charge. The goal of this thesis is to investigate how to develop a system capable of fully charging a PHEV using only alternative and/or regenerative energy sources. In developing such a system, various alternative and regenerative energy sources were investigated with the intent of reaching a specified daily energy goal; sufficient to charge a PHEV. These energy sources were evaluated based upon criteria such as novelty, ability to reach desired daily energy goal, applicability to BEV/PHEV, etc. The primary technological categories considered include but are not limited to regenerative and solar technologies. The evaluation of technologies indicated that a major opportunity lies in solar technologies, and in particular concentrated photovoltaics. Design alternatives for a concentrated photovoltaic system capable of reaching the desired energy goal are described. The design alternatives utilize Fresnel lenses as a means of concentrating a large area of sunlight onto an array of photovoltaics affixed to a vehicle. Various tracking mechanisms for the concentrating systems have been outlined to meet given design criteria. 3-D ray tracing algorithms have been developed to determine the path of the tracking mechanisms depending upon the time of year and on the geographic location. The same algorithms have been used in conjunction with typical meteorological year data to determine the expected output of the concentrating systems based upon the solar resource and solar angles at a specific place and time. The findings suggest that a concentrated photovoltaic system designed specifically for charging an electrified vehicle may generate sufficient energy over the course of a day to power a typical driver’s trips. However, for such a concentrating system to be commercially feasible there are still many design challenges to be overcome. Design limitations and implications for further research are discussed.

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A DC power distribution system (PDS) of a transport aircraft was modeled and analyzed using MATLAB/Simulink software. The multi-level modeling concept was used as a modeling approach, which assumes modeling subsystem of the PDS at three different levels of complexity. The subsystem models were implemented in Simulink and combined into the whole PDS model according to certain interconnection rules. Effective modeling of different scenarios of operation was achieved by mixing subsystem models of different levels in one PDS model. Linearized models were obtained from the nonlinear PDS model for stability analysis and control design. The PDS model was used to examine the system stability and the DC bus power quality under bidirectional power flow conditions. Small-signal analysis techniques were employed to study stability issues resulting from subsystem interactions. The DC bus stability diagram was proposed for predicting stability of the PDS with different types of loads without performing an actual stability test based on regular stability analysis tools. Certain PDS configurations and operational scenarios leading to instability were identified. An analysis of energy transfer in the PDS showed that a large energy storage capacitor in the input filter of a flight control actuator is effective for reduction of the DC bus voltage disturbances produced by regenerative action of the actuator. However, energy storage capacitors do not provide energy savings in the PDS and do not increase its overall efficiency. / Master of Science

The aim of this thesis is to develop a deeper understanding and the technology in the nascent field of solid-state organic-inorganic perovskite solar cells. In recent years, perovskite materials have emerged as a low-cost, thin-film technology with efficiencies exceeding 16% challenging the quasi-paradigm that high efficiency photovoltaics must come at high costs. This thesis investigates perovskite solar cells in more detail with a focus on incorporating plasmonic nanostructures and perovskite film formation. Chapter 1 motivates the present work further followed by Chapter 2 which offers a brief background for solar cell fabrication and characterisation, perovskites in general, perovskite solar cells in specific, and plasmonics. Chapter 3 presents the field of plasmonics including simulation methods for various core-shell nanostructures such as gold-silica and silver-titania nanoparticles. The following Chapters 4 and 5 analyze plasmonic core-shell metal-dielectric nanoparticles embedded in perovskite solar cells. It is shown that using gold@silica or silver@titania NPs results in enhanced photocurrent and thus increased efficiency. After photoluminescence studies, this effect was attributed to an unexpected phenomenon in solar cells in which a lowered exciton binding energy generates a higher fraction of free charge. Embedding thermally unstable silver NPs required a low-temperature fabrication method which would not melt the Ag NPs. This work offers a new general direction for temperature sensitive elements. In Chapters 6 and 7, perovskite film formation is studied. Chapter 6 shows the existence of a previously unknown crystalline precursor state and an improved surface coverage by introducing a ramped annealing procedure. Based on this, Chapter 7 investigates different perovskite annealing protocols. The main finding was that an additional 130°C flash annealing step changed the film crystallinity dramatically and yielded a higher orientation of the perovskite crystals. The according solar cells showed an increased photocurrent attributed to a decrease in charge carrier recombination at the grain boundaries. Chapter 8 presents on-going work showing noteworthy first results for silica scaffolds, and layered, 2D perovskite structures for application in solar cells.