The FDOT has been using supplementary cementitious materials while constructing steel reinforced concrete marine bridge structures for over 3 decades. Previous findings indicated that such additions in concrete mix makes the concrete more durable. To better understand corrosion propagation of rebar in high performance concrete: mature concrete samples that were made (2008/2009) with Portland cement, a binary mix, a ternary mix and recently prepared (April 2016 with 50% OPC + 50% slag and 80% OPC + 20% Fly ash) concrete samples were considered. None of these concretes had any admixed chloride to start with. An accelerated chloride transport process was used to drive chloride ions into the concrete so that chlorides reach and exceed thechloride threshold at the rebar surface and initiate corrosion. Electrochemical measurements were taken at regular intervals (during and after the electro-migration process) to observe the corrosion propagation in each sample. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2017. / FAU Electronic Theses and Dissertations Collection

Two duplex stainless steels rebars: UNS32304SS and UNS32101SS, were selected to investigate the corrosion initiation and propagation in reinforced concrete specimens. The investigation is divided in two phases with two different methods to accelerate the transport of chlorides through the concrete and initiate corrosion in a short period of time. After corrosion had initiated and propagated for some time; selected specimens were terminated for visual examination. On specimens selected for autopsy, the rebars in the top row showed corrosion to various degrees. Corrosion had propagated to such extent on the terminated specimens that the specimen showed cracks. Stray current might have caused accelerated corrosion on rebars where corrosion had initiated. Based on chloride concentrations measured at the rebar trace, corrosion initiated: on S32101 rebars on average at 7.9 kg/m3, and S32101 rebars on average at 6.0 kg/m3. The findings suggest that S32304 rebars corroded at a slower than S32101. / by Francisco Gutierrez Tellez. / Thesis (M.S.C.S.)--Florida Atlantic University, 2013. / Includes bibliography. / Mode of access: World Wide Web. / System requirements: Adobe Reader.

The corrosion propagation stage of D-CRP (types F and C) was tested under immersion in water, high humidity, and covered with wet sand. The half-cell potential, linear polarization test, and electrochemical impedance spectroscopy measurements were performed. Selected specimens were terminated after 300 days of exposure and visually inspected. Based on corrosion potential measurements obtained during the corrosion propagation observation, and calculated corrosion rate based on LPR measurements: all specimens were actively corroding. Additionally, EIS-Rc values were calculated for FS, CS and CH specimens. The Rc_EIS were generally greater than Rc_LPR values. EIS spectra for CI and FI specimens usually included mass transport limitations, as these specimens were immersed. Both type of specimens immersed in water (FI and CI), appeared to have higher corrosion rate based on LPR-Rc. However, upon autopsy it was revealed that a more modest amount of corrosion occurred on the reinforcing steel of FI and CI terminated specimens. / Includes bibliography. / Thesis (M.S.)--Florida Atlantic University, 2014. / FAU Electronic Theses and Dissertations Collection

The aim of this study was to assess the strength, durability properties and corrosion resistance of concrete samples using supplementary cementitious blended materials. In this investigation, three supplementary concrete materials (SCMs) were used together with ordinary Portland Cement (OPC) to form cementitious blends at different proportions. The supplementary materials are silica fume (SF), ground granulated blast furnace slag (GGBS) and fly ash (FA). Sixteen (16) different proportions of the cementitious blends were produced. Tests carried out on concrete samples include slump test, compressive strength, oxygen permeability, sorptivity, porosity, chloride conductivity test, resistance to chloride and sulphate attack. The electrode potentials of tested samples were also observed using electrochemical measurements. Concrete specimens prepared with 10%, 20%, 30%, 40%, up to 60% of blended cements replacement levels were evaluated for their compressive strength at, 7, 14, 28, 90 and 120 days while the specimens were evaluated for durability tests at 28, and 90 days respectively. The results were compared with ordinary Portland cement concrete without blended cement. Voltage, and temperature measurements were also carried out to understand the quality of concrete. The corrosion performance of steel in reinforced concrete was studied and evaluated by electrochemical half-cell potential technique in both sodium chloride, and magnesium sulphate solutions respectively. The reinforced concrete specimens with centrally embedded 12mm steel bar were exposed to chloride and sulphate solutions with the 0.5 M NaCl and MgSO4 concentrations respectively. An impressed voltage technique was carried out to evaluate the corrosion resistance of the combination of quaternary cementitious blended cement, so as to get the combination with optimum performance. Improvement of strength, durability, and corrosion resistance properties of blended concrete samples are observed at different optimum percentages for binary, ternary and quaternary samples. The effect of cementitious blends is recognized in limiting the corrosion potential of the tested SCM concrete samples. Generally, the cementitious blends with limited quantity of SF to 10% have the potential to produce satisfactory concrete. These should however be used for low cost construction, where high quality concrete is not required. / Civil and Chemical Engineering / M. Tech. (Chemical Engineering)