The research objectives are to develop experimental and computational techniques to characterize and to study the influence of polymer coating on the mechanical response of walnut shell particles to be used as proppants. E3-ESEM and Zeiss Axiophot LM are used to study the cellular microstructure and feasibility of polymer infiltration and uniform coating. Three main testing procedures; single particle compression, heating tests on coated and uncoated walnut shell particles and 3-point flexure tests are undertaken. In in-situ ESEM observations on both the coated and uncoated particles showed signs of charring at about 175 – 200 ºC. Single particle compression test are conducted with random geometry particles and subsequently with four distinct shape categories to minimize the statistical scatter; flat top, round top, cone top, and high aspect ratio. Single particle tests on uniformly cut cuboid particles from walnut shell flakes are used to capture the nonlinear material response. Furthermore cyclic compression loads are imposed on flat top particles which reveal that significant permanent deformation set in even at low load levels. Computational models include Hertzian representation, 2D and 3D finite element models to simulate single coated and uncoated particles under compression. The elastic material with geometric nonlinear representation is not able to simulate the compression response observed during testing. The inelastic material representation is able to significantly improve the compression response and address the influence of geometric shape on particle response. A single uniform layer of polymer coat is introduced on the 3D models with nonlinear material definition. Coating provides a marginal improvement in load vs displacement response of the particles while increasing the ability of the particle to withstand higher loads.

The research objectives are to develop experimental and computational techniques to characterize and to study the influence of polymer coating on the mechanical response of walnut shell particles to be used as proppants. E3-ESEM and Zeiss Axiophot LM are used to study the cellular microstructure and feasibility of polymer infiltration and uniform coating. Three main testing procedures; single particle compression, heating tests on coated and uncoated walnut shell particles and 3-point flexure tests are undertaken. In in-situ ESEM observations on both the coated and uncoated particles showed signs of charring at about 175 – 200 ºC. Single particle compression test are conducted with random geometry particles and subsequently with four distinct shape categories to minimize the statistical scatter; flat top, round top, cone top, and high aspect ratio. Single particle tests on uniformly cut cuboid particles from walnut shell flakes are used to capture the nonlinear material response. Furthermore cyclic compression loads are imposed on flat top particles which reveal that significant permanent deformation set in even at low load levels. Computational models include Hertzian representation, 2D and 3D finite element models to simulate single coated and uncoated particles under compression. The elastic material with geometric nonlinear representation is not able to simulate the compression response observed during testing. The inelastic material representation is able to significantly improve the compression response and address the influence of geometric shape on particle response. A single uniform layer of polymer coat is introduced on the 3D models with nonlinear material definition. Coating provides a marginal improvement in load vs displacement response of the particles while increasing the ability of the particle to withstand higher loads.

Polymer-coated controlled-release fertilizers (PCFs) are the most widely used class of fertilizers in the production of container-grown nursery plants. Nutrient release from PCFs is primarily influenced by temperature. The objective of this study was to determine the influences of temperature and time on the nutrient release patterns of three PCFs (each with a rated longevity of 8-9 months), each using a different coating technology: Osmocote Plus™ 15N-3.93P-9.96K, Polyon™ 18N-2.62P-9.96K, and Nutricote™ 18N-2.62P-6.64K. The first three experiments investigated the effects of time on long-term nutrient release. In Expt. 1, each of the three PCFs were placed in flasks of distilled water maintained at 40°C for 22 weeks. Fertilizer solutions were poured off at bi-weekly intervals and measured for electrical conductivity (EC) and NO3-N, NH4-N, P, K, Fe, Mn, Cu, and Zn concentrations. Overall, nutrient release for the three PCFs was higher and more variable in the first eight weeks than later in the experiment. Polyon's™ macronutrient release was generally more gradual than that of the other products. Micronutrient release patterns varied substantially between fertilizers and nutrients. In Expt. 2, pine bark (PB)-filled containers were amended with the three PCFs and irrigated regularly in a greenhouse. PCFs were removed from containers when Osmocote Plus'™ NO₃-N supply was ~66% expended and analyzed for EC, NO₃-N, NH₄-N, and P concentration. Except for P, the percentage of each nutrient remaining was roughly comparable to those remaining at the corresponding stage of Expt. 1, suggesting that PCF nutrient release behavior in the laboratory method is comparable with nutrient release behavior in PB in the greenhouse. At the end of Expts. 1 and 2, Osmocote Plus™ had expended a higher percentage of its nutrients than the other fertilizers. In Expt. 3, substrate solutions were collected weekly from PB-filled containers (same treatments as in Expt. 2) and EC was determined. The substrate solution EC of Osmocote Plus™-fertilized PB began to decline sooner than that of the other fertilizers. Overall, these three experiments led to the conclusion that Osmocote Plus™ nutrient release declines more quickly than does Polyon™ or Nutricote™, while Polyon™ has the most gradual nutrient release pattern. The objective of the second set of experiments was to determine the effects of temperature on short-term nutrient release. In Expt. 4, 14 g of each PCF was maintained at 40°C until ~33% of the NO3-N content in Osmocote Plus™ was expended. Each fertilizer was then placed in a sand column and leached with distilled water at ~100 mL/h. Columns were then incrementally subjected to a simulated diurnal container temperature change from 20°C to 40°C and back to 20°C over a period of 20 h. Leachate was collected hourly and measured for soluble salts and NO₃-N and NH₄-N concentrations. For all fertilizers, nutrient release increased and decreased with the respective increase and decrease in temperature. Nutrient release patterns of the three fertilizers were significantly different, with Osmocote Plus™ showing the greatest overall change in nutrient release between 20°C and 40°C and Nutricote™ the least. In Expt. 5, PCFs were placed in flasks of distilled water in constant temperature baths. Initially, fertilizers were held at 40°C for three days and then at temperatures of 22, 28, 34, or 40°C for two weeks. Fertilizer solutions were poured off after the first and second weeks. Only solutions from the second week were analyzed for soluble salts and NO₃-N, NH₄-N, P, and K concentrations. For Osmocote Plus™ and Polyon™, there was a 29% to 86% (depending on the nutrient measured) mean increase in nutrient release between 22°C and 40°C, whereas for Nutricote™ there was a 345% to 364% (depending on the nutrient measured) mean increase. The overall mean increases in nutrient release in Expt. 4 were between 1032% and 4023%, whereas the mean increases in Expt. 5 were between 29% and 364%. In summary, the second set of experiments found that PCF nutrient release was highly sensitive to diurnal temperature changes. / Master of Science