CIVINS / Systems on modern naval vessels are becoming exclusively dependent on electrical power. One example of this is the replacement of distilling and evaporator plants with reverse osmosis units. As the system is in continuous operation, it is critical to have remote real-time monitoring and diagnostic capabilities. The pressure to reduce shipboard manning only adds to the difficulties associated with monitoring such systems. One diagnostic platform that is particularly well suited for use in such an environment is the non-intrusive load monitor (NILM). The primary benefit of the NILM is that it can assess the operational status of multiple electrical loads from a single set of measurements collected at a central point in a ship's power-distribution network. This reduction in sensor count makes the NILM a low cost and highly reliable system. System modeling, laboratory experiments, and field studies have all shown that the NILM can effectively detect and diagnose several critical faults in shipboard fluid systems. For instance, data collected from the reverse osmosis units for two U.S. Coast Guard Medium Endurance Cutters indicate that the NILM can detect micron filter clogging, membrane failures, and several motor-related problems. Field-tested diagnostic indicators have been developed using a combination of physical modeling and laboratory experiments. / CIVINS

Reverse Osmosis membranes have been successfully proven to remove almost 99% of chemicals dissolved in seawater. However, removal of certain trace elements, such as boron is challenging and relatively low for seawater reverse osmosis desalination plants compared to thermal desalination plants. Boron is naturally occurring and is present in seawater at an average concentration of 4.5-5 mg/L. While boron is a vital element, its toxicity has been proven on crops, animals and possibly humans. Additionally, boron should be removed to comply with the current guideline value of 0.5 mg/L, for drinking water, issued by the World Health Organization (WHO), which is barely attained by a single-pass process seawater reverse osmosis plant. Currently, multipass reverse osmosis membrane operations with pH modifications are the only valid method for boron removal. However, this is not economically efficient as it requires higher energy and chemicals consumptions. The objective of this study was to investigate boron removal by commercial TFC RO membranes in addition to custom-made KAUST-synthesized TFC membrane. Five membrane samples were examined: Toray, Sepro, Koch, and KAUST in-house synthesized membrane. Three different feed pH conditions were used: pH6, pH8, and pH10. Filtration experiments were conducted in two parts. In experiment 1, all five membranes were examined for boron rejection in a dead-end permeation system, whereas in experiment 2 the two membranes with the highest boron rejection from experiment 1 were tested in a cross-flow system. Permeate and feed samples were taken continuously and analyzed for boron concentration, rejection calculation. Membrane surfaces were characterized according to hydrophilicity, roughness and surface charge. The results showed for all the tested membranes that boron rejection increased as the feed pH increased. KAUST, defect-free TFC, showed the highest performance for boron rejection for all pH conditions, although, it shows the roughest surface. Toray membranes 80LB and 80B exhibited the second highest boron rejection and had the most negatively charged membrane surfaces. It was observed in this study that the rejection of boron by a membrane is due to size exclusion and charge repulsion mechanisms. It was concluded that, the KAUST, defect free TFC has the potential to be applicable for boron rejection in industrial application as it has better boron rejection than commercially available RO membranes.

Thesis (M. S.)--Earth and Atmospheric Sciences, Georgia Institute of Technology, 2010. / Committee Chair: Ellery Ingall; Committee Member: Irina Sokolik; Committee Member: Josef Dufek. Part of the SMARTech Electronic Thesis and Dissertation Collection.

No description available.

In spite of abundant water resources, world is suffering from the scarcity of usable water. Seawater Reverse Osmosis (SWRO) desalination technology using polymeric membranes has been recognized as a key solution to water scarcity problem. However, economic sustainability of this advanced technology is adversely impacted by the membrane fouling problem. Fouling of RO membranes is a highly studied phenomenon. However, literature is found to be lacking a detailed study on kinetic and dynamic aspects of SWRO membrane fouling. The factors that impact the fouling dynamics, i.e., pretreatment and water quality were also not adequately studied at full–scale of operation. Our experimental protocol was designed to systematically explore these fouling aspects with the objective to improve the understanding of SWRO membrane fouling mechanisms. An approach with multiple analytical techniques was developed for fouling characterization. In addition to the fouling layer characterization, feed water quality was also analysed to assess its fouling potential. Study of SWRO membrane fouling dynamics and kinetics revealed variations in relative abundance of chemical and microbial constituents of the fouling layer, over operating time. Aromatic substances, most likely humic–like substances, were observed at relatively high abundance in the initial fouling layer, followed by progressive increase in relative abundances of proteins and polysaccharides. Microbial population grown on all membranes was dominated by specific groups/species belonging to different classes of Proteobacteria phylum; however, similar to abiotic foulant, their relative abundance also changed with the biofilm age and with the position of membrane element in RO vessel. Our results demonstrated that source water quality can significantly impact the RO membrane fouling scenarios. Moreover, the major role of chlorination in the SWRO membrane fouling was highlighted. It was found that intermittent mode of chlorination is better than continuous mode of chlorination of seawater, as anti–biofouling strategy. It was also confirmed that significant biofilm development was inevitable even with the use of chlorine to disinfect SWRO membranes. Our findings on the dynamic patterns of SWRO membrane fouling should help in further elaborating research projects focusing on the development of better strategies to minimize this troublesome phenomenon.

Central Arizona Project water was treated using slow sand filtration (SSF) and reverse osmosis (RO) in series. Additional desalination water was recovered from RO brine using the vibratory shear-enhanced processing (VSEP®; New Logic, Inc.). SSF removed 90% of the turbidity in raw CAP water. SSF decreased total organic carbon by almost 20%. After a little more than a year of continuous operation, performance of the RO system declined noticeably, as indicated by a rapid decrease in membrane permeation coefficient and an increase in salt flux. Foulant scrapings contained both clay material and large amounts of unidentified organics. Alternative hypotheses regarding major sources of membrane foulants are discussed in this study.Water lost as brine was reduced from 20% to 2-4% via post-RO VSEP treatment. Estimated costs were compared to those of a no-VSEP option in which disposal of the entire RO brine flow was required. The total annualized cost of brine treatment was fairly insensitive to recovery during VSEP treatment in the range 80-90%, and the period of VSEP operation between cleanings in the range 25-40 hrs. These values define a fairly broad window for near optimal VSEP operation under the conditions of the study. The cost of VSEP treatment to minimize brine loss was estimated at $394- $430 per acre foot ($1.21 - $1.32 per 1000 gal) of 15 MGD CAP water treated. For a hypothetical 3 MGD RO brine flow, the use of VSEP to recover water and reduce the volume of brine for disposal results in a savings of more than $5M/year relative to the no-VSEP brine disposal alternative.

Membrane technologies are considered a promising solution for water scarcity in arid regions. However, fouling is a major challenge facing the application of membrane technologies. Fouling limits the economic viability and reduces the overall efficiency of membrane processes. Therefore, fouling mitigation is a crucial factor in spreading the use of membrane technologies for new applications. The first step in fouling mitigation is to predict the propensity of fouling. Unfortunately, there are immense limitations in current industrial practises for fouling propensity prediction. These limitations come from using outdated and inapplicable approaches, in which crucial assumptions are made. For example, in the case of crystallisation fouling or “scaling” one of the major simplifications is the use of pure scaling salt data to predict the propensity of scaling when, in reality, co-precipitation is present. This research work aims to introduce a new approach to systematic assessment of the fouling problem under real and complex conditions and to enhance understanding of the importance of including interactive effects and co-precipitation in the prediction of scaling propensity. In this research work a novel procedure accounting for the local variation of thermodynamic properties along a long membrane channel is proposed. A new approach considering ion interaction and process hydrodynamics for the prediction of the scaling propensity is then introduced. This new approach provides for the first time a completely theoretical assessment for pure salt scaling propensity along a full scale filtration channel without the use of any empirical constants. A new procedure for including the effect of co-precipitation on scaling propensity prediction is developed. The effect of process pressure on solubility products is included theoretically for the first time to enhance the accuracy of scaling propensity prediction during the full scale RO process. This research work helps to produce more reliable and accurate prediction of the onset of scaling which will help strategies to mitigate scaling and increase the overall efficiency of RO/NF processes. The new approach can be applied in practical situations and could be developed to a user-friendly programme able to give an accurate prediction of the fouling propensity in full scale processes allowing the optimisation of membrane processes accordingly. Moreover, comprehensive experimental work has been carried out during this PhD research work to enhance understanding of crystallisation fouling and coprecipitation. The effect of salinity and dissolved organics (DO) in CaSO4 and SrSO4 precipitation and co-precipitation are studied and discussed. Quantitative and qualitative thermodynamic and kinetic analyses combined with structural analyses of deposits are carried out to investigate the effect of salinity, DO presence and coprecipitation on SrSO4 and CaSO4 precipitation. The observations in this experimental study are very important for a deeper understanding of the effect of scaling salts’ coexistence, salinity and DO presence on the behaviour of the scaling salts. This is crucial to reaching a reliable prediction of the scaling propensity within RO/NF processes. Finally, the new developed approaches in this thesis have been validated using set of hydrodynamic tests. This set of tests has been carried out using a newly installed laboratory membrane rig. Moreover, a new technique to simulate full scale membrane processes is proposed using a laboratory membrane rig combined with the programs previously developed in this thesis. This new technique can be used to study the effect of process hydrodynamics on scaling and process performance of full scale membrane processes using a laboratory membrane rig. The outcomes of this research work can be used to investigate the optimal operating conditions and to guide design criteria for different RO/NF practical scenarios.

There are two basic needs globally and that is the control and supply of reliable electricity and clean water. However, one of the biggest challenges the world is facing today is the lack of fresh water resources. Lower rainfall, together with population and industry growth, are only a few factors contributing to the fast increasing strain on existing water supplies around the world. This fast increasing need therefore necessitates the investigation into finding alternative sources. One such option is that of desalination. In the last 50 years desalination technologies have been applied to produce high quality fresh water from brackish and seawater resources. In the 1980's a breakthrough was made with the introduction of the membrane desalination technology, known as the reverse osmosis (RO) process. Today newly developed technologies are improving the competitiveness of the reverse osmosis process against the traditional distillation processes. There are a number of options to increase the efficiency of a reverse osmosis plant and one option is to use warm industrial waste water as the feed water to the desalination plant. It is known that the viscosity of water is inversely proportional to its temperature. Therefore, if the feed water temperature of a reverse osmosis plant is increased the membranes will become more permeable. This will result in a higher production volume or in a lower energy demand. South Africa is on the edge of building the first fourth generation nuclear power plant, called the Pebble Bed Modular Reactor (PBMR) at Koeberg. The PBMR will produce a cooling water outlet temperature of 40°C which can be used as feed water to a reverse osmosis plant. In this study design guidelines of a reverse osmosis plant are given in nine steps. These steps were then used during a basic component design of a reverse osmosis plant coupled to the waste water stream of a PBMR nuclear power plant. Furthermore design software programs were used to simulate the coupling scheme in order to validate the outcome of the design guidelines. The results of the two design approaches compared well to one another. It furthermore showed that by using the waste water from the PBMR nuclear power plant the efficiency of the RO plant is increased and the operating cost is decreased. Fresh water can be produced at a cost of R 5.64/m3 with a specific electricity consumption of 2.53 kWh/m3. / Thesis (M.Ing. (Nuclear Engineering)--North-West University, Potchefstroom Campus, 2009.

There are two basic needs globally and that is the control and supply of reliable electricity and clean water. However, one of the biggest challenges the world is facing today is the lack of fresh water resources. Lower rainfall, together with population and industry growth, are only a few factors contributing to the fast increasing strain on existing water supplies around the world. This fast increasing need therefore necessitates the investigation into finding alternative sources. One such option is that of desalination. In the last 50 years desalination technologies have been applied to produce high quality fresh water from brackish and seawater resources. In the 1980's a breakthrough was made with the introduction of the membrane desalination technology, known as the reverse osmosis (RO) process. Today newly developed technologies are improving the competitiveness of the reverse osmosis process against the traditional distillation processes. There are a number of options to increase the efficiency of a reverse osmosis plant and one option is to use warm industrial waste water as the feed water to the desalination plant. It is known that the viscosity of water is inversely proportional to its temperature. Therefore, if the feed water temperature of a reverse osmosis plant is increased the membranes will become more permeable. This will result in a higher production volume or in a lower energy demand. South Africa is on the edge of building the first fourth generation nuclear power plant, called the Pebble Bed Modular Reactor (PBMR) at Koeberg. The PBMR will produce a cooling water outlet temperature of 40°C which can be used as feed water to a reverse osmosis plant. In this study design guidelines of a reverse osmosis plant are given in nine steps. These steps were then used during a basic component design of a reverse osmosis plant coupled to the waste water stream of a PBMR nuclear power plant. Furthermore design software programs were used to simulate the coupling scheme in order to validate the outcome of the design guidelines. The results of the two design approaches compared well to one another. It furthermore showed that by using the waste water from the PBMR nuclear power plant the efficiency of the RO plant is increased and the operating cost is decreased. Fresh water can be produced at a cost of R 5.64/m3 with a specific electricity consumption of 2.53 kWh/m3. / Thesis (M.Ing. (Nuclear Engineering)--North-West University, Potchefstroom Campus, 2009.

No description available.