The sedimentary rocks of the Karoo Supergroup in the Tuli Basin (South Africa) consist of various terrigenous clastic and chemical deposits (parabreccias, conglo-breccias, conglomerates, sandstones, fine-grained sediments, calcretes and silc~etes). Four stratigraphic units were identified: the Basal, Middle and· Upper Units, and the CI~rens Formation. The palaeo-environmental reconstructions of the four stratigraphic units are based on evidence provided by primary sedimentary structures, palaeo-flow measurements, clast size/shape analysis, petrographic studies, palaeontological findings, borehole data and stratigraphic relations. The facies associations of the Basal Unit are interpreted as colluvial fan and low sinuosity, braid~d river channel with coal-bearing overbank and thaw-lake deposits. The interpreted depositional environment implies a cold climate, non-glacial subarctic fluvio-Iacustrine system. The current indicators of the palaeo-river system suggest flow direction from ENE to WSW. The lithologies of the Basal Unit are very similar to the deposits of the fluvial interval in the Vryheid Formation (Ecca Group) of the main Karoo Basin. There is no indubitable evidence for glacial activity (e.g. striated pavements or clasts, varvites, etc.), therefore the presence of unequivocal Dwyka Group correlatives in the Tuli Basin remains uncertain. The sedimentary structures and palaeo-current analysis indicate that the beds of the Middle Unit were deposited by an ancient river system flowing in a north-northwesterly direction. A lack of good quality exposures did not allow the reconstruction of the fluvial style, but the available data indicate a high-energy, perhaps braided fluvial system. The lack of bio- and chronostr~~igraphic control hampers precise correlation and enables only the lithocorrelation of the Middle Unit with other braided river systems either in the Beaufort Group or in the Molteno Formation of the main Karoo Basin. The depositional environment of the Upper Unit is interpreted as a low-sinuosity, ephemeral stream system with calcretes and silcretes in the dinosaur-inhabited overbank area. During the deposition of the unit, the climate was semi-arid with sparse precipitation resulting -iFlhighmagnitude, low-frequency devastating flash floods. The sediments were built out from a distant northwesterly source to the southeast. The unambiguous correspondence between the Upper Unit and the Elliot Formation (main Karoo Basin) is provided by lithological similarities and prosauropod dinosaurs remains. The palaeo-geographic picture of the Clarens Fonnation indicates a westerly windsdominated erg environment with migrating transverse dune types. The ephemeral stream deposits, fossil wood and trace fossils are only present in the lower part of the Formation, indicating that the wet-desert conditions were progressively replaced by dry-desert conditions. Based on lithological and palaeontological evidence, the Formation correlates with the Clarens Formation in the main Karoo Basin. At this stage, it remains difficult to establish the exact cause of the regional palaeo-slope changes during the deposition of the Karoo Supergroup in the Tuli Basin. It is probable that foreland system tectonics, which affected the lower part of the Supergroup (Basal Unit and Middle Unit?), were replaced by incipient continental extension and rift related tectonic movements in the Middle and Upper Units, and Clarens Formation.

M.Sc. / The study looks into the sediment-bound metals (Fe, Mn, Cu, Cr, Cd, Co, Pb, Ni, Zn and Hg) of the Leeu/Taaibospruit catchment, which is impacted by agricultural, industrial and urban development. A number of chemical procedures, including total metal determination, the Tessier-sequential extraction scheme, the BCR Protocol, evaluation of the % TOC and determination of AVS to SEM ratios were applied to sediment samples collected from eight sites along the two rivers in the study area. Samples were collected during both high flow (summer) and low flow (winter) conditions. Following the chemical characterisation, bioaccumulation testing was conducted by exposing chironomid larvae to the sediment samples collected in from the study sites and determining their metal uptake relative to control specimens in uncontaminated sediments. These bioaccumulation results were then considered in conjunction with the chemical parameters in an attempt to identify any trends and correlations. Significant spatial and temporal differences were found in the metal concentrations from the study area. The total extraction results indicated that abundant amounts of Cr and Fe are present throughout the system. This was expected based on the make-up of the underlying geology. In addition, one of the sites, which is in close proximity to the town of Sasolburg, was identified as a potentially contaminated site. This site had significantly higher concentrations of Zn, Cu, Pb and, most notably, Hg when compared to the other sites. The elevated metal concentrations are most evident in samples collected under low flow conditions, but are also seen in the high flow Hg concentrations. Sequential extractions showed that Fe and Cr are concentrated in the residual phases of the sediment. Copper is largely present in the oxidisable fraction under low flow conditions, but also has considerable residual and reducible chemical forms. Manganese and Zn are distributed among all the different chemical phases and are therefore likely to be readily available for uptake by benthic organisms. The TOC was found to be highest during low flow conditions and at those sites with observable amounts of organic debris from the surrounding reeds and other vegetation. The AVS/SEM ratios were used to predict that due to the formation of insoluble metal sulphides, Cd, Cu, Hg, Ni, Pb and Zn are unlikely to be bioavailable at certain sites, i.e. the contaminated site 1 and at site 5, which only has agricultural impacts. In general, the bioaccumulation of Fe, Co, Ni, Cr and Mn was higher in the test larvae than the control larvae. Bioaccumulation of Cu, Pb, Zn and Hg levels were only higher than the control worms at sites where contamination was suspected to have taken place. Average bioaccumulation factors indicated that Hg is the metal that is most readily available for bioaccumulation, followed by Cu, Zn and Mn. All of these metals were bioconcentrated in the tissues of the test chironomids, while levels of Fe, Ni, Cr and Pb were found to be lower in the organisms than in the sediments. Although many of the chemical fractions were found to correlate significantly with the uptake of the different metals, the best overall correlation existed between the bioaccumulated metal and the total non-residual fraction. In fact, the sum of the first four steps of the Tessier-scheme correlated significantly with the bioaccumulated metal for all elements considered in the calculation, except for Pb. Additionally, the predictions made by the AVS model were found to be useful in justifying the behaviour and accumulation patterns of Hg, Zn and Cu at certain sites. The correlations and bioavailability clearly differed spatially, temporally and among the different elements. It is therefore suggested that prediction of the bioavailability and subsequent uptake of sediment-bound metals will require as many chemical and environmental factors as possible, and should include bioaccumulation and toxicity testing in order to examine the validity and completeness of these predictions.

Thesis (MSc. (Chemistry)) -- University of Limpopo, 2021 / Surface water from the rivers serves as a source of water for many purposes including drinking, irrigation and animal farming. The quality of surface water deteriorates due to human, animals and industrial waste. Amongst these wastes, selenium and other trace elements contaminants are included. Selenium can either be essential or toxic depending on the concentration and oxidation state. The aim of this current study was to determine the concentrations of inorganic selenium [Se(IV) and Se(VI)] in water and sediment samples collected from Blood and Mokolo Rivers in Limpopo Province, South Africa. Water and sediment samples were collected from 10 different sampling sites from down to upstream of each river. Water samples were acidified with 1% ultra-pure HNO3 and analysed directly for total selenium concentration. The accuracy of the method was validated using SRM1643f (trace elements in water reference material). Sediment samples were digested using microwave assisted acid digestion for the determination of total concentration of selenium. The accuracy of the method was evaluated using SRM 8704 (sediment standard reference material). Total concentration of selenium in both water and sediment samples were quantified using ICP-MS. The total concentration of selenium in water samples from Blood and Mokolo River were found to be in the range of 0.0682 to 2.72 μg/L and 0.0851 to 25.4 μg/L respectively. The selenium concentrations in all sediment samples were found to be below instrument detection limit of 0.0571 ng/g in both rivers. An adopted SPE method using Dowex 1 x 2 resin (chloride form) as an adsorbent material to preconcentrate and separate Se(IV) and Se(VI) was used for the speciation in water samples. Both Se(IV) and Se(VI) were retained on the column. The retained Se(IV) and Se(VI) were eluted using 15 mL 1 M HNO3 and 3 M HNO3 respectively at a flow rate of 2 ml/min and diluted to the final volume of 20 mL. The instrument detection limit was 0.192 μg/L and 0.108 μg/L for Se(IV) and Se(VI) respectively. The validation of the method was performed by using SRM 1643f and solutions of known concentrations. The water samples were adjusted to an optimum pH of 6 throughout the speciation analysis. The Se(IV) had higher percentage recoveries of 95 – 114% than Se(VI) with 53%. vi Concentrations of Se(IV) and Se(VI) in Blood River ranged from 0.0411 to 0.820 μg/L and 0.0811 to 1.75 μg/L respectively. Concentrations of Se(IV) and Se(VI) in Mokolo River ranged from 0.135 to 2.79 μg/L and 0.0961 to 14.8 μg/L respectively. The inorganic selenium species in water samples were also determined by using the adopted online mode of HPLC-ICP-MS with Hamilton PRP-X100 column. The separation of the two species was achieved by using isocratic elution of 100 mM NH4NO3 at pH 8.5 in 8 min. The method was successfully validated using SRM 1643f. The LOD of 0.842 μg/L and LOQ of 2.81 μg/L for Se(IV) were achieved. The LOD of 0.690 μg/L and LOQ of 2.30 μg/L for Se(VI) were achieved. The Se(IV) and Se(VI) concentrations determined using HPLC-ICP-MS were found to be in good agreement with Se(IV) and Se(VI) concentrations obtained using SPE in both rivers. The presence of Se(IV) and Se(VI) in water samples in Blood and Mokolo Rivers indicates that industrial and agricultural activities taking place near the rivers have an effect on the quality of the water. The selenium in water may be due to wastes from industrial, municipal and agricultural runoffs. The absence of selenium in sediment samples suggests that the area where the rivers are located is not rich in selenium.

Submitted in fulfilment of the requirements of the degree of Master of Engineering , Durban University of Technology, Durban, South Africa, 2016. / Reservoirs are designed to specific volume called the dead storage to be able to withstand the quantity of particles in the rivers flowing into it during its design period called its economic life. Therefore, accurate calculation of the quantities of sediment being transported is of great significance in environment engineering, hydroelectric equipment longevity, river aesthetics, pollution and channel navigability. In this study different input combination of monthly upstream suspended sediment concentration and upstream flow dataset for Inanda Dam for 15 years was used to develop a model for each month of the year. The predictive abilities of each of the developed model to predict the quantity of suspended sediment flowing into Inanda Dam were also compared with those of the corresponding developed Sediment Rating Curves using two evaluation criteria - Determination of Coefficient (R2) and Root-Mean-Square Error (RMSE). The results from this study show that a genetic programming approach can be used to accurately predict the relationship between the streamflow and the suspended sediment load flowing into Inanda Dam. The twelve developed monthly genetic programming (GP) models produced a significantly low difference when the observed suspended sediment load was compared with the predicted suspended sediment load. The average R2 values and RMS error for the twelve developed models were 0.9996 and 0.3566 respectively during the validation phase. The Genetic Programming models were also able to replicate extreme hydrological events like predicting low and high suspended sediment load flowing into the dam. Moreover, the study also produced accurate sediment rating curve models with low RMSE values of between 0.3971 and 11.8852 and high R2 values of between 0.9833 and 0.9962. This shows that sediment rating curves can be used to predict historical missing data of the quantity of suspended sediment flowing into Inanda Dam using existing streamflow datasets. The results from this study further show that the predictions from the Genetic Programming models are better than the predictions from the Sediment Raring Curve models, especially in predicting large quantities of suspended sediment load during high streamflow such as during flood events. This proves that Genetic Programming technique is a better predictive tool than Sediment Raring Curve technique. In conclusion, the results from this study are very promising and support the use of Genetic Programming in predicting the nonlinear and complex relationship between suspended sediment load and streamflow at the inlet of Inanda Dam in KwaZulu-Natal. This will help planners and managers of the dam to understand the system better in terms of its problems and to find alternative ways to address them.

M.Sc. (Geology) / The Mzimvubu River, situated in the Eastern Cape Province of South Africa, drains essentially strata of the Late Carboniferous to Jurassic Karoo Supergroup with minor intersection of the underlying Devonian Msikaba Formation near the mouth of the river at Port St. Johns. Rock- and river sediment samples were collected at specific points from within the Mzimvubu River drainage basin, based on changes in the geology through which the rivers flow. Detrital zircon age population data was obtained by LA-ICP-MS for each sample in order to meet the two-fold objective of the study; firstly to investigate the reliability of using detrital zircon grains as indicators of sedimentary provenance and secondly to determine possible source areas for the Karoo strata and underlying Msikaba Formation. Through the comparison of detrital zircon age population data for the rock units of the Karoo Supergroup and Msikaba Formation to that of the river sediment, it is concluded that detrital zircon grains hold value in deciphering the geological history of a sedimentary basin. This interpretation is based on similar distributions and trends that are present in both the zircon age populations of the rock- and sediment samples. However, complexities associated with detrital zircon analysis pertaining to rock type and depositional settings are noted and therefore certain procedures that can be implemented during field sampling have been suggested in this study so as to ensure accurate results are obtained. This will further ensure that reliable interpretations of the geological history of a sedimentary basin are achieved. Additionally, by utilising the detrital zircon population data obtained in the first part of the study in conjunction with published scientific data, the provenance of the Karoo Supergroup in the southeastern part of the Main Karoo Basin has been determined. From this data it was determined that, especially the upper part of the Karoo Supergroup in the Eastern Cape Province of South Africa, was deposited much later than previously thought and that many of the stratigraphic layers in the Karoo Basin were deposited coevally in different parts of the basin with lithostratigraphic boundaries being time-transgressive. Ultimately the data allowed for the construction of a tectono-sedimentary model to explain the deposition of the upper Cape- and Karoo Supergroups that started with the deposition of the Msikaba Formation in a passive continental margin setting, to deposition of the lower part of the Karoo Supergroup in an Andean type of foreland basin, with rifting starting during the times of deposition of the Molteno Formation. The deposition of the Molteno-, Elliot- and Clarens Formations took place as Gondwanaland was breaking apart coeval with the formation of the Karoo Igneous Province.

Fluvial systems are dynamic systems in which variables in a catchment and river channel affect the morphology of river reaches. South African rivers are increasingly being exposed to stresses from a combination of factors, one of the most prevalent being the impacts of damming rivers which result in varying downstream sediment fluxes and flow regimes. The sediment load combined with flow characteristics for respective river channels provides the physical habitat for aquatic ecosystems. The damming of the Tsitsa River, through the construction of the Ntabelanga Dam, will change the overall downstream geomorphology. This creates an opportunity for research in the preconstruction window. The current condition of the Tsitsa River was monitored by completing a baseline survey of the channel geomorphology with specific reference to the influence of sediment on river habitats and ecosystem health. Five sites were established in variable reaches of the Tsitsa River, with Site 1 located above the proposed Ntabelanga Dam inundation and Sites 2-5 below the proposed dam wall. Each site included a range of features that can be monitored for their response to the dam. Physical variables, water quality and biota were monitored seasonally to note changes in habitat quality. A baseline survey of the present geomorphology and associated instream habitats of the selected reaches was set up by conducting cross-sectional surveys of channel topography, water slope surveys, discharge measurements and visual and quantitative assessments of substrate. Level loggers were installed at each site to collect continuous data on variations in depth and temperature. Monitoring surveys, in terms of fine sediment accumulation, were conducted to characterise dynamic habitat arrangements and macroinvertebrate community composition. A taxa related physical habitat score for the Tsitsa River was created. The relationship between water quality, physical and ecological characteristics of the Tsitsa River will aid further research in the area as well as create a better understanding of the influence of sediment on river habitats and ecosystem health. Monitoring sites can be used to monitor the impact of catchment-wide rehabilitation on river health prior to the dam being built. After dam construction, the top site above the dam inundation can still be used as a point to monitor the impact of catchment rehabilitation on ecosystem health in terms of fine sediment accumulation.

Thesis (PhD)--Stellenbosch University, 2012. / ENGLISH ABSTRACT: The discovery of lucrative diamond deposits along the west coast of Southern Africa about 1200 kilometres from the Kimberley region during the period 1908 to 1927, gave rise to a number of different theories with respect to their possible provenance. These included the transportation of diamonds from unknown sources in southern Namibia by south-flowing rivers, hidden on- and off-shore kimberlites along the coast, and transportation by west-bound rivers from the hinterland. Subsequent research has shown that the latter is the only plausible theory. The discovery of marine and coastal diamond deposits as far south as the Olifants River estuary showed that the Vaal-Orange drainage in its current form could not have been the only conduit for diamonds to the coast, and the drainage evolution of southern Africa was interpreted as comprising essentially the following two main palaeo-fluvial systems active in the formation of the world's only known diamond mega-placer deposit:  The Karoo River with its headwaters similar to those of the modern Orange and Vaal Rivers and entering the Atlantic Ocean via the present-day Olifants River;  The Kalahari River that drained southern Botswana and followed the route of the modern-day Molopo River, entering the Atlantic Ocean in the vicinity of the present Orange River mouth. An important shortcoming of the above model is that it could not account for the fact that diamond distribution along the west coast shows a marked increase in grade and average stone size at the estuaries of all the major rivers draining from the escarpment to the Atlantic between the Olifants and the Orange Rivers. The presence of fluvial diamond deposits along the courses of the Buffels, Swartlintjies, Spoeg, Horees and Groen Rivers confirms that the increased grade and diamond size at their estuaries is not a function of large bays and rougher bottom topography associated with the rivers, although these could have contributed to this phenomenon. This proves that the catchments of the rivers between the Olifants and Orange Rivers also had access to diamondiferous debris, although they were not in contact with these two major drainages. A number of researchers proposed that diamonds liberated from pre-Karoo kimberlites were moved from their primary hosts to the south-western parts of the subcontinent by Dwyka glacials. From the above it is clear that nearly a century after the discovery of diamonds along the west coast of southern Africa consensus regarding their origin had not been reached. The aim of this study was therefore to establish a model explaining the most likely sources and distribution history of the more important alluvial diamond deposits in southern Africa. The methodology comprised a study of 1878 diamonds collected from 25 alluvial and two kimberlitic sources for comparison with known similar data from 12 kimberlitic populations in southern Africa. The diamond study was supplemented by a study of sedimentary clasts from bulk gravel samples taken along the Middle and Lower Orange River as well as Scanning Electron-microscope (SEM) Analyses of garnet grains and zircon geochronology. The evidence from the study does not support the postulated existence of a former Karoo River. The surface features of diamonds, notably brown spots indicating – in the context of southern Africa - liberation from pre-Karoo kimberlites, as well as the results of Fourier Transform Infrared analyses revealed that the populations at Kwaggaskop along the Sout River, previously considered an erosion remnant of the Lower Karoo River and those occurring south of Brandvlei and Van Wyksvlei in the valley of the Sak River, previously considered to have been reworked from the Middle Karoo River, differ profoundly from each other. In addition, the surface feature studies and Fourier Transform Infrared Analyses clearly show major distinctions between the diamond populations from the Sout River-Olifants River estuary and those from the Kimberley kimberlite province which was said to have supplied diamonds in large quantities to the Olifants River estuary via the postulated Karoo River. Furthermore the idea of a palaeo-Gamoep River playing a significant role in the transportation of diamonds to the west coast is favoured by the presence of brown-spotted diamonds and diamonds with Platelet Preservation Indices revealing severe platelet destruction that could be traced through Bosluispan in the Koa River valley, the Buffels River valley, the Buffels River estuary and to the shallow marine environment north of the Buffels River. Zircon geochronology confirmed the role of the Orange River in the denudation of the sub-continent. With respect to the drainage evolution and diamond distribution in southern Africa the results of this study indicate a complex diamond dispersal model that differs in some respects from prevailing theories. It shows that diamonds liberated from pre- Karoo kimberlites in the north-eastern part of the sub-continent were initially moved in a south-westerly direction by pre-Karoo drainages, then by Dwyka glaciers and ice sheets. Ultimately, after liberation from exhumed glacial and fluvial deposits and together with diamonds subsequently liberated from Jurassic and Cretaceous kimberlites, Cretaceous and younger drainages provided the transport toward the Atlantic Ocean where the diamonds were concentrated along shorelines and in bedrock trap sites. Significant quantities did not reach the coast, but were locked up in fluvial sediments in erosion remnants like terraces, karstic depressions and other segments of palaeo-channels along the way. The presence of diamonds with FTIR characteristics reminiscent of those from Orapa and Jwaneng in the Orange River deposits as well as in a raised marine terrace in southern Namaqualand and in marine deposits north of Concession 12A, also negates the possible existence of a palaeo-Kalahari River, unless it was a very young system that did not interrupt the south-bound dispersal of Botswana diamonds during the Late Oligocene-Early Miocene. The study also included microscopic examination of a parcel of diamonds from the enigmatic Skeleton Coast deposits, north-western Namibia. These results confirmed the conclusion based on geological and geomorphic grounds that these diamonds cannot be linked to the Oranjemund deposits, while their surface features showed that pre-Karoo sources comprise the most likely provenance for the Skeleton Coast diamonds. Thus the combination of FTIR analyses and surface feature studies of diamonds, zircon geochronology and SEM analyses of garnets allowed the formulation of a revised model for the distribution of alluvial diamonds and the drainage history of the sub-continent since the Middle Cretaceous, while the study of sedimentary clasts confirmed the repeated occurrence of high energy fluvial conditions – especially evident in the palaeo-Orange River sediments – that contributed to the high percentage of gem stones in the surviving alluvial diamond populations due to the destruction of poor quality diamonds. / AFRIKAANSE OPSOMMING: Die ontdekking van ryk alluviale diamantafsettings aan die suider-Afrikaanse weskus, meer as 1200 kilometer van die Kimberley-omgewing af tussen 1908 en 1927, het 'n aantal teorieë omtrent moontlike provenansgebiede vir hierdie afsettings tot gevolg gehad. Dit het gewissel van die suidwaartse vervoer van diamante vanaf bronne in suidelike Namibië, diamantdraende kimberliete in die kusvlaktes of op die vastelandstoep onder huidige seevlak, tot die vervoer van diamante deur weswaarts-vloeiende riviere vanuit die binneland. Geen ontdekkings wat eersgenoemde teorie kon ondersteun is in Namibië gemaak nie. Verder, namate meer gevorderde navorsingsresultate aan die lig gekom het, het dit duidelik geword dat kimberliete wat weg van 'n antieke kraton geleë is, grootliks sonder diamante is, en gevolglik het die idee van nabygeleë diamantdraende kimberliete in die kusvlakte of op die seebodem as bron, onaanvaarbaar geword. Grootskaalse wes- tot suidweswaartse vervoer van diamante het gevolglik die enigste aanvaarbare alternatief gebied. Die ontdekkiing van aan- en aflandige mariene afsettings tot so ver as suid van die Olifantrsrivier het getoon dat die Vaal-Oranjestelsel in sy huidige vorm nie die enigste vervoerkanaal vir diamante na die weskus kon wees nie. Die dreineringsgeskiedenis van suidelike Afrika was gevolglik vertolk aan die hand van twee voorgestelde groot oer-rivierstelsels, naamlik: - Die Karoorivier met sy bolope naastenby soortgelyk aan dié van die moderne Oranje- en Vaalriviere, en wat langs die huidige Olifantsrivier uitgemond het; - Die Kalaharirivier wat die suide van Botswana gedreineer het, en min of meer die roete van die huidige Moloporivier gevolg het, met sy monding baie naby aan dié van die moderne Oranjerivier. 'n Belangrike tekortkoming in bogenoemde model is die feit dat dit nie 'n verduideliking bied vir die volgende feit nie: Diamant-produksiedata van die Suid-Afrikaanse weskus toon 'n skielike toename in graad (karaat per 100 ton) en gemiddelde steengrootte van diamante by die monding van al die belangrike riviere tussen die Olifants- en Oranjeriviere, wat vanaf die platorand na die Atlantiese Oseaan dreineer. Die feit dat fluviale diamantvoorkomste in die valleie van die Bufffels-, Swartlintjies-, Spoeg-, Horees- en Groenriviere aangetref word, bevestig dat hierdie verskynsel nie net aan die teenwoordigheid van kus-inhamme en ruwer vloertopografie wat met die riviermondings geassosiëer is, toegeskryf kan word nie, alhoewel dit wel „n bydrae tot hierdie waarneming kon maak. Dit bevestig dat hierdie riviere wel in hul opvang-gebiede ook toegang tot diamanthoudende puin gehad het, sonder enige kontak met die Olifants- of Oranjeriviere. 'n Aantal navorsers het die gedagte geopper dat diamante wat uit voor-Karoo kimberliete vrygestel was, deur bewegende ysplate en/of gletsers vanaf hul provenansgebiede na die suidweste van die subkontinent vervoer is. Uit die voorafgaande paragrawe is dit duidelik dat, ongeveer ʼn eeu ná die ontdekking van diamante langs die suider-Afrikaanse weskus, daar nog nie eenstemmigheid bereik is oor die oorsprong van hierdie diamante nie. Die doel van hierdie studie was gevolglik die daarstelling van „n model wat „n aanvaarbare verduideliking bied vir die verspreiding en afsetting van sommige voorkomste van spoeldiamante in suidelike Afrika soos tans waargeneem. Vir hierdie doel is 1878 diamante afkomstig vanuit 25 alluviale en twee kimberlietvoorkomste ondersoek. Die resultate is vergelyk met soortgelyke inligting wat bekend is vir diamantpopulasies vanuit 12 suider-Afrikaanse kimberliete. Die diamantstudie is aangevul met die ondersoek van spoelklippe vanuit gruismonsters wat langs die Middel- en Benede Oranjerivier versamel is asook Skanderings-elektron Mikroskoop-analises (SEM) van granaatkorrels en sirkoon-geokronologie. Die resultate van hierdie studie ondersteun nie die hipotese van „n eertydse Karoorivier nie. Die teenwoordigheid van bruin spikkels op diamante wat – in die konteks van die geologiese geskiedenis van suidelike Afrika – vrystelling vanuit vóór- Karoo kimberliete impliseer, asook die resultate van FTIR-analises dui op „n komplekse model wat „n alternatief bied vir bestaande sienswyses. Dit toon dat die diamantpopulasies by Kwaggaskop langs die Soutrivier wat veronderstel was om die Benede Karoorivier te verteenwoordig, en dié wat suid van Brandvlei en Van Wyksvlei in die vallei van die Sakrivier aangetref word en veronderstel was om afkomstig te wees uit die Middel Karoorivier, drasties van mekaar verskil. Dit openbaar ook beduidende verskille tussen die diamantpopulasies van die Olifantsriviermonding en dié van die Kimberley-omgewing waarvandaan die veronderstelde Karoorivier groot hoeveelhede diamante aan die Sout-Olifantsrivier sou gelewer het. Verder verskaf die teenwoordigheid van diamante met bruin spikkels en diamante met eienskappe wat toon dat hul stikstofplaatjies vernietig is, „n skakel tussen Bosluispan in die vallei van die Koarivier en die seegebied noord van die Buffelsrivier, via die Buffelsriviervallei en die Buffelsriviermonding, en hierdie feite ondersteun gevolglik eerder die voorstel dat groot hoeveelhede diamante deur die paleo-Gamoeprivier na die weskus vervoer is. Die teenwoordigheid van diamante met FTIR-kenmerke soortgelyk aan dié van Orapa en Jwaneng in die Mid-Oranje afsettings, 'n mariene terras in die suide van Namakwaland en in mariene konsessies noord van Seegebied 12A, opponeer ook die gedagte van 'n paleo-Kalaharirivier, tensy laasgenoemde 'n baie jong stelsel was wat nie die suidwaartse beweging van Botswana-diamante gedurende die Laat Oligoseen tot Vroeg Mioseen verhinder het nie. Die resultate van die sirkoon-geokronologie het die rol van die Oranjerivier in die afplatting van die subkontinent bevestig. Die volgende model tree uit bogenoemde waarnemings na vore: diamante wat in die noordooste van die subkontinent uit kimberliete met „n voor-Karoo inplasingsouderdom vrygestel is, is aanvanklik suidweswaarts vervoer deur voor-Karoo riviere. Daarna is die diamante deur gletsers en ysplate gedurende die Dwyka-tydperk, en uiteindelik ná vrystelling vanuit ontblote glasiale en paleo-fluviale afsettings tesame met diamante wat intussen vanuit Jura- en Krytouderom kimberliete vrygestel is, deur die dreineringstelsels in die Kryt-tydperk en later, verder suidweswaarts vervoer. Sommige het onderweg in fluviale sedimente (terrasse, karstholtes en ander reste van paleokanale) agtergebly, terwyl „n beduidende hoeveelheid tot in die Atlantiese Oseaan vervoer is waar hulle deur mariene prosesse in ou strandlyne en bodemrots opvangstrukture gekonsentreer is. Die studie het ook die mikroskopiese ondersoek van 'n pakkie diamante afkomstig vanuit die enigmatiese afsettings aan die noordelike Skedelkus van Namibië ingesluit. Op grond van geologiese en geomorfologiese getuienis word die afleiding gemaak dat die Skedelkusdiamante nie met die Oranjemund-afsettings verbind kan word nie, terwyl die mikroskopiese oppervlakteksture toon dat bronne met 'n voor-Karoo inplasingsouderdom die mees waarskynlike provenans vir hierdie diamante is. Die kombinasie van FTIR-analises en oppervlaktekstuur-studies van diamante, sirkoongeokronologie en SEM-analises van granate het die formulering van „n hersiene model vir die subkontinent se dreineringsgeskiedenis sedert die Middel-Kryttydperk en diamantverspreiding moontlik gemaak terwyl die studie van sedimentêre klaste getoon het dat hoë-energietoestande, waardeur diamante van swak gehalte vernietig sou word, herhaaldelik voorgekom het, veral in die paleo-Oranjerivier. Die afleiding word gemaak dat hierdie aspek „n bydrae gelewer het tot die hoë persentasie juweelstene in die oorblywende alluviale diamantpopulasies.