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Design and synthesis of luminescent metal polypyridyl complexes of platinum(II), ruthenium(II) and osmium(II) for chemosensing andbiological studiesTang, Wing-suen., 鄧詠璇. January 2006 (has links)
published_or_final_version / abstract / Chemistry / Doctoral / Doctor of Philosophy
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Design, synthesis and characterization of ruthenium(II) and rhenium(I)complexes with functionalized ligands for photo-and electrochemi-luminescence, solvatochromism, molecular recognition and HPLCseparation studiesLi, Meijin., 李梅金. January 2006 (has links)
published_or_final_version / abstract / Chemistry / Doctoral / Doctor of Philosophy
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Multinuclear DNA binding ruthenium complexesBrodie, Craig R., University of Western Sydney, College of Health and Science, School of Biomedical and Health Sciences January 2006 (has links)
This thesis reports the synthesis, characterisation and DNA binding of a number of novel ruthenium(II) complexes. Four mononuclear complexes were synthesised. These complexes were resolved using a large scale extraction procedure employing the chiral TRISPHAT anion. The racemic mononuclear complexes containing halogenated ligands were used in the synthesis of the racemic dinuclear complexes. Resolved mononuclear complexes were also used to stereo-selectively synthesise enantiomers of their respective dinuclear complexes. All metal complexes were characterised using fluorescence spectroscopy. Resolved metal complexes were further characterised using CD spectroscopy to determine their molar rotation coefficients and optical purity. Preliminary DNA binding studies were conducted using the racemic dinuclear complexes and their mononuclear equivalent. Titration experiments with calf thymus-DNA were used to determine the DNA binding constant and binding site size. Samples containing a higher NaCl concentration (100 mM) slightly improved the oligonucleotide spectrum resolution, but not to an extent where a complex binding model could be determined. Attempts to determine DNA binding preferences of the dinuclear complexes with oligonucleotides which contain two-adenine bulge sites using a 96-well a fluorescence plate reader were attempted, but were unsuccessful. Samples containing a higher NaCl concentration (100 mM) slightly improved the oligonucleotide spectrum resolution, but not to an extent where a complex binding model could be determined. Attempts to determine DNA binding preferences of the dinuclear complexes with oligonucleotides which contain two-adenine bulge sites using a 96-well a fluorescence plate reader were attempted, but were unsuccessful. / Doctor of Philosophy (PhD)
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Substitution and redox chemistry of ruthenium complexes / by Paul Stuart MoritzMoritz, Paul Stuart January 1987 (has links)
Includes bibliographies / 128 leaves : ill ; 30 cm. / Title page, contents and abstract only. The complete thesis in print form is available from the University Library. / Thesis (Ph.D.)--University of Adelaide, Dept. of Physical and Inorganic Chemistry, 1987
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Design, synthesis and characterization of ruthenium(II) and rhenium(I) complexes with functionalized ligands for photo-and electrochemi- luminescence, solvatochromism, molecular recognition and HPLC separation studiesLi, Meijin. January 2006 (has links)
Thesis (Ph. D.)--University of Hong Kong, 2006. / Title proper from title frame. Also available in printed format.
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Surface characterization of Rh-Co, Ru-Co and Pd-Co bimetallic catalystsMoorthiyedath, Sajeev. January 2003 (has links)
Thesis (M.S.)--Mississippi State University. Department of Chemical Engineering. / Title from title screen. Includes bibliographical references.
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Syntheses and spectroscopic studies of luminescent surfactant rhenium(I) and ruthenium(II) diimine complexes: potential applications as functional materials forsecond-harmonic generation and mesoporous silicate formationZhang, Jiaxin, 張家新 January 2004 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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Design, synthesis, and photophysics and photochromic study of dithienylethene-containing heterocyclic derivatives and N-heterocycliccarbene-ruthenium (II) complexesDuan, Gongping., 段公平. January 2010 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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Bioconjugation reactions of peptides and proteins mediated by manganese, ruthenium and gold compoundsChan, On-yee., 陳安怡. January 2010 (has links)
published_or_final_version / Chemistry / Doctoral / Doctor of Philosophy
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Interface engineering and reliability characteristics of HfO₂ with poly Si gate and dual metal (Ru-Ta alloy, Ru) gate electrode for beyond 65nm technologyKim, Young-Hee 28 August 2008 (has links)
Not available / text
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