The Cocos Gap is a deeper portion, or saddle, of the Cocos Ridge and forms part of the western boundary of the Panama Basing It is probably typical of saddles within most submarine ridges, In order to determine the mechanisms controlling sediment dispersal, the nature and sources of the sediments at 23 core locations were defined by hydrodynamic size separation (> 63, 2- 63, <2 micron) and microscopic or X-ray diffraction analysis of the individual fractions. In addition, calcium carbonate, organic carbon, opal and quartz determinations were made for the total sediment. The silt sized fraction was resolved into eight textural modes, The coarse modes reflect the progressive breakage and winnowing of the corase fraction (foraminifera) under the influence of bottom currents and gravity. Above 2000 m mechanical breakdown, winnowing and relocation by bottom currents mask the effects of depth related dissolution of the carbonate fraction, Intermediate modes in general represent a transitional facies with both biogenic and terrigenous influences, while the finest modes characterize a distal regime of clay deposition, The clay fraction is amorphous material with very low percentages of well crystallized clays. Three main sources and transport paths were recognized, including one associated with the circulation of the Panama Basin. Sedimentation within the Gap is controlled by local processes, predominantly the interaction between tidally induced intensification of bottom water flow and directional (thermohaline) flow. The steep' ness of the sea floor slope is a major factor controlling the efficiency of winnowing of the sediment away from certain higher elevations (biogenic source areas) to the sheltered parts and flanks of the ridge. Superimposed upon this sediment dispersal is the influx of terrigenous material carried by directional bottom currents that operate as postulated upper and lower contour currents along the flanks of the ridge. The crest of the Cocos Gap acts as a catchment area for the biogenic components, while the adjacent more sloping region, the sub-plateau, acts as a source area. The extreme breakage of the foraminifera is most likely a function of the tidally induced intensification of the bottom water flow, characteristic of many shallow ridges, and is probably most significant in the subplateau. Hydrographic data indicates that there is no significant transport of bottom water across the Cocos Gap into the Panama Basin, but downslope transport of carbonate and siliceous fragments and minerals from the Gap into the basin is associated with cyclical tidal bottom water flow. / Graduation date: 1976

Graduation date: 1969

Heavy minerals can contain potentially economic amounts of metals as both matrix and trace constituents. Such minerals appear as unconsolidated black sands on the continental shelf off southwest Oregon and along the Oregon coast. Two diverse energies are considered in this investigation. Environmental energy of the depositional regimen, Part I; energy involved in crystallization of transition metals from a magma, Part III. In Part II, an analytical scheme for the evaluation of opaque oxides is proposed, and an examination of the results as applied to two samples is presented. Part I The unconsolidated black sands on the Oregon continental margin have been profoundly affected by tectonic uplift aid by cyclic erosive transgression and regression. Progressive enrichment in heavy minerals from the Klamath Mountains has apparently occurred during each glacio-eustatic regression of the Pleistocene seas, each regression a period of intensified erosion and sediment transport. Subsequent erosive transgressions selectively sort and redistribute these heavy minerals into paralic beach and nearshore deposits. Uplift of the coast and shelf implies that the heavy minerals were reworked during the Holocene transgression into concentrations of greater extent and higher ore tenor than relict deposits of earlier transgressions in upraised Pleistocene terraces. Extrapolation of ore reserve values from the terraces by "Mirror Image" concepts might seriously underestimate the potential of offshore deposits. Offshore heavy mineral concentrations should be coincident with observed submarine terraces. Part II An analytic scheme was developed to investigate opaque oxides in two samples; one from the Pleistocene terraces; the other from near the present shelf edge. Analyses involving X-ray diffraction techniques, atomic absorption and neutron activation established the mineralogy and elemental distribution in magnetically separated diagnostic splits. Chrome spinel, ilmenite and magnetite comprise the opaque oxide fraction in both samples. Correlation studies of these analyses suggest: (1) Chromium is a matrix metal of chrome spinel and is diadochic into magnetite. (2) Iron appears in all opaque oxides and in increasing amounts with increasing magnetic susceptibility. (3) Titanium is a matrix metal in ilmenite, and diadochic into chrome spinel and magnetite. (4) Nickel and ruthenium are diadochic into and correlated to the spinel structure; i.e. to chrome spinel and magnetite. (5) Osmium appears to be correlated to chromium. (6) Zinc is limited to spinel in these samples. Part III Goldschmidt's and Ringwood's criteria for diadochy often fail to explain the distribution of the transition metals because crystal field effects are not considered. Favored d[superscript n] configurations, e.g. octahedrally coordinated, low spin d⁶ cations in the spinel minerals, result in shortened interatomic distance and significantly strengthened cation-ligand bonds, possibly affecting the distribution of such metal cations. The octahedral site preference energy parameter (OSPE) has been used to explain distributional behavior of the first (3d) transition series metals. OSPE calculations for four low spin d⁶ cations - Co(III), Ru(II), Rh(III), and Pt(IV) - give significantly high values for this parameter. High OSPE valued transition metal cations possibly form stable proto-mineral oxide complexes in the magma which persist through crystallization. These associations predetermine the enrichment of transition metals in oxide minerals and act as nuclei during cooling and solidification. Subduction of oxidized and hydrolyzed near-surface rocks down a Benioff zone provides progressively higher Eh in the magma, a variety of cation oxidation states, and water for sepentinization of ultramafic rocks. The distribution of the platinum metals in a strongly reducing magma environment should be different than in the oxidizing magma proposed for the Klamath ultramafics. The OSPE parameter offers an explanation for the observed distribution of platinum group metals in spinel minerals from this investigation, in chromites from Uralian dunitic massifs and the Stillwater complex; and of iridium from the Great Lake Doleritic Sheet, Tasmania. Chrome spinel from Oregon had twice the concentration of ruthenium, and one-third the amount of osmium as similar Uralian chromite deposits. The first significant concentration of ruthenium in magnetite is herein reported recommending continued research into the platinum metal distribution in southwest Oregon. / Graduation date: 1972

Thesis (M.S.)--Oregon State University, 1982. / Typescript (photocopy). Includes bibliographical references (leaves 89-93). Also available on the World Wide Web.

Thesis (M.Sc.)--University of Guelph (Ont.), 2001. / Adviser: Ray Kostaschuk. Includes bibliographical references.

The sequence stratigraphy of the middle Eocene-Pliocene of the Pannonian Basin permits to differentiate fifty-nine depositional sequences. An earlier compressional Paleogene basin in the central and eastern Pannonian Basin is unconformably overlain by a Neogene extensional basin. Tectonic regimes interacted with transgressive-regressive facies cycles. The boundaries of these cycles coincide with regional stage boundaries. Unconformities separating these cycles mark the episodic closure of connections between the Pannonian Basin and the European epicontinental seas from Oligocene through middle Miocene time. The unconformities are the result of short-term glacio-eustatic falls, sometimes enhanced by tectonic events. Within the limits of biostratigraphic resolution during the Eocene-middle Miocene, many of the sequences of the Pannonian Basin correlate well with the sequences proposed by Haq et al. (1987). However, eight sequences, i.e. one in the Lutetian, three in the Bartonian, one in the Priabonian, one in the Rupelian and two in the Burdigalian, were not identified by Haq et al. (1987). The sequences and their boundaries are directly correlated with global oxygen isotope events. Glacioeustasy generates sequence boundaries beginning as early as the middle Eocene. Within the lacustrine setting of the Pannonian Basin (late Miocene- Pliocene time) relative lake level changes appear to control the overall sequence development. However, other minor variables, the sediment supply and the topography of the initial depositional surface were additional controlling factors. Thus differences in the physiography of the basin lead to totally different sequence types that all reflect to lake level fluctuations. In lateral direction, during a short time period, these lacustrine sequences are more sensitive to changes in the initial depositional profile and sediment supply. / pages 390 and 396 are missing from text.

Persistent organic pollutants (POPs), which include polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs), are widely distributed in the environment. Some investigations have demonstrated that these pollutants will cause potential impacts such as carcinogenic and mutagenic for human health. In this study, we analyzed the concentrations and distributions of PAHs and PCBs in sediments of the Er-ren River, as well as the relations with total organic carbon (TOC) and particle sizes. Several molecular ratios were utilized to distinguish the major sources in this study. Results showed that PAH and PCB concentrations in Er-ren River ranged from 12.1 to 1460 and 0.45-591 (ng/g dw), respectively. The maximum concentrations of PAHs and PCBs were mostly found in sediments from Sanyegong River. In comparison with other studies all over the world, the concentrations of PAHs in this study were between low and mid-low levels. PCB concentrations in sediments of the Er-ren River were lower than those reported from previous studies. PAH and PCB concentrations showed no significant correlation between TOC and particle size. Petrogenic and petroleum combustion origin were the main sources of PAHs in sediments of Er-ren River In addition, perylene was the most dominant compound in Er-ren River, suggesting that it could be a useful indicator to differentiate various PAH sources in sediments. The results of hierarchical cluster analysis (HCA) and principal components analysis (PCA) indicated that PAH groups were clustered based on the loading of perylene, while PCB groups were clustered by the compositional homologues of PCBs. Comparing with sediments quality guidelines (SQGs), the PAH concentrations in all the sampling sites were below ERL value, suggesting that few adverse ecological effects would arise from the PAHs. However, the PCB concentrations in 14 sampling sites ranged between TEL and PEL values, indicating that adverse effects could arise for benthic organisms. The £UESBTUFCV of PAHs and the toxic equivalents (TEQ) of PCBs were both lower than quality values reported, suggesting that adverse ecological effects might be not expected.

Polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) are persistent, ubiquitous, and toxic organic contaminants in coastal sediments. Being hydrophobic in water column, PAHs and PCBs tend to sorb rapidly on particles and eventually accumulate in sediments. Re-suspension of fine or low-density particles from the surface sediment would lead to release of the pollutants bound in sediment particles into water column. This study was to evaluate the potential of remobilization of sediment-bound pollutants into harbor water column by measuring the concentrations and compositions of PAHs and PCBs in different particle size (size fraction: 1000, 500, 250, 125 and 63 £gm) and the different density fractions (density: > 2.15, < 2.15 g/cm3) in the Kaohsiung Harbor area. The total PAH concentrations obtained from the sediments of Kaohsiung sub-channel (KH1) is higher than those of Shang-Zhu-Li fishing ferry (KH2), but it presents the opposite situation in total PCB concentrations. Total PAH concentrations are 3400 and 1700 (ng/g dw) and total PCB concentrations are 103 and 141 (ng/g dw) at sites of KH1 and KH2. PAH and PCB concentrations in the low-density fraction sediment made up more than 91% and 87% of the total concentration of the bulk sediment, respectively; while low-density fraction sediment made up only 4.3 to 7.7% of the bulk sediment in dry weight. According to the chemical fingerprinting, PAH source of Kaohsiung sub-channel (KH1) is from pyrogenic which might be from the diesel oil burning of shipping activities and containerized traffic. But the PAH sources in Shang-Zhu-Li fishing ferry (KH2) were from the combustion of coal and petroleum, which is possibly from iron and steel plant and the power plant nearby. The Toxic equivalents (TEQ) of dioxin-like PCBs in low and high-density fraction sediments were ranged from 1.1-7.6 pg-TEQ/g and 8.9-1500 pg-TEQ/g, respectively. Based on the Sediment Quality Guidelines (SQGs), only few PAH concentrations in the high-density fraction sediments were higher than the TEL value, while most of PAH concentrations in the low-density fraction sediments ranged between ERL and ERM values. This suggests the low-density sediment particles possessed higher potential of adverse effects to organisms in the aquatic environment.

Thesis (Ph. D.)--Lehigh University, 2000. / Includes vita. Includes bibliographical references (leaves 88-97).

Thesis (M.C.E.)--University of Delaware, 2009. / Principal faculty advisor: Jack A. Puleo, Dept. of Civil & Environmental Engineer. Includes bibliographical references.