Hybrid lead halide perovskites, AMX 3 compounds in which A = CH 3 NH 3 (MA), CH(NH 2 ) 2(FA), Cs; M = Pb,Sn; X = I, Br, Cl, display remarkable performance in solution-processed optoelectronic devices, including > 22% efficient thin film photovoltaic cells. These compounds represent the first class of materials discovered to exhibit properties associated with high performance compound semiconductors, while being formed at or near room temperature using simple solution chemistry techniques. This thesis is focused on the synthesis, structural characterisation and phase behaviour of MAPbI 3 , FAPbI 3 , A-site solid solutions and novel organic metal halide framework materials. The complete atomic structure and phase behaviour of methylammonium lead iodide is elucidated for the first time, including hydrogen positions, using high flux, constant wave-length neutron powder diffraction. At 100 K an orthorhombic phase, space group Pnma, is observed, with the methylammonium cations ordered as the C–N bond direction alternates in adjacent inorganic cages. Above 165 K a first order phase transition to tetragonal, I4/mcm, occurs with the unlocking of cation rotation, which is disordered primarily in the ab plane. Above 327 K a cubic phase, space group Pm3m, is formed, with the cations isotropically disordered on the timescale of the crystallographic experiment. The high temperature phase of formamidinium lead iodide, α-FAPbI 3 is shown for the first time to be cubic, (Pm3m), at room temperature using time-of-flight, high resolution neutron powder diffraction. Polymorphism and the low temperature phase behaviour of FAPbI 3 have been further investigated using reactor and spallation neutron sources with high resolution in temperature. A tetragonal phase, P4/mbm, is confirmed in the temperature range 140-285 K.The composition, structural and optical parameters of ’A’ site solid solutions (MA/FA)PbI 3 have been investigated by single crystal X-ray diffraction, UV-vis spectroscopy and 1 H solution NMR. A composition-dependent transition in the crystal class from tetragonal to cubic(or pseudo-cubic) at room temperature is identified and correlated to trends in the optical absorption. Novel hybrid materials with inorganic frameworks of varying dimensionality from 0D to 2D, including imidazolium lead iodide and piperazinium lead iodide, have been synthesised using various templating organic cations and their atomic structures solved by single crystal X-ray diffraction.

Thesis. 1977. M.Arch.--Massachusetts Institute of Technology. Dept. of Architecture. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND ROTCH. / Bibliography : leaves 98-100. / by James S. Day. / M.Arch.

Orientador: Vicente Luiz Scalon / Banca: Ismael de Marchi Neto / Banca: Geraldo Luiz Palma / Resumo: A busca mundial for fontes de energia que garantam um crescimento sustentável tem marcado o século XXI. Nesse cenário, o Brasil é beneficiado, com diversas fontes de energias viáveis nas condições atuais e outras promissoras num cenário de médio e longo prazo. A utilização da energia solar convertida em energia térmica ou elétrica apresenta-se como uma destas alternativas. Explorar a energia solar de forma viável economicamente e melhorar a eficiência de captação e transformação são os grandes desafios que se apresentam. Neste contexto, este estudo se propôs a analisar experimentalmente o desempenho de um Sistema Acoplado, composto por coletores planos com e sem cobertura. O objetivo é reduzir o custo de implantação de um sistema de aquecimento, uma vez que o os coletores sem cobertura são mais baratos. Além disso, dependendo das características de implantação, é ainda possível aumentar a eficiência global do sistema através de um pré-aquecimento da água no coletor sem cobertura, aproveitando a maior eficiência térmica para temperaturas de operação próximas a do ambiente. Para estudo do Sistema Acoplado, um outro sistema composto apenas por coletores com cobertura foi montado e denominado Sistema Simples. Desta forma, com os dois aparatos montados e devidamente instrumentados foi possível obter resultados para as mesmas condições ambientais de teste. Assim, diversos esquemas de controle também puderam ser testados e analisados tanto na operação do Sistema Acoplado como do Sis... (Resumo completo, clicar acesso eletrônico abaixo) / Abstract: The global search for energy sources that ensure sustainable growth has market the 21 st century. In this scenario, Brazil is benefited, with several viable sources of energy under current conditions and other promising sources in a medium and long-term scenario. The use of solar energy converted into thermal or electric ones presents itself as one of these alternatives. Using solar energy in a cost-effective way and improving the performance for capturing and transforming are the major challenges nowadays. In this content, this study proposed to analyze experimentally the performance of a Coupled System, composed by glazed and unglazed flat collectors. The purpose of this system is to reduce the installation costs of a heating system, since the unglazed collectors are less expensive. In addition, depending on its implementation chareacteristics, it is possible to increase the overall eficiency of the system by preheating the water in an unglazed collector, taking advantage of its higher thermal efficiency at nearby operating and ambient temperatures. For analysis of Coupled System, another system composed only of glazed collectors was assembled and denominated as Simple System. In this way, with the two devices mounted and instrumented some results can be obtained for the same environmental test conditions. Thus, several control schemes could also be tested and analyzed in the operation of both systems. Comparative results evaluating the output conditions, useful and stored energy and thermal performances are presented and compared for the systems / Mestre

In a world that is constantly in need of a continuous, reliable and sustainable energy supply, concentrating photovoltaic technologies have the potential to become a cost effective solution for large scale power generation. In this light, important progresses have been made in terms of cell’s design and efficiency, but the concentrating photovoltaic industry sector still struggles to gain market share and to achieve adequate economic returns. The work presented in this thesis is focused on the development of innovative solutions for high concentrating photovoltaics receivers. The design, the fabrication and the characterization of a large cell assembly for high concentrations are described. The assembly is designed to accommodate 144 multijunction cells and is rated to supply energy up to 2.6kWe at 500 suns. The original outline of the conductive copper layer limits the Joule losses to the 0.7% of the global power output, by reducing the number of interconnections. All the challenges and the issues faced in the manufacturing stage are accounted for and the reliability of the fabrication has been proven by quality tests and experimental investigations conducted on the prototype. An indoor characterization shows the receiver’s potential to supply a short-circuit current of 5.77A and an open circuit voltage per cell of 3.08V at 500×, under standard test conditions, only 4.80% and 2.06% respectively lower than those obtained by a commercial single-cell assembly. An electrical efficiency of 29.4% is expected at 500 suns, under standard conditions. A prototype’s cost of $0.91/Wp, in line with the actual price of CPV systems, has been recorded: a cost breakdown is reported and the way to further reduce the cost have been identified and is accounted. In a second approach, the design of a natural convective micro-finned array to be integrated in a single cell receiver has been successfully attempted. Passive cooling systems are usually cheaper, simpler and considered more reliable than active ones. After a detailed review of micro-cooling solutions, an experimental investigation on the thermal behaviour of micro-fins has been conducted and has been combined with a multiphysics software model. A micro-finned heat sink shows the potential to keep the CPV temperature below 100°C under standard conditions and the ability to handle the heat flux when the cell’s efficiency drops to zero. Moreover, a micro-finned heat sink demonstrates the potential to introduce significant benefits in terms of material usage and weight reduction: compared to those commercially available, a micro-finned heat sink has a power-to-weight ratio between 6 and 8 times higher, which results in lower costs and reduced loads for the CPV tracker.

Although the thermodynamic advantages of using solar energy to replace the bled off steam in the regeneration system of Rankine cycle coal fired power stations has been proven theoretically, the practical techno/economic feasibility of the concept has yet to be confirmed relative to real power station applications. To investigate this concept further, computer modelling software “THERMSOLV” was specifically developed for this project at Deakin University, together with the support of the Victorian power industry and Australian Research Council (ARC). This newly developed software simulates the steam cycle to assess the techno/economic merit of the solar aided concept for various power station structures, locations and local electricity market conditions. Two case studies, one in Victoria Australia and one in Yunnan Province, China, have been carried out with the software. Chapter one of this thesis defines the aims and scope of this study. Chapter two details the literature search in the related areas for this study. The thermodynamic concept of solar aid power generation technology has been described in chapter three. In addition, thermodynamic analysis i.e. exergy/availability has been described in this chapter. The “Thermosolv” software developed in this study is detailed in chapter four with its structure, functions and operation manual included. In chapter five the outcomes of two case studies using the “Thermosolv” software are presented, with discussions and conclusions about the study in chapters 6 and 7 respectfully. The relevant recommendations are then made in chapter eight.

Graduation date: 1966

Thesis (Ph.D.)--University of Delaware, 2006. / Principal faculty advisor: Jingguang G. Chen, Dept. of Chemical Engineering. Includes bibliographical references.

The growing necessity for meaningful climate change response has encouraged the development of global warming mitigation and adaptation initiatives. Urban solar energy generation is one opportunity that has been investigated by numerous cities through various solar potential Web-applications. However, as solar feasibility can vary considerably across a small geographic area due to variations in local topography and feature shading, there is no one-size-fits-all solution to be implemented. This thesis investigates how a Web-based spatial decision support system (SDSS) can enable non-experts to explore urban solar feasibility and, to a lesser extent, issues related to urban heat. First, a conceptual framework is developed that investigates the linkages between SDSS, Web technologies, public participation, volunteered geographic information, and existing green energy initiatives. This framework identifies the relevance between these fields of study as well as a number of opportunities for improving on past work and taking advantage of new technical capabilities. Second, in order to test the opportunities identified, SunSpot was developed. This Web-SDSS investigates rooftop solar feasibility as well as land cover and surface temperature dynamics relating to the urban heat-island effect in Toronto, Ontario, Canada. A number of solar resource datasets were developed in order to facilitate the decision making capabilities of SunSpot. This was done using a combination of different topographical data sources, atmospheric data, and a raster-based irradiance model called Solar Analyst. Third, a number of in-person workshops were conducted to obtain feedback on SunSpot’s usability and ability for users to understand the visual layers and results. Finally, this feedback was analyzed to identify the successes and challenges of SunSpot’s capabilities and design. This revealed a number of recommendations for further development of SunSpot, as well as opportunities for future research relating to the development of local scale solar resource data and the development of similar Web-SDSS applications.

Photon energy upconversion (UC), a process that can convert two or more photons with low energy to a single photon of higher energy, has the potential for overcoming the thermodynamic efficiency limits of sunlight-powered devices and processes. An attractive route to lowering the incident power density for UC lies in harnessing energy transfer through triplet-triplet annihilation (TTA). To maximize energy migration in multicomponent TTA-assisted UC systems, triplet exciton diffusivity of the chromophores within an inert medium is of paramount importance, especially in a solid-state matrix for practical device integration. In this thesis, low-threshold sensitized UC systems were fabricated and demonstrated by a photo-induced interfacial polymerization within a coaxial-flow microfluidic channel and in combination with nanostructured optical semiconductors. Dual-phase structured uniform UC capsules allow for the highly efficient bimolecular interactions required for TTA-based upconversion, as well as mechanical strength for integrity and stability. Through controlled interfacial photopolymerization, diffusive energy transfer-driven photoluminescence in a bi-molecular UC system was explored with concomitant tuning of the capsule properties. We believe that this core-shell structure has significance not only for enabling promising applications in photovoltaic devices and photochromic displays, but also for providing a useful platform for photocatalytic and photosensor units. Furthermore, for improving photon upconverted emission, a photonic crystal was integrated as an optical structure consisting of monodisperse inorganic colloidal nanoparticles and polymer resin. The constructively enhanced reflected light allows for the reuse of solar photons over a broad spectrum, resulting in an increase in the power conversion efficiency of a dye-sensitized solar cell as much as 15-20 %.

The two main challenges of the twenty-first century are the scarcity of energy sources and global warming; trigged by the emission of greenhouse gases. In this context, solar energy became increasingly relevant. Because it makes optimal use of the resources, minimizes environmental impacts, and is sustainable over time. However, before installing solar panels, it is convenient pre-assessing the amount of energy that a building can harvest. This study proposes a methodology to semi-automatically generate information a building scale; on a large area. This thesis integrates airborne Light Detection and Ranging (LiDAR) and WoldView-2 satellite data for modelling the solar energy potential of building rooftops in San Francisco, California. The methodology involved building detection solar potential analysis, and estimations at building scale. First, the outline of building rooftops is extracted using an object-based approach. Next, the solar modelling is carried out using the solar radiation analysis tool in ArcGIS, Spatial Analyst. Then, energy that could potentially be harvested by each building rooftop is estimated. The energy estimation is defined in economic and environmental terms.