Long-term perspectives on the evolution of river deltas have provided useful knowledge capable of responding to pending questions related to the ongoing climate and environmental changes. Increasing utilization pressure on delta environments has necessitated increased attention to protect the socio-economic and ecological values. As a result, multiple local initiatives have been designed, aimed at mitigating environmental deterioration and implementing adaptive measures, but many such initiatives have shown limited success. This thesis uses a case study of Save River delta in Mozambique to explore the relation between geomorphological evolution and socio-ecological system dynamics in delta environments. In addition, key environmental variables that concern the society today are highlighted and discussed in a management perspective. The results of the study show the development of Save River delta from the mid-Holocene to the present. The geomorphological settings of the delta suggest a faulted coastline over which subsequent deposition of fluvial sediments has formed a protruding delta front. Between c. 3000 and 1300 years ago, fine-grained sediments accumulated on top of the delta-front in the proximal part of the delta. This type of material was deposited under intertidal conditions and supported the formation of mangrove habitat. The geographical distribution of the mangrove deposit was driven by successive stages of back-barrier swamp formation and sea-level change as the delta evolved. From c. 1300 years ago, the river delta started to receive fluvial sediments from pulses of floods forming an alluvial floodplain. These sediments have accumulated mainly on the fine-grained mangrove wetland deposit. All the geomorphological features have evolved in a shoreward-shifting pattern over time. Centennial to decadal changes observed in the delta have followed a predictable geomorphological pattern, which is also part of the millennial evolution. The mangrove system, the base for the socio-economic system, is consequently strongly affected by the geomorphological development of the area. An increasing sensitivity of socio-ecological systems to environmental stressors, e.g. floods, cyclones and erosion, has motivated multiple initiatives to work towards a sustainable management of delta environments. This thesis highlights the need for interplay between geomorphology and ecology, considering both long- and short-term dynamics of delta environments. Hitherto, management initiatives have been concentrated on fragmented interventions of controlling water flow, which have disrupted the natural dynamics by obstructing the sedimentation-erosion cycle. To change this trend, coastal planners need to consider the significance of natural processes, e.g. cyclones, floods, erosion and accretion, for the long-term ecological and social sustainability of delta environments. / <p>At the time of the doctoral defense, the following papers were unpublished and had a status as follows: Paper 1: Manuscript. Paper 2. Manuscript. Paper 3: Manuscript. Paper 4: Manuscript.</p>

Les concentrations élevées en pesticides dans les eaux de surface drainant des bassins versants agricoles sont devenues une préoccupation majeure en Europe depuis une cinquantaine d'années. Les pesticides sont transférés dans l'environnement par différentes voies (le ruissellement de surface et de sub-surface, le flux de nappe), soit en solution soit adsorbés aux particules de sol en suspension dans l'eau. Les eaux de ruissellement et de percolation entraînent avec elles des charges de contaminants dont les concentrations en solution peuvent s'avérer toxiques pour la faune et la flore aquatique et rendre l'eau impropre à la consommation humaine si le réseau de drainage est une source de captage pour l'alimentation en eau potable. Les crues constituent donc des événements hydrologiques de première importance dans la contamination des eaux continentales par les pesticides. Les objectifs de cette thèse ont été de (1) caractériser, à l'aide d'un modèle agro-hydrologique, la dynamique des transferts de pesticides à l'échelle du bassin versant dans une région agricole, notamment en période de crue ; (2) identifier les facteurs de contrôle du transfert de pesticides et (3) améliorer, le cas échéant, les équations formalisées dans le modèle. Deux approches ont été menées de front afin de répondre aux questions posées : l'analyse de données mesurées et modélisées sur le bassin versant agricole de la Save (sud-ouest de la France). Une étude de faisabilité réalisée en préliminaire a montré que le modèle Soil and Water Assessment Tool (SWAT - Arnold et al., 1998) était adapté à la modélisation du transfert de pesticides, dans les phases dissoute et particulaire, à l'échelle du bassin versant. L'hydrologie et les concentrations à l'exutoire des phases dissoute et particulaire (respectivement les nitrates et les matières en suspension) ont été calibrées. Les voies privilégiées de transfert des pesticides en fonction des conditions hydrologiques ont été identifiées. La modélisation a ensuite été mise en œuvre avec des itinéraires techniques plus détaillés en entrée du modèle et des mesures sub-journalières de pesticides en crue. Les différentes voies de transfert des pesticides dans les deux phases, ainsi que leurs facteurs de contrôle environnementaux, ont été étudiés. Deux facteurs de contrôle, respectivement dépendant des pratiques agricoles (la date d'application des pesticides, qui est un facteur anthropique) et intrinsèque aux molécules de pesticides (le coefficient Kd de partition entre phases dissoute et particulaire, qui est un facteur physico-chimique) ont été abordés plus en détail. Le rôle de la typologie du bassin versant sur les transferts est discuté. Des cartes de risque de contamination des eaux de surface par les pesticides sont présentées pour le bassin de la Save. Dans la perspective d'améliorer le formalisme des modèles de transfert des pesticides, une équation qui relie le coefficient Kd au coefficient de distribution octanol/eau Kow et à la concentration en matières en suspension a été proposée. / Rising pesticide levels in streams draining intensively managed agricultural land has become a widespread problem throughout Europe in recent decades. Pesticides are transferred into the environment through various pathways (surface and sub-surface runoff, groundwater return flow), either in solution or sorbed onto particles. Runoff and percolating water carry contaminants loads which concentrations in solution may be harmful to terrestrial and aquatic ecosystems rendering water unfit to human consumption if the draining network is a source for drinking water. Floods are hydrological events of major importance in continental waters contamination by pesticides. The objectives of this PhD thesis were (1) to characterise pesticides transfer dynamics at catchment scale in an agricultural area during floods; (2) to identify the factors controlling pesticides transfer and (3) to improve modelling by changing formalism with more suitable equations. Two approaches were set up: analysing both measured and simulated data sets, stemming from the River Save catchment (south-western France). A preliminary feasibility study showed that the Soil and Water Assessment Tool (SWAT - Arnold et al., 1998) was adapted for pesticides transfer modelling in both dissolved and sorbed phases, at catchment scale. Water discharge, dissolved and sorbed phases (respectively nitrate and suspended sediments) were calibrated. Pesticides transfer preferred pathways depending on hydrological conditions were identified. Modelling was then carried on more detailed management practices as input and on sub-daily pesticides concentration measurements during flood events. The various transfer pathways in both phases together with the environmental controlling factors were assessed. At last, two controlling factors, respectively depending on management practices (application date, an anthropogenic factor) and on an intrinsic pesticide molecule property (the partition coefficient Kd which is a physico-chemical factor) were studied. The role of catchment typology was discussed. Surface water contamination risk maps were drawn on Save catchment. In order to improve the formalism of pesticide transfer models, an equation was proposed that relates Kd to the octanol/water partition coefficient Kow and to suspended matter concentration.