Thesis (Ph. D.)--Brigham Young University. Dept. of Electrical and Computer Engineering, 2000. / Includes bibliographical references (p. 255-65).

Little is known about the factors driving the cycle of the climate-active gas dimethylsulfide (DMS) and of its precursor the metabolite dimethylsulfoniopropionate (DMSP) in sea ice. To date, studies have focused on biotic factors, linking high DMSP concentrations to the high biomass of sympagic communities, and to physiological adaptations to the low temperatures and high salinities of the brine habitat. This thesis presents an approach integrating biotic and abiotic factors, investigating the influence of ice growth processes and brine dynamics on the DMS cycle. First, brine dynamics from growth to melt are explored based on ice temperature and salinity profiles measured in the Arctic. A strong but brief desalination phase is identified in spring. Using calculated proxies of permeability (brine volume fraction) and of the intensity of brine convection (Rayleigh number), this phase is shown to correspond to full-depth gravity drainage initiated by restored connectivity of brines on warming. Full-depth gravity drainage is crucial for the vertical transfer of DMS-compounds at the ice-ocean interface. This physical background is then used to investigate the spatio-temporal variability of DMS in Arctic sea ice during a year-round survey in Amundsen Gulf. The influence of processes such as scavenging and brine convection on the DMS cycle is shown, and the first combined measurement of DMS, DMSP, and dimethylsulfoxide (DMSO), a compound acting as source/sink for DMS through photo-chemical and bacterial processes, is presented. DMSO is shown to dominate the dimethylated sulfur pool in surface ice when the snow cover is low. Based on correlations with irradiance, it is suggested that this DMSO originates from photo-chemical oxidation of DMS trapped in impermeable ice. Finally, the spatio-temporal variability of DMS in Antarctic sea ice is investigated during another year-round survey in McMurdo Sound. Platelet crystals growth under the influence of ice-shelf waters are shown to favor the incorporation of strong DMSP producers, to increase the environmental stress on cells, and to favor the accumulation of DMS,P by reducing permeability. The increase of permeability on warming is shown to trigger strong release of DMS in the ocean and a vertical redistribution of DMSP in the ice cover.

The seasonal pattern of ice motion in response to wind forcing and potential consequences to upwelling on the Mackenzie Shelf are considered using satellite-derived ice motion data from the National Snow and Ice Data Center and the NCEP 10 m wind data. The frequency of strong upwelling-favorable alongshore ice motion is high in early winter (November and December) compared to middle and late winter (January to May).For periods when the alongshore component of the wind is upwelling-favorable, the ratio of ice drift divided by wind speed on the Mackenzie Shelf is 0.024 in November and0.008 in March; we conjecture that this ratio decreases as winter progresses because the internal ice stress becomes stronger as both ice thickness and ice concentration increase. This constitutes a possible 10-fold decrease in the seasonal transmission of wind stress to the underlying water from November to March. This ratio in May (0.015) is higher than that in March. We suggest that it is because the internal ice stress becomes weaker as ice concentration decreases on the Mackenzie Shelf in May. Hence, under the same wind forcing, the potential for winter upwelling on Mackenzie Shelf may be enhanced if climate warming results in reduced ice thickness and/or ice concentration. Numerical model results show that the stress on the shelf could be reduced because of the internal ice stress from the pack ice over the deep ocean when the ice moves like a rigid body. We found that the model results are not realistic when the ice strength is 5,000 Nm-2. When the ice strength is 27,500 Nm-2, the model results are more realistic.

The seasonal asymmetry in coastal temperatures on Hudson Bay was explored and evaluated as a proxy to hindcast sea ice conditions prior to 1972. Various indices of air temperature difference (∆T) between Churchill, MB and Inukjuak, QC were tested for linear correlations with spatially averaged sea ice concentration (SIC) and ice-free season length (IFS). A multiple regression equation employing a 31-day average of peak ∆T and a 61-day average of temperature during freeze-up reproduced the IFS record with an average error of 8.1 days. This equation was employed to extend the IFS record by 28 years. The resulting 68-year time series revealed a significant increasing trend most pronounced from 1985 to 2011. Hindcast data helped eliminate low-frequency climate oscillations of periodicity <68 years as a source of this trend, lending further evidence to the growing consensus of a declining sea ice being the result of anthropogenic climate forcing.

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Mercury (Hg) is one of the primary contaminants of concern in the Arctic marine ecosystem. Methyl Hg (MeHg) is known to biomagnify in food webs. During the International Polar Year - Circumpolar Flaw Lead study, sea ice, seawater, bottom ice algae, phytoplankton and the herbivorous copepods were collected from the Amundsen Gulf to test whether ice algae and phytoplankton assimilate Hg from their habitat, and whether Hg bioaccumulates from the seawater to the primary consumers. Sea ice algae were found to accumulate Hg primarily from the bulk bottom ice, and the sea ice algae bloom depleted Hg stored within the bottom section of the ice. Furthermore, biodilution of Hg was observed to occur in sea ice algae. Higher concentrations of Hg were also found in phytoplankton and in grazing copepods. A positive correlation between MeHg and trophic level suggests the occurrence of MeHg biomagnification even at these low trophic positions.

No description available.

Active microwave remote sensing is an important tool for classification of sea ice in polar regions. The aim of this research is to improve the understanding of microwave scattering that occurs during the advanced melt season, with a focus on multiyear ice (MYI). This was done using a combination of in situ C-Band scatterometer measurements, geophysical characteristics of ice, and Radarsat-2 data. Results indicate that it is difficult to differentiate between first year ice (FYI) and MYI during advanced melt but combinations of incidence angle and polarization exist that assist with this. It is known that the presence of liquid water governs microwave scattering, therefore further research investigating the variation of microwave backscattered signatures over a diurnal time period was conducted. These results indicate an inverse relationship between temperatures and microwave signatures. The overall results from this research show that summer MYI signatures are extremely variable and difficult to classify.

Mercury (Hg) is one of the primary contaminants of concern in the Arctic marine ecosystem. Methyl Hg (MeHg) is known to biomagnify in food webs. During the International Polar Year - Circumpolar Flaw Lead study, sea ice, seawater, bottom ice algae, phytoplankton and the herbivorous copepods were collected from the Amundsen Gulf to test whether ice algae and phytoplankton assimilate Hg from their habitat, and whether Hg bioaccumulates from the seawater to the primary consumers. Sea ice algae were found to accumulate Hg primarily from the bulk bottom ice, and the sea ice algae bloom depleted Hg stored within the bottom section of the ice. Furthermore, biodilution of Hg was observed to occur in sea ice algae. Higher concentrations of Hg were also found in phytoplankton and in grazing copepods. A positive correlation between MeHg and trophic level suggests the occurrence of MeHg biomagnification even at these low trophic positions.