The study aims to investigate the correlation for new veterans among their personalities, family factors, relevant coping strategies for employments provided by Veteran Affairs Commission in Tainan and re-employment. The research findings will be offered to administrators in Veteran Affairs Commission, as well as future researchers in the field, which would promote the possibility of employment for new veterans. Moreover, individual personalities such as gender, age, marriage, education, military seniority, type of demobilization pension, demobilization rank, situations of family and work, duration of unemployment and so on will be taken into consideration for probing the effect on re-employment. These findings will be reference for government to provide adaptive service for individual difference based on called ¡§Walking around service.¡¨ Finally, the research findings would suggest the administration, i.e. Ministry of National Defense, Council of Veteran Affairs, and Council of Labor Affairs, to cultivate second major training for those active military officials. These plans for their careers after demobilization will help them get used to the society, contribute more effort to the country in the next stage of life. The research subjects include new veterans in Tainan who demobilized in three years. The data was collected by distributing 486 questionnaire and 128 returned, effective returned rate reached 26.83%. The questionnaire was designed based on related references and inventories. The collected data were analyzed with SPSS 12.0 by using Reliability Analysis, Factor Analysis, Descriptive Statistics, t-test, One-Way ANOVA, Regression Analysis as well as Hieraechical Regression Analysis. The research findings concluded as follows: 1. The personality of new veteran has significant effect on his/her re-employment. 2. The personality of new veteran has significant positive effect on his/her work value. 3. The family factor new veteran has interaction between his/her personality and work value. 4. The opinion on re-employment provided by Veteran Affair Commission in Tainan has significant effect on personality, work values, family factors.