Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. The unique behavior of hydrate-bearing sediments requires the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Hydraulic conductivity decreases with increasing variance in pore size distribution; while spatial correlation in pore size reduces this trend, both variability and spatial correlation promote flow focusing. Invading gas forms a percolating path while nucleating gas forms isolated gas bubbles; as a result, relative gas conductivity is lower for gas nucleation than for gas invasion processes, and constitutive models must be properly adapted for reservoir simulations. Physical properties such as gas solubility, salinity, pore size, and mixed gas conditions affect hydrate formation and dissociation; implications include oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations. High initial hydrate saturation and high depressurization favor gas recovery efficiency during gas production from hydrate-bearing sediments. Even a small fraction of fines in otherwise clean sand sediments can cause fines migration and concentration, vuggy structure formation, and gas-driven fracture formation during gas production by depressurization.

published_or_final_version / Environmental Management / Master / Master of Science in Environmental Management

No description available.

Graduation date: 1980

Hydrate-bearing sediments may contribute to the availability of energy resources, affect climate change, or cause seafloor instability. The comprehensive study of hydrate-bearing sediments documented in this manuscript includes physicochemical aspects of hydrate nucleation near mineral surfaces, the validity of THF as a substitute guest molecule for the study of hydrate-bearing sediments, and the effects of hydrate formation on the electromagnetic and the mechanical properties of various soils with a wide range of specific surface. Natural marine sediments are included as part of this investigation to explore the effects of inherent fabric, salts, organic matter, and stress history on the geophysical properties of hydrate-bearing sediments. Experiments are designed to reproduce the state of effective stress in the field at the time of hydrate formation. A comprehensive set of instruments is deployed in this study, and the unprecedented development of electrical resistivity tomography for the study of hydrate formation and dissociation is also documented in detail. Results from this research have important implications for geophysical field characterization and monitoring processes such as production.

Title page, contents and abstract only. The complete thesis in print form is available from the University of Adelaide Library. / The aims of this investigation on the Holocene carbonate successions of three shallow, ephemeral lakes from the Cooring coastal plain were: to determine the timing of the sapropel ’events’ in the three lakes; to determine the origin of the sapropelic organic matter and evaluate changes; to establish whether sapropel deposition in these shallow, coastal lakes primarily reflects increased organic matter delivery to the sediments during periods of enhanced terrestrial input and/or aquatic productivity, and; to relate sapropel deposition in these three lakes to both regional and global palaeoenvironment reconstructions. --p. 23-24. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1324064 / Thesis (Ph.D.) -- University of Adelaide, School of Earth and Environmental Sciences, 2007

Title page, contents and abstract only. The complete thesis in print form is available from the University of Adelaide Library. / The aims of this investigation on the Holocene carbonate successions of three shallow, ephemeral lakes from the Cooring coastal plain were: to determine the timing of the sapropel ’events’ in the three lakes; to determine the origin of the sapropelic organic matter and evaluate changes; to establish whether sapropel deposition in these shallow, coastal lakes primarily reflects increased organic matter delivery to the sediments during periods of enhanced terrestrial input and/or aquatic productivity, and; to relate sapropel deposition in these three lakes to both regional and global palaeoenvironment reconstructions. --p. 23-24. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1324064 / Thesis (Ph.D.) -- University of Adelaide, School of Earth and Environmental Sciences, 2007

Thesis (Ph. D.)--University of Adelaide, Dept. of Geology and Geophysics, 1987. / Includes bibliographical references (leaves 275-290).

Thesis (Ph. D.)--University of Texas at Austin, 2007. / Vita. Includes bibliographical references.

Thesis (Ph. D.)--Oregon State University, 2009. / Printout. Includes bibliographical references (leaves 211-223). Also available on the World Wide Web.