A self-healing material has the inherent ability to partially reverse damage such as crack formation that might have occurred during its service. Significant evidence exists in the literature to indicate that asphalt binder is a self-healing material. It is also well known that healing has a substantial affect on the performance of asphalt mixtures and consequently on the serviceable life of asphalt pavements. For example, shift factors from laboratory experimental data to field observed data show that laboratory data underpredict field observations. There is a need to understand the mechanisms that are responsible for healing in asphalt binders as well as to develop test methods that can be used to determine properties related to these mechanisms. This thesis presents details and findings from a two-part study that addresses each one of these two aspects. In the first part of this study, a test method based on the use of a Dynamic Shear Rheometer (DSR) was developed to determine the parameters of characteristic healing function of asphalt binders. In the second part of this study, Molecular Modeling (MM) techniques were used to determine the interrelationship between molecular structure, surface free energy, self diffusivity, and other healing properties of asphalt binders.The healing characteristic equation parameter (Ro) which represents the instantaneous healing nature of the asphalt binders is analogous to surface energy in terms of effect on healing in asphalt binders. Ro values for three asphalt binders AAM, AAD and ABD are calculated and compared with the surface energy values available from the literature. It was observed that the Ro values are proportional to surface energy values. Surface energy values for five asphalt binders AAM, AAD, AAB, AAG and AAF are calculated using MM method based on SHRP representative molecules. These values were observed to be proportional to the surface energy values from literature. Bulk and surface diffusion coefficients of asphalt molecules are calculated using MM method. Parametric analysis was done to determine the effect of chemical structure of asphalt on its diffusion properties. It was observed that the higher percentage of saturates in the chemical structure results into higher diffusion coefficients.

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This paper will examine, how queer is represented in the animated tv-serie She-Ra and the princesses of powerfrom 2018-2020. To understand this work, the paper will define representation, gender and queer, and examine the visual and narrative elements in the tv-serie. Through a visual analysis, the paper can understand if the serie represent queer values. Then the paper will look at some characters from the serie, to see if their visual design and the narrative structure reflects queer characteristics. This means the paper will define what are queer values and how is it shown in the characters of the show. It will be supplied with theory about queer and gender, for examples Raewyn Connell and Stuart Hall. The theory will supply characteristics, which have defined the social norms about genders through history. This paper concludes that the tv-serie reflects queer values through it’s visual and narrative structure. The characters have queer personalities. I need this paper with a discussion of the effects of queer representation and other ways to look at the serie from a perspective of gender.

This research aims to investigate the behaviour of glass fibre reinforced polymer bars (GFRP) reinforced continuous concrete deep beams. For this purpose, experimental, analytical and numerical studies were conducted. Nine continuous concrete deep beams reinforced with GFRP bars and one specimen reinforced with steel bars were experimentally tested to failure. The investigated parameters included shear span-to-overall depth ratio (𝑎/ℎ), size effect and web reinforcement ratio. Two 𝑎/ℎ ratios of 1.0 and 1.7 and three section heights of 300 mm, 600 mm and 800 mm as well as two web reinforcement ratios of 0% and 0.4% were used. The longitudinal reinforcement, compressive strength and beam width were kept constant at 1.2%, ≈55 MPa and 175 mm, respectively. The web reinforcement ratio achieved the minimum requirements of the CSA S806-12. The experimental results highlighted that the web reinforcement ratio improved the load capacities by about 10% and 18% for specimens having 𝑎/ℎ ratios of 1.0 and 1.7, respectively. For specimens with web reinforcement, the increase of 𝑎/ℎ ratio from 1.0 to 1.7 led to reductions in the load carrying capacity by about 33% and 29% for beams with overall depths of 300 mm and 600 mm, respectively. Additionally, a considerable reduction occurred in the shear strength due to the increase of the section depth from 300 mm to 600 mm. The experimental results confirmed the impacts of web reinforcement and size effect that were not considered by the strut-and-tie method (STM) of the only code provision, the Canadian S806-12, that addressed such elements. In this study, the STM was illustrated and simplified to be adopted for GFRP RC continuous deep beams, and then, the experimental results obtained from this study were employed to assess the performance of the effectiveness factors suggested by the STMs of the American (ACI 318-2014), European (EC2-04) and Canadian (S806-12) codes as well as those factors recommended by the previous studies to predict the load capacities. It was found that these methods were unable to reflect the influences of member size and/or web reinforcement reasonably, the impact of which has been confirmed by the current experimental investigation. Therefore, a new effectiveness factor was recommended to be used with the STM. Additionally, an upper bound analysis was developed to predict the load capacities of the tested specimens considering a reduced bond strength of GFRP bars after assessing the old version recommended for steel RC continuous deep beams. A good agreement between the predicted results and the measured ones was obtained with the mean and coefficient of variation values for experimental/calculated results of 1.02 and 5.9%, respectively, for the STM and 1.03 and 8.6%, respectively, for the upper-bound analysis. A 2D finite element analysis using ABAQUS/Explicit approach was carried out to introduce a model able to estimate the response of GFRP RC continuous deep beams. Based on the experimental results extracted from the pullout tests, the interface between the longitudinal reinforcement and concrete surface was modelled using a cohesive element (COH2D4) tool available in ABAQUS. Furthermore, a perfect bond between the longitudinal reinforcement and surrounding concrete was also modelled to evaluate the validity of this assumption introduced by many previous FE studies. To achieve a reasonable agreement with the test results, a sensitivity analysis was implemented to select the proper mesh size and concrete model variables. The suitability and capability of the developed FE model were demonstrated by comparing its predictions with the test results of beams tested experimentally. Model validation showed a reasonable agreement with the experiments in terms of the failure mode, total failure load and the load-deflection responses. The perfect bond model has overestimated the predicted results in terms of stiffness behaviour and failure load, while the cohesive element model was more suitable to reflect the behaviour of those specimens. The validated FE model was then employed to implement a parametric study for the key parameters that govern the behaviour of beams tested and to achieve an in depth understanding of such elements. The parametric study showed that the higher the 𝑎/ℎ ratio the more pronounced the effect of web and the longitudinal reinforcements and the lower the effect of concrete compressive strength; and vice versa when 𝑎/ℎ ratio reduces.