The objectives achieved in this thesis are: (1) to develop a new method for measuring the most important acid buffering mechanism within a soil ecosystem-mineral weathering and (2) to test a soil acidification simulation model against actual field data to determine which soil acidifying or buffering mechanisms seem to be understood and which mechanisms need more detailed analysis. First, a new method was developed that allows for quantification of H$ sp+$ consumption due to weathering and H$ sp+$ consumption due to cation exchange. Initial results yield mineral weathering rates that are well within the range of results obtained by other workers. This technique permits the analysis of multiple soil samples in a relatively short time, allowing for better quantification of spatial variability of mineral weathering within a soil ecosystem. Secondly, it was demonstrated that the acid simulation model generally underestimates soil chemistry values for pH, base cation saturation and soil solution base cations, and overestimates soil solution nitrate concentrations. Problems with obtaining accurate measurements of atmospheric dry deposition, a lack of data on cycling of nutrient elements and the absence of a sub-model to deal with the accumulation and mineralization of organic matter are reasons thought to explain the differences between model and field results.

No description available.

Calcium (Ca) depletion and increased bioavailability of aluminum (Al) are potential consequences of soil acidification caused by acidic deposition and other anthropogenic factors. Tree declines are associated with base cation depletion and increased Al toxicity in forest soils in North America, Europe, and Asia. Changes in soil Ca and Al availability may lead to increased oxidative stress and disruptions in carbohydrate relationships in forest trees, as well as to substantial alterations in the capacity for enzymatically controlled processes of decomposition and mineralization in forest soils. Assessments were made to determine if forest systems are prone to disruption associated with altered Ca and Al bioavailability. Foliar elemental concentrations, foliar antioxidant enzyme activities, foliar and woody shoot carbohydrates were measured in sugar maple (Acer saccharum, Marsh.), and soil extracellular enzyme activities (EEA) were assayed at a long-term nutrient perturbation study (NuPert) in the Hubbard Brook Experimental Forest, New Hampshire, USA. Treated plots received Ca to increase soil Ca above ambient depleted levels or Al to further reduce Ca availability. Additions of Ca to soil are associated with greater Ca concentrations in foliage compared to leaves from trees from control and Al-addition plots. Soil Aladditions are associated with lower foliar phosphorus concentrations in comparison with foliage from trees in Ca-addition plots. Additions of Al to soil are associated with higher antioxidant enzyme (glutathione reductase and ascorbate peroxidase) activities in foliage and lower shoot sugar (total sugars, sucrose, glucose and fructose) concentrations relative to trees in Ca-addition and control plots. Al accumulations in distal tissues likely triggered toxicity responses reported for leaves and stems. Soil EEA results highlight treatment-induced alterations to soil processes. Across soil enzyme systems, EEA levels are greatest in Al-addition soils in fall, but are elevated in Caaddition soils in spring compared with ambient conditions. Seasonal differences in EEA levels suggest a differential influence of soil treatments on specific soil communities. Within this native, mature northern hardwood forest, early indications of response in foundation species to Ca and Al manipulation are detected including Al-induced oxidative stress and resulting carbohydrate irregularities in sugar maple trees, and substantial seasonal swings in soil EEA: processes that could foreshadow broader ecosystem alterations as anthropogenic disruptions of soil Ca and Al availability continue.

Thesis (M.S.)--West Virginia University, 2005. / Title from document title page. Document formatted into pages; contains viii, 169 p. : ill. (some col.), col. maps. Includes abstract. Includes bibliographical references (p. 62-67).

No description available.

No description available.

Thesis (Ph.D.)--University of Western Australia, 2006.

Acid deposition (AD) results largely from the combustion of fossil fuels, and has been found to negatively impact forest ecosystems. AD may acidify soils through base cation leaching or Al mobilization, may cause accumulation of nitrates and sulfates in soils, and in some cases has been related to forest decline. The Monongahela National Forest (MNF) lies downwind from many sources of AD pollution, and average deposition pH is around 4.4. Therefore, managers are concerned about the possible deleterious effects of AD on the forest ecosystem. During the 2006 Forest Plan revision, evaluation of site sensitivity to acidification was specifically stated as a step in the Forest's adaptive management process. To meet this management objective, forest practitioners must understand the effects AD has on the forest, prescribe appropriate practices, and be able to monitor for future changes. To address the needs of MNF managers we used Forest Inventory and Analysis (FIA) sites to evaluate forest growth patterns on the Forest and determined the relationship between growth and key indicators of soil acidity. Furthermore, we used those relationships to create a map of site resistance to acidification across the MNF. To further develop a monitoring scheme we assessed two soil sampling protocols and two soil analysis methods for their suitability for monitoring AD-related changes in soil chemistry. Additionally, we evaluated the utility of dendrochronological and foliar sampling as AD-specific monitoring methods. Across all FIA sites on the MNF periodic mean annual volume increment (PMAVI) ranged from -9.5 m³ha⁻¹yr¹ to 11.8 m³ha⁻¹yr¹, suggesting lower-than-expected growth on two-thirds of the sites. Growth was compared to soil indicators of acidity on 30 FIA sites. In the surface horizon, effective base saturation (+), Ca concentration (+), base saturation (+), K concentration (+), Fe concentration (-), Ca/Al molar ratio (+), and Mg/Al molar ratio (+), were correlated with PMAVI (p ≤ 0.1). In the subsurface horizon pH_(w) (+), effective base saturation (+), Al concentration (-), and K concentration (-) were correlated with PMAVI. Site resistance to acidification was mapped based on site parent material, aspect, elevation, soil depth, and soil texture. There was a significant (p ≤ 0.1) positive correlation between PMAVI and a resistance index developed using five soil and site factors. Resistance was also compared with key soil indicators of AD-induced decline on 28 sites across the forest, and pH, effective base saturation, and Al content were found to be the best indicators related to resistance index. Resistance index was used to create a map of the MNF, of which 14% was highly resistant (RI ≥ 0.7), 57% was moderately resistant (0.7 > RI > 0.45) and 29% was slightly resistant (RI ≤ 0.45). The first of our monitoring program evaluations compared soil sampling and analysis methods on 30 FIA plots. Analyses of variance showed that soil pH, effective base saturation, Ca/Al molar ratio, and sum of bases varied significantly with sampling protocol. We also compared lab analyses methods and found that if sampling by horizon, a linear relationship can be used to estimate Ca/Al_SrCl₂ ratio using NH₄Cl extractions. The second monitoring approach evaluated the utility of a northern red oak (Quercus rubra L.) dendrochronology on two FIA plots. This analysis suggests that pollution on the MNF caused a decrease in growth rate during the 50-year period from 1940 to 1990. There were no differences among ring width increment and basal area increment between the two sites. From 1900 to 2007 the two sites showed 58.5% similarity in growth trends, but these could not be attributed to a dissimilar influence of AD. The third monitoring approach evaluated the relationship between foliar and soil chemical indicators. Across FIA plots, nutrient concentrations varied by tree species. The first year results from a potted-seedling study suggest that soil acidity influences growth, and foliar concentrations are related to growth rates. This evaluation of the effects of AD on the MNF can be used to develop adaptive management plans and a monitoring program that will meet the AD-related objectives of the 2006 Forest Management plan. / Master of Science

I explored the importance of decaying wood to survival and growth of trees in south coastal British Columbia, and the effect of decaying wood on the intensity of podzolization on mesic sites. A field pot study was carried out in both high light and low light conditions using woody and non-woody forest floor materials. After two growing seasons, Pseudotsuga menziesii, Tsuga heterophylla, and Abies amabilis seedlings growing in clearcuts had greater survival and growth in the non-woody substrate; however, in the understory, the effect was much less. The proliferation of western hemlock roots was used as an indicator of the value of decaying wood to trees. In both greenhouse trials (using seed sown on a series of planting pots with each half filled with either a woody substrate or a non-woody substrate), and in field sampling of woody and non-woody substrates in mature stands, the non-woody substrate had a larger density of fine and very fine roots compared to the woody substrates or mineral soil. Ten litres of concentrated solutions of non-woody humus substrate and woody substrates were leached through soil columns. Both the non-woody and woody solutions had similar mean pH but significantly different chemical properties. The non-woody solution leachate had greater net average output of dissolved organic C, Fe, and Mn. The mineral soil treated with the nonwoody solution had significantly greater concentrations of total N and pyrophosphate-extractable Fe. In the field, forest floor and soil samples were compared between pedons having large accumulation of decaying wood and pedons with non-woody humus forms. Despite large and significant differences in chemical properties between the two substrates, there were generally no significant differences between the chemical properties of the soils directly under these substrates. In most cases, the results of (3-analyses showed that the means were not pedologically different. Additionally, 18 pairs of zero tension plate lysimeters were installed under the two substrates. The lysimeter solutions showed no significant differences. I concluded that coarse woody debris appears not to have either a positive effect of increased productivity of trees or a negative effect of increased intensity of podzolization.

No description available.