The environmental and agricultural viability of land disposal of a water treatment residue (WTR) from the Midmar Water Treatment Works of Umgeni Water was investigated by determining answers to four broad questions: 1. What effects would the application of the WTR have on plants growing on the treated soils? 2. What effects would application of the WTR have on soil chemical properties? 3. What effects would the WTR have on the soil solution composition (and by implication the quality of the groundwater)? 4. Could this material be used to reduce solubility of potential pollutants? To answer these questions, the following experiments were set up, and their respective results are reported. 1. Effects of the water treatment residue on plant growth This was investigated in a pot experiment and two field experiments. In the pot experiment five soils, two Huttons (Hu-M and Hu-T), an Inanda (la-C), a Namib (Nb-F) and a Shortlands (Sd) were used to grow perennial ryegrass ((Lolium perellne). All samples were fertilized with a basal dressing of N, P, K, Mg and S. Two lime levels were added to the Ia-C and Nb-F soils, the higher calculated to reduce acid saturation to 1%, and the lower being half of that. The WTR was applied at rates of 0, 40, 80 and 120 Mg ha-1. All treatments were in triplicate. Eight cuts in all were made of the perennial ryegrass. The dry matter (DM) yield of perennial ryegrass grown in the pot experiment increased with the WTR applied in all five soils although the highest increase was with the acidic Ia-C and Nb-F soils. The fact that the highest yields were on the strongly acid soils suggests that the liming effect of the WTR could have contributed, more so considering that lime also increased yields in these soils. It was, however, clear that no one factor was responsible for the increase in yield as the timing effect could not explain the results of the other three soils. At the two field experiments perennial ryegrass was grown at Brookdale Farm from 1998 to 2001, after which the site was re-seeded with tall fescue (Festuca arundinaceae). At Ukulinga Farm tall fescue was grown from the outset in 2000. In the two field experiments with both perennial ryegrass and tall fescue, no significant increase in yield was apparent. Importantly, however, from an environmental point of view there was no decrease in yield whether the WTR was incorporated or applied as a mulch. This was observed even at the highest rates of application, namely 1280 Mg ha-1. The growth on the mulched plots was often observed to be better than any of the other treatments, including the control. Analysis of the plant material from both pot and field experiments indicated that the WTR neither pollution of the groundwater by nitrates. However, analysis of saturated pastes from soils at both field experiments showed that the levels of nitrate were increased by application of the WTR in only the fallow plots. 4. The water treatment residue as a possible pollutant-reducing agent The effect of the water treatment residue on the sorption of P and heavy metals (Cd, Ni and Zn) was studied in the laboratory. Soils treated with WTR were equilibrated for 6 hours in 0.005 M calcium cWoride solution containing a known concentration of each element. For the coarse-textured soils, initial P concentrations ranged from 0 to 1000 mg kg-1 as opposed to 0 to 1800 mg kg-1 for the clay soils. Treatments of WTR used were 0, 80, 320 and 1280 Mg ha-1, both incubated and non-incubated. At high initial P solution concentrations, the WTR increased the extent of sorption in the coarser textured soils (Hu-T, Nb-A, Nb-F, Va and We), and decreased it in highly sorbing Av, Hu-M, la-C and la-W soils. In general though, the WTR greatly reduced soluble P. For Cd, Ni and Zn only one concentration, 50 mg kg-1, was studied using the incubated soil samples as affected by WTR rates from 0 to 1280 Mg ha-1. For all three metals, the amount sorbed increased with increase in amount of WTR for the nine soils studied, namely the Av, Hu-F, Hu-M, Hu-T, la-C, la-W, Nb-F, Va and We. In many cases the sorption was so high that more than 40 mg kg-1 of the initial concentration was removed from solution. Even for those soils with high sorption capacity e.g. the Va and We, the WTR still increased sorption by up to an average of more than 25% for Cd and more than 40% for Ni and Zn. Because for the Av and la-W soils liming also increased sorption, it could be assumed that the accompanying increase in pH as a result of the addition of WTR promoted precipitation of metals, and/or the resultant increase in negative charge increased their adsorption. These results show that where excess concentrations of soluble heavy metals may occur (especially in coarse-textured soils), and where there is concern about run-off with high P concentrations then this WTR could be considered to immobilize these elements and render them less harmful to the environment. General comments and management guidelines. Based on the results reported above, it is apparent that the WTR can be safely disposed of onto land. It has been demonstrated in the current investigation that rates of application can be as high as 1280 Mg ha-1. Rates of application to land higher than 1280 Mp; ha-1 could probably be acceptable - this was the highest rate tested in this investigation - where the residue is produced in large amounts at the plant, and land for disposal is somewhat limited. / Thesis (Ph.D.)-University of KwaZulu-Natal, Pietermaritzburg, 2005.

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Limitations on water infiltration and soil aeration through compaction processes have the potential to limit production in irrigated agricultural fields. This project was conducted to determine the impact of sub-soiling with a paraplow (Howard Rotavator) on soil physical properties and processes that are important in affecting soil-water relations and productivity. The paraplow was the subsoiler selected for use in this study because of its ability to loosen the soil at the depth of plowing while producing minimal surface disturbance. The research plots were located on Chernozem and Vertisol soils in the Brown soil zone in the Lake Diefenbaker irrigation district near Birsay, SK. Irrigated and dryland sites were used for comparison. Sub-soiling was able to consistently reduce bulk density of the soil and effects persisted for one to two years under normal precipitation conditions. Excessively wet conditions (2010 and 2011) reduced the effectiveness of the sub-soiling. Tillage induced porosity in the soil was associated with a greater infiltration capacity measured in the field. Yield benefits in crops grown (canola, flax, wheat) from sub-soiling were variable under the wet conditions of 2010 and 2011. A greater benefit was observed under the normal precipitation conditions of 2012 on sites that were paraplowed in 2011. Subsoiling at a depth of 45cm and a row spacing of 45cm (manufacturer’s recommended configuration) was more effective than shallower depth and wider row spacing treatments. A significant yield benefit was only observed at the dryland site established in 2011, and limited yield benefit was observed in the irrigated sites. Over the three years of the study, annual yields from sub-soiling were on average about 5% higher than the un-tilled control. However, yield benefits were variable depending on crop and year. Given an estimated cost of subsoiling of ~$30 per acre, a benefit of sub-soiling that lasts one year would produce close to break-even conditions, and sub-soiling benefits that are consistent and last longer than one year are needed to be cost effective.

Under iron (Fe3+)-reducing conditions where aqueous Fe2+ and unreduced solid Fe3+-oxides commonly coexist, soil Fe2+ oxidation has been shown to be coupled with nitrate (NO3-) reduction. One possible secondary reaction is the involvement of NO3- and nitrite (NO2-) with Fe-oxide minerals found in many natural environments. Yet, spectroscopic measurements and kinetic data on reactivity of NO3- and NO2- with Fe-containing oxide minerals such as goethite (a-FeOOH), and magnetite (Fe3O­4) are not found in the literature. The reactivity of goethite and magnetite with NO3- and NO2- was studied over a range of environmentally relevant pH conditions (5.5-7.5) with and without added Fe2+(aq) under anoxic conditions. Laboratory experiments were conducted using stirred batch experiments and reaction products were analyzed using ion chromatography (IC), gas chromatography (GC), ultraviolet visible near infrared spectroscopy (UV-VIS-NIR), x-ray diffraction (XRD), scanning electron microscopy (SEM), Mössbauer, and Attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy. Nitrate removal by goethite and magnetite was much slower when compared with NO2-. There was a pH-dependence in the reduction of NO2-, and the initial rate of NO2- removal was nearly 2 and 8 times faster at pH 5.5 than at pH 7.5 by magnetite and goethite, respectively. Nitric oxide (NO) and nitrous oxide (N2O) were identified as products when NO2- has reacted with magnetite, whereas N2O is the major reaction product in the experiment with goethite. In comparison to experiments containing magnetite or goethite alone, addition of Fe2+ greatly accelerated the NO2- removal rate. Wet chemical experiments combined with the Mössbauer study reveals that NO2- reduction to NO and subsequently to N2O by magnetite occurs via a heterogeneous electron transfer process. ATR-FTIR and diffuse reflectance spectroscopy (DRS) results from the studies with goethite indicate that NO2- was removed from solution by adsorption in a surface complex involving the oxygen atoms, and a portion of the nitrite is reduced to NO and N2O. This study suggests that under anaerobic conditions soil and sediments that contain goethite, magnetite, and other Fe3+-oxides can catalyze abiotic NO2- reduction and the kinetics data from this study can be used to predict the NO2- removal under such conditions.

<p> Soil moisture sensor use in crop production systems has the potential to give inference on plant water status for the purpose of irrigation scheduling and site-drought characterization. These processed measurements could serve as the framework on which to compile trial results across locations, thereby more accurately defining varietal yield response to drought. Still, the ability to characterize drought within a given field or initiate irrigations from these data hinge upon the ability of the instrument to characterize soil moisture at the sampled point and extrapolate that information across the landscape and time. Therefore, the objectives of this research were to: (1) test the response of the Watermark 200SS (Irrometer Company, Inc., Riverside, CA) and Decagon 10HS (Decagon Devices, Inc., Pullman, WA) to changes in water content of three dissimilar soils representing common soils in row-crop production under variable environmental conditions; (2) develop a soil moisture-based index to quantify drought stress in dryland cotton cultivar trials; and (3) determine if a limited number of soil moisture sensors deployed into a dryland cultivar trial could accurately characterize the VWC at a given point within the field and if this measurement could be extrapolated out to the field scale from the very small sphere of influence characterizing the utilized soil moisture sensors. During the 2012 and 2013 growing seasons soil moisture sensors were deployed into over 14 cotton cultivar trials across the U.S. Cotton Belt and into a water-input controlled container study. Tested sensors' inability to accurately predict container VWC emphasized the relatively small quantity of soil on which these sensors rely and the variability in soil moisture within a very limited volume. Results from the drought-index studies suggested both the Accumulated Soil Moisture Stress Index (ASMSI) and the relative reduction in evapotranspiration (1-(ET_{c adj}/ET_c)) appear to have potential in characterizing the amount of stress experienced within dryland cultivar trials. Analysis of spatial and temporal stability suggested trends between sensors were consistent, but absolute node readings varied. Optimism concerning the potential of these measurements/approaches for increasing water use efficiency is coupled with a call for more arbitrary, universal methods of measurement analysis.</p>

Soil water erosion is recognized as the principal mechanisms behind soil organic carbon (SOC) losses from soils, a soil constituent essential for ecosystem functions. SOC erosion can thus be far-reaching, affecting the future human welfare and the sustainability of ecosystems. Little research has yet been done to investigate the main mechanisms involved in the lateral translocation of SOC on the landscape. Understanding the effects of the different water erosion mechanisms, which control SOC losses (SOCL) at the hillslope level, creates scope for further scientific studies. Empirical data from 357 plots, with a range in slope length from 1 (n=117) to 22.1m (n=240) were analysed to estimate the global variations of particulate organic carbon content (POCC), POC losses (POCL) and sediment POC enrichment ratio (ER). The global average POCL rate was calculated to be 12.1 g C m-2 y-1. Tropical clayey soil environments revealed the highest POCL (POCL=18.0 g C m-2 y-1), followed by semi-arid sandy (POCL=16.2 g C m-2 y-1) and temperate clayey soil environments (POCL=2.9 g C m-2 y-1). The global net amount of SOC displaced from its original bulk soil on an annual basis was calculated to be 0.59±0.09 Gt C, making up an approximated 6.5% of the net annual fossil fuel induced C emissions (9 Gt C). POCL data for different spatial scales revealed that up to 83% of the eroded POC re-deposits near its origin in hillslopes, and is not exported out of the catchment. The low organic carbon sediment ER obtained from the data of clayey soils (ER of 1.1) suggests that most of the eroded POC remains protected within soil aggregates. Consequently, erosion-induced carbon dioxide (CO2) emissions in tropical areas with clayey soils are likely to be limited (less than 10%), as the process of POC re-burial in hillslopes is likely to decrease the rate of organic matter (OM) decomposition and thus serve as a potential carbon sink. Water erosion in sandy and silty soils revealed organic carbon sediment ER as high as 3.0 and 5.0, suggesting that in these soils the eroded POC is not re-buried, but is made vulnerable to micro-decomposers, thus adding to the atmospheric CO2 influx. The results obtained in the review study only reaffirm that large variations of POCL are evident across the different pedo-climatic regions of the world, making it a scientific imperative to conduct further studies investigating the link between SOC erosion by water and the global carbon cycle. A field study was designed to quantify the POC exported in the eroded sediments from 1x1m2 and 2x5m2 erosion plots, installed at different hillslope aspects, and to further identify the main erosion mechanisms involved in SOC erosion and the pertaining factors of control. The erosion plots were installed on five topographic positions under different soil types, varying vegetation cover, and geology in the foothills of the Drakensberg mountain range of South Africa. Soil loss (SL), sediment concentration (SC), runoff water (R) and POCL data were obtained for every rainfall event from November 2010 up to February 2013. Scale ratios were calculated to determine which erosion mechanism, rain-impacted flow versus raindrop erosion, dominates R, SL and POCL. Averaged out across the 32 rainfall events, there were no significant differences in R and POCL between the two plot sizes but SL were markedly higher on the 5m compared to the 1m erosion plots (174.5 vs 27g m-1). This demonstrates that the sheet erosion mechanism has a greater efficiency on longer as opposed to shorter slopes. Rain-impacted flow was least effective where soils displayed high vegetation coverage (P < 0.05) and most efficient on steep slopes with a high prevalence of soil surface crusting. By investigating the role of scale in erosion, it was possible to single out the controlling in situ (soil surface related conditions) and ex situ (rainfall characteristics) involved in the export of SOC from soils. This information will in future contribute toward generating SOC specific models and thus further inform erosion mitigation. / M. Sc. University of KwaZulu-Natal, Durban 2013.

Archaeologists have often speculated about the role of soil in the selection of prehistoricarchaeological site locations. These locations may be temporary or permanent settlements as well as isolated finds resulting from transient activities such as hunting. As an ecological factor, it would seem evident that soil played some part in the decision-making process. A review of recent literature reveals limited studies in this area. Several different approaches to the problem have been attempted. Recent research in the Central Indiana Wabash and Maumee drainages has been used develop a predictive model for this selection process based on the location of 890 sites on specific soils. The model has been tested with additional sites from various counties throughout Southern Indiana.The predictive model is based on the percentage of the original 890 sites which were located on each soil and on the resulting probability of finding additional sites on similar soils. The percentage of sites on each soil drainage class from the very poor to the excessively drained classes creates a curve similar to a normal curve. The test sites from the southern part of Indiana create a similar curve. / Department of Anthropology

A computer simulation model of the soil water regime can be a useful research, planning and management tool, providing that the data required by the model are available. Finite difference solutions of the general flow equation can be applied to complex field situations if soil profile characteristics are reflected by appropriate retentivity (B( Ψ)) and hydraulic conductivity (K(Ψ)) functions. The validity of a flow simulation model depends upon the degree to which simulated flow corresponds to the flow pattern in real soils. Macroscopic flow in apedal soils is likely to obey Darcy's law but in structured or swe~ling soils, macro-pores and shrinkage voids lead to non-Darcian flow. Physical composition and structural stability properties of a wide range of South African soils were used to assess swelling behaviour and depth-related textural changes. The applicability of a one-dimensional Darcian flow model to various soil types was evaluated. Core retentivity data for South African soils were used to derive regression equations for predicting B (Ψ) from textural criteria and bulk density. A sigmoidal, non-hysteretic two-part retentivity function having only two constants in addition to porosity was developed for use in water flow simulation models. Values of the constants, shapes of the retentivity curves and soil textural properties were related by fitting the retentivity function to retentivity data generated using regression equations~ Hydraulically inhomogeneous soils may be modelled by varying the values of the retentivity constants through the profile to reflect changing soil properties. Equations for calculating K(B) or K(Ψ) from retentivity data were derived by applying each of three capillary models to both exponential and two-part retentivity functions. Comparison of these equations showed that the definition and value of semi-empirical constants in the capillary models were as important as the choice of model in determining K(B). K(Ψ) was calculated using retentivity constants corresponding to a range of bulk density, clay and silt content combinations. Three retentivity constant-soil property systems were evaluated. These were derived from retentivity data for South African soils between 1) -10 and -1500 kPa, 2) 0 and -50 kPa and 3) from published retentivity data for British soils. Only that derived from retentivity data accurate in the 0 to -50 kPa range led to K(Ψ) relationships in which saturated K and the slope sK/sΨ decreased as bulk density, clay or silt content increased. Absolute values of K were unreliable and measured values are essential for matching purposes. A method for evaluating the constants in a K(Ψ) or K(B) function from the rate of outflow or inflow of water after a step change in potential at the base of a soil core was described. Simple exponential g (Ψ) and K(Ψ) functions were assumed to apply to each pressure potential range. Retentivity parameters were obtained by fitting the 8(Ψ) function to the measured retentivity curve. A value for K[s] , the remaining unknown parameter in the K(Ψ) function, was obtained by matching measured outflow and inflow data to a family of simulated curves. These were computed using measured retentivity parameters, core dimensions and ceramic plate conductivity, and a range of K[s] values. An advantage of this method is that there are no limitations on core length, plate impedance or pressure potential range which cannot be ascertained by prior simulation. Regression equations relating texture to retentivity, and a conductivity model were applied in a simulation study of the water regime in a weighing lysimeter in which gains and losses of water were measured accurately. Active root distribution was assumed proportional to root mass distribution. Relative K(Ψ) curves for each node were computed using one of the conductivity equations derived earlier. Daily water potentials for a month were simulated using three conductivity matching factors. By matching simulated Ψ values to tensiometer potentials measured at five depths an appropriate matching factor was chosen. The effects of an over- or underestimate of K(Ψ) were demonstrated. This work simplifies the prediction and use of retentivity and conductivity relationships in soil water flow simulation models. These models can be used for assessing the water regime in both irrigated and dry-land crop production. Other applications include catchment modelling, effluent disposal and nutrient and solute transport in soil. / Thesis (Ph.D.)-University of Natal, Pietermaritzburg, 1983.

The storage or disposal of nuclear waste is one of the major concerns faced by governments, communities, and environmentalists. This radioactive waste, as a source of ionising radiation, represents a potential hazard to human health and must be carefully managed so as to reduce the associated risks to acceptable levels for both now and in the future. The migration of radioactive waste (radionuclides) in the environment is controlled by many factors, such as the interaction of the radionuclides with soil. Humic acid (plant material) has substantial chelating properties for metal ions and can therefore considerably affect the migration behaviour of radionuclides in a soil layer. To manage the radioactive waste effectively, it is important to know the presence and interaction of humic acid with radionuclides released from radioactive waste repositories. The aim of this study is therefore to investigate the influence of humic acid on the distribution coefficients of radionuclides found in both Thabana and Vaalputs waste repositories. The technique employed in this study is based on a laboratory batch method to study the influence of humic acid on the distribution coefficients of (131)^I and (137)^Cs on soil samples from Thabana and Vallputs waste repositories at different concentrations. The results of this study show that (131)^I and (137)^Cs do not form any complexes with humic acid and therefore the presence of humic acid does not have a significant effect on the migration of (131)^I and (137)^Cs. / MSc (ARST) North-West University, Mafikeng Campus, 2005