In 1996, four cores (∼30 cm depth) were extracted from the high marsh zone of Dipper Harbour salt marsh in the Bay of Fundy. Soil bulk densities are shown to be controlled by mineral density and are higher than those reported for salt marshes in the northeastern United States. Examination of variations in mineral content suggests that regular tidal action and ice rafting deposits the majority of the mineral sediment to the high marsh zone. Dating techniques (based upon pollen, 137Cs, 210Pb and total Pb) were applied to selected cores, suggesting accretion rates from 0.25 to 0.31 cm yr-1 which are higher than the rates of local relative sea level rise. Correlation of trace metal densities (Cu, Fe, Pb and Zn) to Al densities were used to justify Al normalization. After consideration of natural sources and adsorption factors, the normalized Pb profiles are shown to reflect historical pollution levels of leaded gasoline consumption. Carbon storage values in the upper 25 cm of sediment range from 7.3--10.5 kg C m-2 and carbon accumulation rates vary from 95 to 124 g C m-2 yr-1, representing 15--29% of the salt marsh macrophyte productivity.

[Truncated abstract] The principal aim of this thesis was to examine the response of the microbial community to the addition of small amounts (<50 μg C g-1 soil) of organic C substrates (‘trigger molecules’) to soil. This addition is comparative to indigenous soluble C concentrations for a range of soil types in Western Australia (typically measured between 20 and 55 μg C g-1 soil). Previously it has been reported that the application of trigger molecules to European soils has caused more CO2-C to be evolved (up to six fold) than was applied . . . Findings from this study indicated that there was an additional CO2 release (i.e. greater than the C added) on application of organic C substrates to some soil treatments. However, findings from this study indicate that the response of the microbial community to small additions of soluble C substrate is not consistent for all soil types and may vary due to greater availability of C, and supports the premise that microbial responses vary in a yet to be predicted manner between soil type and ecosystems. Differences in microbial response to the addition of soluble organic C are likely attributable to differences in soil attributes and environmental factors influencing both the diversity of microbes present and the frequency of food events. Theoretically, trigger molecules could also provide a possible control mechanism for microorganisms in arable farming systems. These mechanisms include stimulating either targeted pathogenic microorganisms that starve after depletion of a suitable substrate; or stimulating beneficial microorganisms to manipulate nutrient cycling, by targeting specific functional groups and altering mineralisation and immobilisation turnover rates.

Thesis (M. Sc. Agriculture (Soil Science)) -- University of Limpopo, 2021 / Globally and in most parts of South Africa, there is a trend of increasing shrub encroachment in savanna rangelands. A number of studies have investigated the impact of shrub encroachment on soil organic carbon content (SOC) and soil organic carbon stocks (SOCs) in savannas. So far there is no clear consensus on whether shrub encroachment increases or decreases the level of SOC and SOCs, especially in semi arid savanna grasslands. Furthermore, knowledge on the effects of shrub encroachment on SOCs is largely restricted to the topsoil, as this is the part of the profile influenced by inputs and losses of soil organic matter. How shrub encroachment affects the vertical distribution of SOCs is rarely considered in the existing literature and the edaphic factors controlling SOCs with depth are poorly understood. The objectives of this study were (i) to quantify the vertical distribution of SOC and SOCs and (ii) to identify the edaphic factors controlling the vertical distribution of SOC and SOCs in a shrub-encroached savanna grassland sited on shallow plinthic soil. To achieve the objectives, a vegetation and soil survey of the savanna grassland was conducted whereby sampling areas were demarcated and characterized into open and shrub encroached grassland plots. In each encroachment level, three pits were randomly dug to the limiting layer on plots sited on the same soil type and similar topographic position. Soil samples were collected from the pits at depth intervals of 0-10, 10-20, 20-30, 30-40, 40-50, 50-60 and 60-70 cm. The collected soil samples were analyzed for chemical and physical properties in the laboratory. Correlation analysis was carried out to determine the relationship between SOC and SOCs, which were the variables of interest in this study and related controlling soil physicochemical properties. The results showed that SOC was significantly greater (P<0.05) in the shrub-encroached grassland compared to open grassland. Furthermore, the results revealed that SOC was on average 19 and 13% greater in the topsoil (0-20 cm) and subsoil (20-70 cm) of shrub encroached grassland compared to open grassland. The greater SOC in the topsoil of the shrub-encroached grassland was mainly attributed to higher SOC inputs from plant litter and detritus derived from trees and grasses, which are the dominant plant life forms in savannas. In the topsoil, SOC and SOCs were positively correlated with extractable phosphorus (P) (r = 0.60; P < 0.05), while in the subsoil they were positively correlated ix with extractable phosphorus (r = 0.54), soil porosity (r = 0.52), extractable copper (r = 0.46), extractable zinc (r = 0.41), exchangeable calcium (r = 0.37) and negatively correlated with mean weight diameter (r = -0.43). Overall, SOC and SOCs under both shrub-encroached and open grasslands vertically decreased with soil depth. The results obtained highlighted that the factors controlling the level of SOC and SOCs differs in the topsoil and subsoil of the studied shrub encroached grassland. These findings suggest that in the shallow plinthic soil investigated in this study, SOC in the topsoil is controlled by the macronutrient P, while in the subsoil it is physically protected by soil aggregates and chemically stabilized via complexation interactions with exchangeable cations and heavy metals. In-depth understanding of the physico-chemical factors controlling SOC storage is critical to foster management practices that will improve the cycling of SOC in shrub-encroached savanna grasslands.

No description available.

No description available.

No description available.

Thesis (MScAgric)--University of Stellenbosch, 2004. / ENGLISH ABSTRACT: Storing soil organic carbon (SOC) is a possible way of reducing atmospheric CO2 and potentially mitigating the effects of global warming. This study looks at soil carbon stocks, the sampling methodology and modelling of soil organic carbon in indigenous forests, wetlands, grasslands and pine plantations in Woodbush in the North-Eastern escarpment of Limpopo Province, South Africa. Dominant Pine species planted in Woodbush are Pinus patula, Pinus elliotti and Pinus taeda. Woodbush plantation was selected as study area because it provided easy access to all the ecosystems that were to be studied. All ecosystems in Woodbush are located in such a way that it was easy to compare them, as they existed under similar environmental and climatic conditions. The climatic conditions of Woodbush promote accumulation of SOC due to relatively higher precipitation and cooler temperatures than most parts of Limpopo Province. Five transects were made: two in indigenous forests and three in plantations. Only the surface (0-7 cm) layer was sampled with a distance of 20 m between sampling points. Transects were not made in grasslands and wetlands because of the patchy occurrence of these ecosystems. In addition to transects, eight 1ha plots, two in each ecosystem, were sampled. Surface (0- 7 cm depth) samples were collected on a grid of 20 x 20 m in each sampling plot. Two soil profile pits were sampled in each sampling plot, with samples being taken at 5, 10, 15, 20 30, 40, 50 60, 75 and 100 cm depth. The average carbon stocks per hectare of land to a soil depth of 100 cm were as follows: 71 t.ha-1 in wetlands, 28 t.ha-1 in grasslands, 64 t.ha-1in indigenous forests, and 46 t.ha-1 in pine plantations. Although wetlands sequestered large amounts of SOC per hectare, their relative contribution to carbon sequestration was low because of the relatively small area (87.2 ha) they occupy in the study area (and in South Africa). Prediction models for vertical distribution of SOC were developed using STATISTICA 6.0 for each ecosystem in order to estimate the carbon stocks to a depth of 100 cm based on SOC content and soil bulk density of the surface samples. These models were developed from observed values in soil profiles for each ecosystem. SOC content and carbon stocks were analyzed using GIS (ARCVIEW). The GIS analysis was aimed at assessing the effect of topography, elevation, soil type, and vegetation on accumulation and distribution of SOC stocks. Most shallow Inanda soils were distributed at elevations between 1545 m and 1777 m, and on a gentle slope in the Northern aspect of the mountain. Deep Inanda soils were found mostly in the lower elevation range of 967 m and 1545 m on moderate slopes. Deep and shallow Inanda soils were found on the southern aspect. Deep Kranskop soils are evenly distributed and mostly found at an elevation range of between 1080 and 1430 m on gentle slopes, while at an elevation range of between 1430 and 1780 m, they were found on moderate slopes. Deep soils had higher SOC stocks than shallow soils and soils in the southern aspects had higher SOC stocks than in the northern aspects. / AFRIKAANSE OPSOMMING: Die berging van grond organiese koolstof is ‘n moontlike manier om atmosferiese koolsuurgas (CO2) te verminder en dus om die invloed van globale verwarming te versag. In hierdie studie was die grond-koolstof voorraad bestudeer, asook die metodologie van die monsterneming en modellering van organiese grond-koolstof van inheemse woude, vleie, grasvelde en denneplantasies. Die studie was uitgevoer op Woodbush plantasie gele op die Noord-Oosterlike platorand van die Limpopo Provinsie, Suid-Afrika. Die algemeenste dennespesies in Woodbush is Pinus patula, Pinus elliotti en Pinus taeda. Die Woodbush plantasie was gekies as studiegebied omdat dit oor al die ekosisteme wat bestudeer moet word, beskik. Die ekosisteme in Woodbush is naby mekaar en dus maklik vergelykbaar want die omgewings- en klimaatstoestande is eenders. Die klimaatstoestande van Woodbush bevorder die akkumulasie van grond organiese koolstof omdat die reënval hoër en die temperature laer is as in die meeste ander dele van die Limpopo Provinsie. Vyf dwarssnitte was gemaak, twee in inheemse woude en drie in plantasies. Monsters was net uit die grondoppervlak laag geneem (7 cm) met 20 m tussen monsterpunte. Dwarssnitte was nie in grasvelde en vleie gemaak nie want hierdie sisteme is te gelokaliseerd. Monsters was ook geneem in agt 1 ha persele, twee in elke ekosisteem. Oppervlakmonsters (tot ‘n diepte van 7 cm) is op ‘n ruitnet van 20 x 20 m uit elke perseel versamel. Monsters was verder ook geneem uit twee profielgate per perseel, op dieptes 5, 10, 15, 20, 30, 40, 50, 60, 75 en 100 cm. Die gemiddelde koolstof voorraad per hektaar, op ‘n gronddiepte van 100 cm, was as volg: 71 t.ha –1 in vleie, 28 t.ha-1 in grasvelde, 64 t.ha-1 in inheemse woude en 46 t.ha-1 in denneplantasies. Alhoewel vleie groot hoeveelhede grond organiese koolstof akkumuleer, is hulle bydrae tot koolstof akkumulasie laag want hulle beslaan ‘n klein oppervlak binne die studiegebied (87.2 ha) asook klein oppervlaktes binne Suid-Afrika. Voorspellingsmodelle vir die vertikale verspreiding van grondkoolstof was met die gebruik van STATISTICA 6.0 ontwikkel ten einde te skat wat die koolstofvoorrraad op ‘n diepte van 100 cm was. Die skattings was gebaseer op organiese grondkoolstofinhoud en die gronddigtheid van oppervlakmonsters. Hierdie modelle was ontwikkel vanaf die waargenome waardes van grondprofiele vir elke ekosisteem. Die organiese koolstofinhoud van die grond en die koolstofvoorraad is ontleed met behulp van GIS (ARCVIEW). Die GIS ontleding was daarop gemik om die effek van topografie, hoogte bo seespiëel, grondtipe en plantegroei, op die akkumulasie en verspreiding van organiese grondkoolstof, te beraam. Die meeste vlak Inanda grondvorms kom voor tussen 1545 m en 1777 m bo seespiëel, asook op effens steil hellings op die Noordelike berghang. Die diep Inanda grondvorms is geleë op laer hoogtes bo seespiëel, gewoonlik tussen 967 en 1545 m, op effens steil hellings. Beide diep en vlak Inanda gronde word gevind op die suidelike berghang. Diep Kranskop gronde is eweredig versprei en word gewoonlik tussen 1080 en 1430 m bo seespiëel, op effens steil hellings, gevind. Dit kom ook voor op matig steil hellings, tussen 1430 en 1780 m bo seespiëel. Daar is meer organiese koolstof in diep grond as in vlak grond en meer in gronde teen die suidelike hang as op die noordelike hang.

Forest harvest can have significant impacts on forest ecosystems that may influence the capacity of soils to sequester carbon (C). The microbial community controls decomposition, which is a critical process in partitioning litter- and root-C between CO₂ and storage in semi-permanent soil-C pools. The objectives of this study were to determine the effect of clear-cutting and stand age on: 1) temporal dynamics of soil microbial community (SMC) structure and physiological status; and 2) shifts among microbial functional groups in taking up ¹³C-labeled plant materials during decomposition. The experiment was conducted in Douglas-fir ecosystems within the Gifford Pinchot National Forest, Washington. We chose stands of three different ages: old-growth where trees are between 300 and 500 years old; an 8-year old stand; and a 25-year old stand. Phospholipid fatty acid (PLFA) profiling and ¹³C-PLFA labeling techniques along with the ratio of saturated to monounsaturated PLFAs and the ratios of cyclopropyl PLFAs to their monoenoic precursors as microbial physiological stress markers were utilized. Microbial PLFA profiles showed that SMC structure and physiological status was most affected by season and secondarily by time since clear-cutting. Total microbial biomass and bacterial and fungal biomass were significantly reduced in CC8 but not in CC25 sites relative to old-growth sites. Total microbial biomass concentration was lowest and the stress indicators were highest in August, which corresponded to low soil moisture and high temperatures. The relative amount of ¹³C incorporated into PLFAs was also influenced by stand age and ¹³C source (¹³C-labeled litter vs. ¹³C-labeled root material). A significantly greater amount of ¹³C was incorporated in CC8 samples compared to OG1 samples in five out of the seven sample dates. Additionally, a significantly greater proportion of ¹³C was incorporated into soil samples containing the ¹³C-labeled litter material relative to samples containing ¹³C-labeled root material in four out of the seven dates. In general, 18:lω9 and 18:2ω6,9 (common fungal biomarkers) had the greatest amount of ¹³C incorporation throughout the study period in both clear-cut and old-growth sites, indicating the important role of fungi in the decomposition of litter and root material and translocation of C within soil layers. / Graduation date: 2006

This paper models the supply curve of carbon sequestration on Pacific Northwest rangelands. Rangeland managers have the ability to sequester carbon in agricultural soils by implementing alternative management practices on their farms. Their low adoption rate in practice suggests a high opportunity cost associated with their implementation. To increase their adoption, a payment for ecosystem services plan is proposed, where the public compensates farms for lost profits. The TOA-MD model is used to estimate the resulting sequestration incentivized by payments for soil carbon sequestration. Methodological questions of geographical stratification and estimating variation from available data are tested. Sensitivity analysis is also run on key assumptions in the study. Results show that while the economic potential of both systems is much lower than the technical potential, at reasonable CO��� payment levels rangeland sequestration could be a significant mitigation strategy for Pacific Northwest states. / Graduation date: 2012

The link between aboveground net primary productivity (ANPP) and resource gradients generated by complex terrain (solar radiation, nutrients, and moisture) has been established in the literature. Belowground ecosystem stocks and functions, such as soil organic carbon (SOC), dissolved organic carbon (DOC), and belowground productivity have also been related to the same topography and resource distributions, and therefore it is expected that they share spatial and temporal patterns with ANPP. However, stand structure on complex terrain is a function of multiple trajectories of forest development that interact with existing resource gradients, creating feedbacks that complicate the relationships between resource availability and ANPP. On a 96 ha forested watershed in the H.J. Andrews Experimental Forest in the Western Cascades range of Oregon, spatiotemporal heterogeneity in the secondary succession of a replanted Pseudotsuga menziesii stand following harvest results from the interaction of stand composition and abiotic drivers and may create unique "hot spots" and "hot moments" that complicate gradient relationships. In this dissertation, I tested the hypotheses that (chapter 3) multiple successional trajectories exist and can be predicted from a general linear model using specific topographic, historical, and biological parameters and that an estimated "maximum ANPP" may better represent stand characteristics than ANPP measured at a particular moment in time. I also test that (chapter 4) the distribution of light fraction carbon (LFC; C with a density of less than 1.85 g/cm��) is spatially variable, elevated on hardwood-initiated sites (hardwood biomass > 50% of biomass), and positively correlated with litter fall and ANPP. Chapter 4 also tests that heavy fraction carbon (HFC; C with a density of greater than 1.85 g/cm��) is a function of both soil mineralogy, stand composition, and ANPP, such that edges observed spatially in site mineralogy (changes in soil type) are reflected in sharp changes in the composition of the forest community and the magnitude of HFC stores. Finally, I hypothesized (chapter 5) that in complex terrain, dissolved organic carbon (DOC) export can be predicted from landform characteristics, relates to ANPP, and may be measured by several methods which are well-correlated with one another. In chapter 6, I discuss how litter fall measurements can be extrapolated to a watershed extent, and use litter fall as an example of the error that can occur in scaling up measurements taken at a small scale, within a heterogeneous stand on complex terrain, to a landscape scale extent. / Graduation date: 2013