Graduation date: 1999

Nitrogen availability in agricultural soils from fertilizer, plant residue inputs, and soil organic matter has important implications beyond crop yield. Legume winter cover crops and one fourth the recommended N rate on sweet corn resulted in yields equivalent to those at the recommended rate in the Willamette Valley of western Oregon. Cereal rye winter crops absorbed an average of 40 kg N/ha that otherwise would have been leached, but did not effectively replace fertilizer N. Cereal rye as a cover crop therefore shows an ability to immobilize N from fertilizer. This was further confirmed in an experiment with "N labeled urea where results showed that N derived from fertilizer in sweet corn or cereal rye plant residue was less available for crop uptake and loss from the system than inorganic N or N directly immobilized from fertilizer. Losses of N from fertilizer ranged from 40 to 73% of that which was in the soil over winter. Mineralization of organic matter N is an important process in N availability, especially when cover crops are used to replace fertilizer. Finding a general indicator or predictor of N mineralization in soils would help in reducing fertilizer N costs and leaching of inorganic N that is applied in excess of crop needs. In a screening of 17 biological and chemical properties of 19 differently managed soils from around the state of Oregon, a model using total soil N and ��-glucosidase activity provided the best model of mineralized N uptake by ryegrass. Biological activity is primarily responsible for the transformations that result in N availability in soils. Management of soils directly impacts soil biology, and results from multivariate analyses of biological and chemical parameters in differently managed soils showed that disturbance creates an overriding common biochemical state in soils. Beyond disturbance, vegetation and the nature of organic inputs also impart recognizable multivariate patterns in soils managed differently. These results suggest that indicators independent of soil type may be used to discern effects of management on agricultural soils. / Graduation date: 1999

Rotating wheat with other crops is a common practice in the Willamette Valley of western Oregon. Depending upon previous crop and soil type, current N fertilizer recommendations for wheat in the Willamette Valley vary widely. Excessive fertilizer poses environmental risk, whereas lower N inputs than required by the crop represent economic losses to growers. Growers and their advisors face the challenge to minimize the environmental risk, and at the same time to maintain or increase economic returns. Questions are often raised concerning the efficient use of N fertilizer and accurately predicting the amount of N needed by wheat following different crops. The first study measured growth, N uptake and N use efficiency (NUE) of winter wheat grown after either a legume or oat for three years. In all three growing seasons, winter wheat showed higher biomass, N uptake and NUE when grown after a legume than after oat. The contribution of legume was evident before the wheat was fertilized in spring, indicating that legume N had mineralized in fall or winter. Contribution of soil N to wheat suggested that fertilizer N can be reduced by 44 kg N ha����� if a legume is grown previously. Nitrogen use efficiency estimated 50 to 70 days after N application by isotopic method (24 to 94%) was comparable with that estimated simply by difference (21 to 94%) at the same time. The second study predicted gross mineralization rates using analytical models. Comparable N mineralization was predicted by a model assuming remineralization and a model assuming no remineralization, suggesting that remineralization was negligible. In the spring, mineralization-immobilization turnover was at a lower pace than expected in both rotations. In two growing seasons, gross mineralization rates were higher where the previous crop was legume (0.37 to 0.74 kg����� ha����� day�����) as compared to where oat was grown previously (0.14 to 0.6 kg����� ha����� day). Negative net mineralization indicated that fertilizer N was immobilized in the oat-wheat rotation. The third study evaluated calibration and digestion techniques used to determine elemental concentration in grasses. Use of a dry ashed standard to calibrate the ICP spectrometer generated highly variable calibration curves and was not a viable calibration method. Good agreement was found between chemical and microwave digested standards. Dry ashing resulted in considerable S and Mn losses, whereas, perchloric acid digestion and microwave digestion showed similar results. Our study suggests that if routine analysis are to be performed for macro nutrients or involve trace level work, the best method is microwave digestion with chemical standard calibration of ICP spectrometer. / Graduation date: 1999

Winter wheat is commonly grown in rotation with leguminous and non-leguminous crops in the Willamette Valley. For agronomic, economic, and environmental reasons it is important to understand the influence of previous crops on availability of N and other nutrients. Objectives of this study were: (1) to evaluate the effects of long-term rotations on winter wheat response to N fertilizer, and (2) to evaluate the use of Plant Root Simulator���(PRS) probes for measuring soil N mineralization and N availability to winter wheat. Field experiments were conducted over three growing seasons in plots of `Stephens' soft white winter wheat at Hyslop farm. Plots receiving 0, 50, 100, 150 and 200 kg N ha����� at Feekes GS 4 were sampled to determine above ground N uptake, grain yield, and grain protein. In spring 1998, PRS probes were placed in 0 kg N ha����� plots and removed at one-week or two-week intervals. In autumn 1998, probes were placed in unfertilized plots and removed at 1-week, 4-week, and 8-week intervals. Probes measured the availability of NH������-N, NO������-N, K���, Ca�����, Mg�����, and P0��������-P. Grain yield and N uptake were greater for wheat following clover as compared to following oats. Three-year average fertilizer equivalent values calculated from N uptake and grain yield data were 44.5 kg N h����� and 49.0 kg N h�����, respectively. The similarity of these independent measurements suggest that differences in N availability were the primary reason for the rotation effect. PRS probes also detected rotational differences in N availability. Average N recovered by probes sampled at 1-week intervals indicated that there was 63% as much NO������-N available to wheat following oat as compared to clover. Wheat recovered 64% as much N following oats as compared to clover. This suggests that PRS probes are an effective method for predicting relative amounts of plant available N. PRS probes also detected rotational differences in plant available potassium. Agronomic responses are useful for assessing the availability of nutrients that are limiting plant growth. PRS probes, on the other hand, are effective for assessing the availability of both limiting and non-limiting nutrients. / Graduation date: 2000

Graduation date: 1996