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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Influ?ncia da taxa de resfriamento na microestrutura da fase quasicristalina na liga Al65Cu35-xFex com baixo teor de Fe solidificada fora do equil?brio

Piedade, Luiz Alberto Silva da 18 August 2017 (has links)
Submitted by PPG Engenharia e Tecnologia de Materiais (engenharia.pg.materiais@pucrs.br) on 2017-10-26T16:09:28Z No. of bitstreams: 1 Tese Eng. Piedade.pdf: 6225051 bytes, checksum: c7f77823a538300959734acada65a861 (MD5) / Rejected by Caroline Xavier (caroline.xavier@pucrs.br), reason: Devolvido devido a 1) Arquivo PDF sem capa institucional. 2) Na primeira e segunda folha do arquivo PDF, o nome do autor est? incompleto. Na ficha catalogr?fica e publica??o enviada est? completo. 3) Nome e descri??o do arquivo na publica??o est?o em desacordo com o manual enviado. on 2017-11-07T13:03:14Z (GMT) / Submitted by PPG Engenharia e Tecnologia de Materiais (engenharia.pg.materiais@pucrs.br) on 2017-11-08T17:01:40Z No. of bitstreams: 1 final para entrega com capa.pdf: 6291908 bytes, checksum: a447082574d55fe4709b55f1c2da38fb (MD5) / Approved for entry into archive by Caroline Xavier (caroline.xavier@pucrs.br) on 2017-11-17T12:16:13Z (GMT) No. of bitstreams: 1 final para entrega com capa.pdf: 6291908 bytes, checksum: a447082574d55fe4709b55f1c2da38fb (MD5) / Made available in DSpace on 2017-11-17T12:20:52Z (GMT). No. of bitstreams: 1 final para entrega com capa.pdf: 6291908 bytes, checksum: a447082574d55fe4709b55f1c2da38fb (MD5) Previous issue date: 2017-08-18 / Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior - CAPES / Quasicrystals are materials that have unusual characteristics, they can not be described as crystalline, for not having long-range order, or as amorphous, have medium-range structure. Some Al-Cu-Fe family alloys presents quasicrystalline phases when have rapidly solidification. In order to obtain this alloy, ingots of the Al65Cu35-xFex family were casted with x=6 (atomic), initially in a standard mold with solidification equilibrium. To provide samples with different cooling rates, the alloy was cast in a stepped mold, containing six different steps, resulting in samples out of equilibrium state (rapidly solidification). For the analysis of the cooling curves, the CACC-TA technique was used, with cooling rates varying from170 to 540?C / s, which were obtained by dT/dt. Analyzes by optical microscopy, scanning electron microscopy (SEM), dispersive energy spectrometry (EDS), show microstructure with faceted dendrites, lamellar interdendritic formations and pentagonal precipitates (IQC). The Vickers microhardness ranged from 4.09 to 7.22 GPa and the X-ray diffraction (XRD) proved by characteristic diffractograms the icosahedral quasicrystalline phase formation. / Os quasicristais s?o materiais que apresentam caracter?sticas incomuns, pois n?o podem ser descritos como cristalinos, por n?o apresentarem ordem de longo alcance, nem como amorfos, apresentam estrutura de m?dio alcance. Algumas ligas da fam?lia Al-Cu-Fe apresentam fases quasicristalinas quando rapidamente solidificadas. Para obter-se esta liga, foram fundidos lingotes da fam?lia Al65Cu35-xFex com x=6 (at?mico), inicialmente em um molde padr?o com solidifica??o em estado de equil?brio. Para proporcionar amostras com taxas de resfriamento variadas, a liga foi vazada em um molde escalonado, contendo seis cavidades diferentes, resultando em amostras solidificadas fora do estado de equil?brio (solidifica??o r?pida). Para an?lise das curvas de resfriamento utilizou- se a t?cnica CACC-TA, com taxas de resfriamento variando entre 170 e 540?C/s, que foram obtidas por meio de dT/dt. An?lises por microscopia ?ptica, microscopia eletr?nica de varredura (MEV), espectrometria por energia dispersiva (EDS), mostram microestrutura com dendritas facetadas, forma??es interdendr?ticas lamelares e precipitados pentagonais (IQC). A microdureza Vickers variou entre 417 HV e 736 HV (4,09 e 7,22 GPa) e a difra??o de raios X (DRX) comprovou por meio de difratogramas caracter?sticos a forma??o de fase quasicristalina icosa?drica.

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