The non-ideal aqueous electrolyte simulator (NAELS) is composed of three major parts: a Newton-Raphson non-linear optimization program written by Weare, et al (1987); an activity coefficient subroutine for non-ideal electrolyte systems based on Pitzer's model; and an extensive, user expandable database. It is robust, stable, and requires neither thermodynamic data nor initial guesses as input. NAELS provides very good estimates of equilibrium speciation and solubility in concentrated electrolyte systems. NAELS was assembled as a technical utility package for use on IBM-compatable microcomputers. / Graduation date: 1992

Microfluidics refers to devices and methods for controlling and manipulating fluid flows at length scales less than a millimeter. Miniaturization of a laboratory to a small device, usually termed as lab-on-a-chip, is an advanced technology that integrates a microfluidic system including channels, mixers, reservoirs, pumps and valves on a micro scale chip and can manipulate very small sample volumes of fluids. While several flow control concepts for microfluidic devices have been developed to date, here flow control concepts based on thermally responsive polymer solutions are presented. In particular, flow control concepts base on the thermally triggered reversible phase change of aqueous solutions of the polymer Pluronic will be discussed. Selective heating of small regions of microfluidic channels, which leads to localized gel formation in these channels and reversible channel blockage, will be used to control a membrane valve that controls flow in a separate channel. This new technology will allow generating inexpensive portable bioanalysis tools where microvalve actuation occurs simply through heaters at a constant pressure source without a need for large external pressure control systems as is currently the case. Furthermore, a concept for controlled cross-channel transport of particles and potentially cells is presented that relies on the continuous regeneration of a gel wall at the diffusive interface of two co-streaming fluids in a microfluidic channel.

No description available.

The capillary surface formed within a symmetric annular tube is analyzed. Assuming identical contact angles along each boundary, we consider surfaces u(x,y) that satisfy the capillary problem on an annular region. Several qualitative properties of u are determined and in particular, the behaviour of u is examined in the limiting cases of the annular domain approaching a disk as well as a thin ring. The iterative method of Siegel is also applied to the boundary value problem and convergence is demonstrated under conditions which include a contact angle of zero. Moreover, some geometries still yield interleaving iterates, allowing for upper and lower bounds to be placed on the boundary values of u. However, the interleaving properties no longer hold universally and for other geometries, another more complex behaviour is described. Finally, a numerical method is designed to approximate the iterative scheme.

The capillary surface formed within a symmetric annular tube is analyzed. Assuming identical contact angles along each boundary, we consider surfaces u(x,y) that satisfy the capillary problem on an annular region. Several qualitative properties of u are determined and in particular, the behaviour of u is examined in the limiting cases of the annular domain approaching a disk as well as a thin ring. The iterative method of Siegel is also applied to the boundary value problem and convergence is demonstrated under conditions which include a contact angle of zero. Moreover, some geometries still yield interleaving iterates, allowing for upper and lower bounds to be placed on the boundary values of u. However, the interleaving properties no longer hold universally and for other geometries, another more complex behaviour is described. Finally, a numerical method is designed to approximate the iterative scheme.

No description available.

No description available.

No description available.

Thesis (M.Sc.)--Memorial University of Newfoundland, 2000. / Restricted until November 2001. Bibliography: leaves 100-105.

Thèse de doctorat : Chimie : Metz : 1998. / 1998METZ002S. 162 REF.